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Water-Assisted Formation of Micrometer-Size Honeycomb Patterns of Polymers
Abstract
Micropatterned thin films have received increased interest in the past few years. Besides preparation by conventional lithography, self-assembly of materials around a template can be used for patterning. Recently a method that utilizes the condensation of micrometer-size water droplets on solutions of block copolymers was reported for the preparation of ordered micrometer-size honeycomb structures. Here we show that the formation of honeycomb-like porous films is a general method that can be used for patterning many materials, e.g., block copolymers, amphiphilic polyion complexes, organic/inorganic hybrids, and homopolymers, such as polystyrene. Stabilization of water droplets is indispensable for regular pattern formation.
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Citations
Cites
Organically modified aluminosilicate mesostructures from block copolymer phases
Templin, M., Franck, A., Du Chesne, A., Leist, H., Zhang, Y., Ulrich, R., Schädler, V., & Wiesner, U. (1997) · Science · doi:10.1126/science.278.5344.1795 · Cited by 668
Cited by
Nanostructure fabrication using block copolymers
Hamley, I. W. (2003) · Nanotechnology · doi:10.1088/0957-4484/14/10/201 · Cited by 773
Single-Step Fabrication of Transparent Superhydrophobic Porous Polymer Films
Yabu, H., & Shimomura, M. (2005) · Chemistry of Materials · doi:10.1021/cm051281i · Cited by 375
Self-citationSun, F., Zhou, H., & Lee, J. (2011) · Acta Biomaterialia · doi:10.1016/j.actbio.2011.07.002 · Cited by 310
Kim, W. J., Basavaraja, C., Thinh, P. X., & Huh, D. S. (2013) · Materials Letters · doi:10.1016/j.matlet.2012.09.007 · Cited by 14
Metadata
- Authors
- Karthaus, O., Maruyama, N., Cieren, X., Shimomura, M., Hasegawa, H., & Hashimoto, T.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2000-06-29
- Volume
- 16
- Issue
- 15
- Pages
- 6071-6076
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2088513048
- Cited by
- 374
- References
- 1
- FWCI
- 9.06
- Type
- journal article
- Language
- en
- Open access
- closed
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- Karthaus, O., Maruyama, N., Cieren, X., Shimomura, M., Hasegawa, H., & Hashimoto, T. (2000). Water-Assisted Formation of Micrometer-Size Honeycomb Patterns of Polymers. Langmuir. https://doi.org/10.1021/la0001732
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