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Spontaneous Self-Assembly of Glycolipid Bilayer Membranes in Sugar-philic Ionic Liquids and Formation of Ionogels
Abstract
Ether-containing ionic liquids are developed, which are capable of dissolving carbohydrates such as β- d -glucose, α-cyclodextrin, amylose, agarose, and a glycosylated protein, glucose oxidase. When glycolipids are dispersed in these sugar-philic ionic liquids, stable bilayer membranes are formed. They display reversible thermal transformation from fibrous assemblies to vesicles. Physical gelation of ionic liquids occurs by dissolving amide-group-enriched glycolipids, providing a first example of self-assembling ionogels. The ability to dissolve carbohydrates in ionic liquids and the formation of bilayer membranes, self-assembling gels will open new dimensions in ionic liquid research.
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Cited by
Wang, P., Zakeeruddin, S. M., Comte, P., Exnar, I., & Grätzel, M. (2003) · Journal of the American Chemical Society · doi:10.1021/ja029294+ · Cited by 963
Electrolyte‐Gated Transistors for Organic and Printed Electronics
Kim, S. H., Hong, K., Xie, W., Lee, K. H., Zhang, S., Lodge, T. P., & Frisbie, C. D. (2013) · Advanced Materials · doi:10.1002/adma.201202790 · Cited by 957
Applications of Ionic Liquids in Carbohydrate Chemistry: A Window of Opportunities
El Seoud, O. A., Koschella, A., Fidale, L. C., Dorn, S., & Heinze, T. (2007) · Biomacromolecules · doi:10.1021/bm070062i · Cited by 668
Ionic liquids as amphiphile self-assembly media
Greaves, T. L., & Drummond, C. J. (2008) · Chemical Society Reviews · doi:10.1039/b801395k · Cited by 532
Solubility of Carbohydrates in Ionic Liquids
Zakrzewska, M. E., Bogel-Łukasik, E., & Bogel-Łukasik, R. (2010) · Energy & Fuels · doi:10.1021/ef901215m · Cited by 490
Ionic liquids and deep eutectic mixtures: Sustainable solvents for extraction processes
Pena‐Pereira, F., & Namieśnik, J. (2014) · ChemSusChem · doi:10.1002/cssc.201301192 · Cited by 432
Physico-chemical processes in imidazolium ionic liquids
Dupont, J., & Suarez, P. A. Z. (2006) · Physical Chemistry Chemical Physics · doi:10.1039/b602046a · Cited by 417
Metadata
- Authors
- Kimizuka, N., & Nakashima, T.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-10-01
- Volume
- 17
- Issue
- 22
- Pages
- 6759-6761
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2000480639
- Cited by
- 338
- References
- 0
- FWCI
- 5.40
- Type
- journal article
- Language
- en
- Open access
- closed
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