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Dewetting Instability during the Formation of Polymersomes from Block-Copolymer-Stabilized Double Emulsions
Abstract
We investigate the formation of polymer vesicles, or polymersomes, of polystyrene-block-poly(ethylene oxide) diblock copolymers using double emulsion droplets of controlled architecture as templates. To engineer the structure of the polymersomes, it is important to consider the concentration of diblock copolymer in the middle phase of the double emulsion. We describe how the presence of excess polymer can induce a transition from complete wetting to partial wetting of the middle phase, resulting in polymer shells with inhomogeneous thicknesses.
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Citations
Cited by
Teh, S.-Y., Lin, R., Hung, L.-H., & Lee, A. P. (2008) · Lab on a Chip · doi:10.1039/b715524g · Cited by 2,690
Blanazs, A., Armes, S. P., & Ryan, A. J. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800713 · Cited by 1,500
The biophysics and cell biology of lipid droplets
Thiam, A. R., Farese Jr, R. V., & Walther, T. C. (2013) · Nature Reviews Molecular Cell Biology · doi:10.1038/nrm3699 · Cited by 986
Synthesis of micro and nanostructures in microfluidic systems
Marre, S., & Jensen, K. F. (2010) · Chemical Society Reviews · doi:10.1039/b821324k · Cited by 734
Polymeric nanostructured materials for biomedical applications
Tang, Z., He, C., Tian, H., Ding, J., Hsiao, B. S., Chu, B., & Chen, X. (2016) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2016.05.005 · Cited by 363
Double Emulsion Templated Monodisperse Phospholipid Vesicles
Shum, H. C., Lee, D., Yoon, I., Kodger, T., & Weitz, D. A. (2008) · Langmuir · doi:10.1021/la801833a · Cited by 362
Self-citationIndocyanine Green J Aggregates in Polymersomes for Near-Infrared Photoacoustic Imaging
Changalvaie, B., Han, S., Moaseri, E., Scaletti, F., Truong, L., Caplan, R., Cao, A., Bouchard, R., Truskett, T. M., Sokolov, K. V., et al. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b14519 · Cited by 93
Metadata
- Authors
- Hayward, R. C., Utada, A. S., Dan, N., & Weitz, D. A.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-04-11
- Volume
- 22
- Issue
- 10
- Pages
- 4457-4461
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2330147581
- Cited by
- 179
- References
- 0
- FWCI
- 2.99
- Type
- journal article
- Language
- en
- Open access
- closed
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