Organically modified aluminosilicate mesostructures from block copolymer phases
Abstract
Organically modified aluminosilicate mesostructures were synthesized from two metal alkoxides with the use of poly(isoprene-b-ethyleneoxide) block copolymers (PI-b-PEO) as the structure-directing molecules. By increasing the fraction of the inorganic precursors with respect to the polymer, morphologies expected from the phase diagrams of diblock copolymers were obtained. The length scale of the microstructures and the state of alignment were varied using concepts known from the study of block copolymers. These results suggest that the use of higher molecular weight block copolymer mesophases instead of conventional low-molecular weight surfactants may provide a simple, easily controlled pathway for the preparation of various silica-type mesostructures that extends the accessible length scale of these structures by about an order of magnitude.
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Simply varying the amount of the precursor with respect to the copolymer leads to morphological changes in the composite system.
“Interestingly, simply varying the amount of the precursor with respect to the copolymer would also lead to morphological changes in the composite system [148].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [148]
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- Authors
- Templin, M., Franck, A., Du Chesne, A., Leist, H., Zhang, Y., Ulrich, R., Schädler, V., & Wiesner, U.
- Affiliations
- Max Planck Institute for Polymer Research (DE)
- Max-Planck-Institut für Polymerforschung, Postfach 3148, 55021 Mainz, Germany.
- Corresponding author
- Wiesner, Ulrich
- Venue
- Science
- Published
- 1997-12-05
- Volume
- 278
- Issue
- 5344
- Pages
- 1795-1798
- ISSN
- 0036-8075 (ISSN-L)
- 1095-9203
- OpenAlex
- W2010768970
- Cited by
- 668
- References
- 36
- Citations by year
- 2026: 4 · 2025: 8 · 2024: 5 · 2023: 10 · 2022: 11 · 2021: 13 · 2020: 14 · 2019: 12 · 2018: 18 · 2017: 18 · 2016: 11 · 2015: 23 · 2014: 24 · 2013: 40 · 2012: 27
- FWCI
- 18.59
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Science (publishedVersion)
- PubMed (publishedVersion)
- Max Planck Institute for Plasma Physics (submittedVersion)
- MPG.PuRe (Max Planck Society) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Keywords
- metal alkoxides, polymer chain alignment
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