Poly(organophosphazenes) with Poly(alkyl ether) Side Groups: A Study of Their Water Solubility and the Swelling Characteristics of Their Hydrogels

New directions in thermoresponsive polymers

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Thermosensitive water-soluble copolymers with doubly responsive reversibly interacting entities

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Ring-Opening Polymerization—An Introductory Review

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Thermoresponsive polymers with LCST transition: synthesis, characterization, and their impact on biomedical frontiers

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Thermoresponsive Dendronized Polymers

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Transiently thermoresponsive polymers and their applications in biomedicine

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Synthesis and characterization of poly(ethylene glycol)/poly(l-lactic acid) alternating multiblock copolymers

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A New Class of Biodegradable Thermosensitive Polymers. 2. Hydrolytic Properties and Salt Effect on the Lower Critical Solution Temperature of Poly(organophosphazenes) with Methoxypoly(ethylene glycol) and Amino Acid Esters as Side Groups

Lee, S. B., Song, S., Jin, J., et al. (1999) · Macromolecules · doi:10.1021/ma990645n · Cited by 123 · see citing works

Polyphosphazene elastomers, gels, and other soft materials

Allcock, H. R. (2012) · Soft Matter · doi:10.1039/c2sm26011e · Cited by 100 · see citing works

Thermosensitive poly(organophosphazene) hydrogels for a controlled drug delivery

Kang, G. D., Cheon, S. H., Khang, G., et al. (2006) · European Journal of Pharmaceutics and Biopharmaceutics · doi:10.1016/j.ejpb.2006.01.001 · Cited by 95 · see citing works

Synthetic Biomaterials for Regenerative Medicine Applications

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Synthesis and characterization of pH-sensitive poly(organophosphazene) hydrogels

Allcock, H. (1996) · Biomaterials · doi:10.1016/0142-9612(96)00073-7 · Cited by 80 · see citing works

Injectable and Biodegradable Supramolecular Hydrogels by Inclusion Complexation between Poly(organophosphazenes) and α-Cyclodextrin

Tian, Z., Chen, C., & Allcock, H. R. (2013) · Macromolecules · doi:10.1021/ma4004314 · Cited by 78 · see citing works

In Vitro and In Vivo Characterization of Biodegradable Poly(organophosphazenes) for Biomedical Applications

Kumbar, S. G., Bhattacharyya, S., Nukavarapu, S. P., Khan, Y., Nair, L. S., & Laurencin, C. T. (2006) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/s10904-006-9071-6 · Cited by 76 · see citing works

Synthesis and Micellar Characterization of an Amphiphilic Diblock Copolyphosphazene

Chang, Y., Lee, S. C., Kim, K. T., Kim, C., Reeves, S. D., & Allcock, H. R. (2000) · Macromolecules · doi:10.1021/ma992036l · Cited by 74 · see citing works

Lower Critical Solubility Temperature Study of Alkyl Ether Based Polyphosphazenes

Allcock, H. R., & Dudley, G. K. (1996) · Macromolecules · doi:10.1021/ma951129+ · Cited by 74 · see citing works

A Strategy to Design a Donor–π–Acceptor Polymeric Hole Conductor for an Efficient Perovskite Solar Cell

Kim, G., Kim, J., Lee, G., et al. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201500471 · Cited by 61 · see citing works

Influence of additives on thermoresponsive polymers in aqueous media: a case study of poly( N -isopropylacrylamide)

Umapathi, R., Reddy, P. M., Rani, A., & Venkatesu, P. (2018) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp08172c · Cited by 58 · see citing works

Synthesis and Self-Association Behavior of Biodegradable Amphiphilic Poly[bis(ethyl glycinat-N-yl)phosphazene]− Poly(ethylene oxide) Block Copolymers

Chang, Y., Bender, J. D., Phelps, M. V. B., & Allcock, H. R. (2002) · Biomacromolecules · doi:10.1021/bm020087b · Cited by 55 · see citing works

Amphiphilic Poly[bis(trifluoroethoxy)phosphazene]−Poly(ethylene oxide) Block Copolymers: Synthesis and Micellar Characteristics

Chang, Y., Prange, R., Allcock, H. R., Lee, S. C., & Kim, C. (2002) · Macromolecules · doi:10.1021/ma0206063 · Cited by 54 · see citing works

Dendrimers Derived from Polyphosphazene−Poly(propyleneimine) Systems: Encapsulation and Triggered Release of Hydrophobic Guest Molecules

Cho, S. Y., & Allcock, H. R. (2007) · Macromolecules · doi:10.1021/ma062582w · Cited by 52 · see citing works

DNA-induced chirality in water-soluble poly(cobaltoceniumethylene)

Qiu, H., Gilroy, J. B., & Manners, I. (2012) · Chemical Communications · doi:10.1039/c2cc37026c · Cited by 52 · see citing works

Biomimetic, bioactive etheric polyphosphazene‐poly(lactide‐co‐glycolide) blends for bone tissue engineering

Deng, M., Nair, L. S., Nukavarapu, S. P., Kumbar, S. G., Brown, J. L., Krogman, N. R., Weikel, A. L., Allcock, H. R., & Laurencin, C. T. (2009) · Journal of Biomedical Materials Research Part A · doi:10.1002/jbm.a.32334 · Cited by 49 · see citing works

Ultraviolet Photolithographic Development of Polyphosphazene Hydrogel Microstructures for Potential Use in Microarray Biosensors

Allcock, H. R., Phelps, M. V. B., Barrett, E. W., Pishko, M. V., & Koh, W. (2006) · Chemistry of Materials · doi:10.1021/cm050316b · Cited by 40 · see citing works

