The DOI matches its Crossref record; 24 of the 24 references it cites were found in a registry or an index.
Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts
Abstract
Electrochemical reduction of CO 2 to high-energy-density oxygenates and hydrocarbons beyond CO is important for long-term and large-scale renewable energy storage. However, the key step of the C–C bond formation needed for the generation of C 2 products induces an additional barrier on the reaction. This inevitably creates larger overpotentials and greater variety of products as compared to the conversion of CO 2 to C 1 products. Therefore, an in-depth understanding of the catalytic mechanism is required for advancing the design of efficient electrocatalysts to control the reaction pathway to the desired products. Herein, we present a critical appraisal of reduction of CO 2 to C 2 products focusing on the connection between the fundamentals of reaction and efficient electrocatalysts. An in-depth discussion of the mechanistic aspects of various C 2 reaction pathways on copper-based catalysts is presented together with consideration of practical factors under electrocatalytic operating conditions. By providing some typical examples illustrating the benefit of merging theoretical calculations, surface characterization, and electrochemical measurements, we try to address the key issues of the ongoing debate toward better understanding electrochemical reduction of CO 2 at the atomic level and envisioning the roadmap for C 2 products generation.
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Cites
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Self-citationHow copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels
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Cited by
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
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Boosting electrocatalytic CO2–to–ethanol production via asymmetric C–C coupling
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Self-citationStabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane
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Metadata
- Authors
- Zheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., & Qiao, S.-Z.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2019-04-15
- Volume
- 141
- Issue
- 19
- Pages
- 7646-7659
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2938620684
- Cited by
- 1,075
- References
- 24
- FWCI
- 24.07
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zheng, Y., Vasileff, A., Zhou, X., Jiao, Y., Jaroniec, M., & Qiao, S.-Z. (2019). Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.9b02124
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