The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.
The Evolution of the Polycrystalline Copper Surface, First to Cu(111) and Then to Cu(100), at a Fixed CO2RR Potential: A Study by Operando EC-STM
Abstract
A study based on operando electrochemical scanning tunneling microscopy (EC-STM) has shown that a polycrystalline Cu electrode held at a fixed negative potential, -0.9 V (vs SHE), in the vicinity of CO2 reduction reactions (CO2RR) in 0.1 M KOH, undergoes stepwise surface reconstruction, first to Cu(111) within 30 min, and then to Cu(100) after another 30 min; no further surface transformations occurred after establishment of the Cu(100) surface. The results may help explain the Cu(100)-like behavior of Cu(pc) in terms of CO2RR product selectivity. They likewise suggest that products exclusive to Cu(100) single-crystal electrodes may be generated through the use of readily available inexpensive polycrystalline Cu electrodes. The study highlights the dynamic nature of heterogeneous electrocatalyst surfaces and also underscores the importance of operando interrogations when structure-composition-reactivity correlations are intended.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Introduction to Solid State Physics
Kittel, C., & Dexter, D. L. (1953) · American Journal of Physics · doi:10.1119/1.1933590 · Cited by 13,240
Electrochemical CO2 Reduction on Metal Electrodes
Hori, Y. (2008) · Modern Aspects of Electrochemistry · doi:10.1007/978-0-387-49489-0_3 · Cited by 1,868
Clavilier, J., Faure, R., Guinet, G., & Durand, R. (1980) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/s0022-0728(79)80022-4 · Cited by 1,503
Introduction to surface chemistry and catalysis
Mckee, C. (1994) · Applied Catalysis A: General · doi:10.1016/0926-860x(94)85211-1 · Cited by 1,492
A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
Gattrell, M., Gupta, N., & Co, A. (2006) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2006.05.013 · Cited by 1,486
Two Pathways for the Formation of Ethylene in CO Reduction on Single-Crystal Copper Electrodes
Schouten, K. J. P., Qin, Z., Pérez Gallent, E., & Koper, M. T. M. (2012) · Journal of the American Chemical Society · doi:10.1021/ja302668n · Cited by 902
Electrochemical Reduction of CO at a Copper Electrode
Hori, Y., Takahashi, R., Yoshinami, Y., & Murata, A. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp970284i · Cited by 816
Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces
Durand, W. J., Peterson, A. A., Studt, F., Abild-Pedersen, F., & Nørskov, J. K. (2011) · Surface Science · doi:10.1016/j.susc.2011.04.028 · Cited by 551
Gattrell, M., Gupta, N., & Co, A. (2007) · Energy Conversion and Management · doi:10.1016/j.enconman.2006.09.019 · Cited by 247
Oxygen electrosorption on copper single crystal electrodes in sodium hydroxide solution
Droog, J. M. M., & Schlenter, B. (1980) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(80)80421-9 · Cited by 89
Soriaga, M. P., Baricuatro, J. H., Cummins, K. D., Kim, Y.-G., Saadi, F. H., Sun, G., McCrory, C. C. L., McKone, J. R., Velázquez, J. M., Ferrer, I. M., et al. (2014) · Surface Science · doi:10.1016/j.susc.2014.06.028 · Cited by 28
Self-citationKim, Y.-G., & Soriaga, M. P. (2014) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2014.09.010 · Cited by 28
Self-citationCrystal growth at high temperatures
Zerfoss, S., Johnson, L. R., & Egli, P. H. (1949) · Discussions of the Faraday Society · doi:10.1039/df9490500166 · Cited by 17
Baricuatro, J. H., Ehlers, C. B., Cummins, K. D., Soriaga, M. P., Stickney, J. L., & Kim, Y.-G. (2013) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2013.10.001 · Cited by 16
Self-citation
Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Designing materials for electrochemical carbon dioxide recycling
Ross, M. B., De Luna, P., Li, Y., Dinh, C.-T., Kim, D., Yang, P., & Sargent, E. H. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0306-7 · Cited by 1,302
Zheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., & Qiao, S.-Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b02124 · Cited by 1,075
Improved CO2 reduction activity towards C2+ alcohols on a tandem gold on copper electrocatalyst
Morales-Guio, C. G., Cave, E. R., Nitopi, S. A., Feaster, J. T., Wang, L., Kuhl, K. P., Jackson, A., Johnson, N. C., Abram, D. N., Hatsukade, T., et al. (2018) · Nature Catalysis · doi:10.1038/s41929-018-0139-9 · Cited by 773
Arán-Ais, R. M., Scholten, F., Kunze, S., Rizo, R., & Roldan Cuenya, B. (2020) · Nature Energy · doi:10.1038/s41560-020-0594-9 · Cited by 771
Metadata
- Authors
- Kim, Y.-G., Baricuatro, J. H., Javier, A., Gregoire, J. M., & Soriaga, M. P.
- Venue
- Langmuir
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-12-09
- Volume
- 30
- Issue
- 50
- Pages
- 15053-15056
- ISSN
- 0743-7463 (ISSN-L)
- 1520-5827
- OpenAlex
- W2050529292
- Cited by
- 324
- References
- 14
- FWCI
- 4.37
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
