The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
Water Stability of Microporous Coordination Polymers and the Adsorption of Pharmaceuticals from Water
Abstract
The stability of a variety of microporous coordination polymers (MCPs) to water-containing solutions was studied using powder X-ray diffraction. It was determined that the stability of the MCP is related to the metal cluster present in the structure with trinuclear chromium clusters more stable than copper paddlewheel clusters which are more stable than basic zinc acetate clusters. Zn(2-methylimidizolate)(2) was found to be more water stable than zinc MCPs with carboxylate linkers; however, extended exposure to water led to decomposition of all zinc-based MCPs. Matériaux de l'Institut Lavoisier (MIL)-100 was also found to be completely water stable and was used to adsorb the pharmaceuticals furosemide and sulfasalazine from water with large uptakes achievable at low concentrations, indicating that the adsorption of wastewater contaminants may be a feasible application for these materials.
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Cites
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Metal–Organic Frameworks for Separations
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Water Stability and Adsorption in Metal–Organic Frameworks
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Understanding the Effect of Water on CO2 Adsorption
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Metadata
- Authors
- Cychosz, K. A., & Matzger, A. J.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-05
- Volume
- 26
- Issue
- 22
- Pages
- 17198-17202
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2325374631
- Cited by
- 455
- References
- 44
- FWCI
- 16.11
- Type
- journal article
- Language
- en
- Open access
- closed
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