New Amphiphilic Poly[bis(2,2,2-trifluoroethoxy)phosphazene]/Poly(propylene glycol) Triblock Copolymers: Synthesis and Micellar Characteristics

Allcock, H. R., Cho, S. Y., & Steely, L. B. (2006) · Macromolecules · doi:10.1021/ma061531w · Cited by 39 · see citing works

Activity of urea amidohydrolase immobilized within poly[di(methoxyethoxyethoxy)phosphazene] hydrogels

Allcock, H. R., Pucher, S. R., & Visscher, K. B. (1994) · Biomaterials · doi:10.1016/0142-9612(94)90015-9 · Cited by 36 · see citing works

Ion and pH Effect on the Lower Critical Solution Temperature Phase Behavior in Neutral and Acidic Poly(organophosphazene) Counterparts

Ahn, S., Monge, E. C., & Song, S. (2009) · Langmuir · doi:10.1021/la802815u · Cited by 33 · see citing works

Preparation of Polyphosphazene Hydrogels for Enzyme Immobilization

Qian, Y., Chen, P., He, G., Huang, X., & Xu, Z. (2014) · Molecules · doi:10.3390/molecules19079850 · Cited by 29 · see citing works

The investigation of structural and thermosensitive properties of new phosphazene derivatives bearing glycol and amino acid

Uslu, A., & Güvenaltın, Ş. (2010) · Dalton Transactions · doi:10.1039/c0dt00818d · Cited by 27 · see citing works

Preparation of polymeric biomaterials with the aid of radiation-chemical methods

Кабанов, В. Я. (1998) · Russian Chemical Reviews · doi:10.1070/rc1998v067n09abeh000433 · Cited by 27 · see citing works

Controlling the gelation temperature of biomimetic polyisocyanides

Kouwer, P. H. J., de Almeida, P., den Boomen, O. V., et al. (2017) · Chinese Chemical Letters · doi:10.1016/j.cclet.2017.11.002 · Cited by 26 · see citing works

Structural and Thermosensitive Properties of Cyclotriphosphazenes with Poly(ethylene glycol) and Amino Acid Esters as Side Groups

Lee, S. B., Song, S., Jin, J., et al. (2001) · Macromolecules · doi:10.1021/ma010648b · Cited by 23 · see citing works

Click synthesis of ionic strength-responsive polyphosphazene hydrogel for reversible binding of enzymes

Qian, Y., Chen, P., Zhu, X., & Huang, X. (2015) · RSC Advances · doi:10.1039/c5ra06649b · Cited by 22 · see citing works

Thermoresponsive cyclodextrins with switchable inclusion abilities

Yan, J., Li, W., Zhang, X., et al. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33328g · Cited by 22 · see citing works

Sol–gel hybrid materials based on hydroxylatedpoly[bis(methoxy–ethoxy–ethoxy)phosphazene] and silica: a ceramic ionic conductor

Brusatin, G., Guglielmi, M., Jaeger, R. D., Facchin, G., Gleria, M., & Musiani, M. M. (1997) · Journal of Materials Science · doi:10.1023/a:1018640410763 · Cited by 21 · see citing works

Hydrolysis‐improved thermosensitive polyorganophosphazenes with α‐amino‐ω‐methoxy‐poly(ethylene glycol) and amino acid esters as side groups

Lee, S. B., & Song, S. (2005) · Polymer International · doi:10.1002/pi.1702 · Cited by 20 · see citing works

Photochemistry and photophysics of poly(organophosphazenes) and related compounds: A review. I. Monomolecular processes

Bortolus, P., & Gleria, M. (1994) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/bf00684025 · Cited by 20 · see citing works

Synthesis and hydrolytic properties of polyphosphazene/(diamine)platinum/saccharide conjugates

Song, S., & Sohn, Y. S. (1998) · Journal of Controlled Release · doi:10.1016/s0168-3659(98)00046-7 · Cited by 19 · see citing works

Synthesis of New Polyelectrolytes via Backbone Quaternization of Poly(aryloxy- and alkoxyphosphazenes) and their Small Molecule Counterparts

Chen, C., Hess, A., Jones, A. R., Liu, X., Barber, G. D., Mallouk, T. E., & Allcock, H. R. (2012) · Macromolecules · doi:10.1021/ma202619j · Cited by 18 · see citing works

Inorganic‐organic polymers as a route to biodegradable materials

Allcock, H. R. (1999) · Macromolecular Symposia · doi:10.1002/masy.19991440105 · Cited by 16 · see citing works

Synthesis and characterization of new biodegradable thermosensitive polyphosphazenes with lactic acid ester and methoxyethoxyethoxy side groups

Bi, Y. M., Gong, X. Y., Wang, W. Z., et al. (2009) · Chinese Chemical Letters · doi:10.1016/j.cclet.2009.10.003 · Cited by 15 · see citing works

Synthesis and Characterization of Covalently Interconnected Phosphazene−Silicate Hybrid Network Membranes

Chang, Y., & Allcock, H. R. (2005) · Chemistry of Materials · doi:10.1021/cm050122w · Cited by 12 · see citing works

Spectroscopic and Magnetic Resonance Elucidation of the Structure of the Polymer Derived from 1,2-Dihydro-4-(4-Hydroxyphenyl)-1-oxo-(2H)-Phthalazine and Bis(4-Fluorophenyl)Sulfone

Paventi, M., Chan, K. P., & Hay, A. S. (1996) · Journal of Macromolecular Science Part A · doi:10.1080/10601329608010859 · Cited by 12 · see citing works

Synthesis, characterization, in vitro degradation and cytotoxicity of polyphosphazenes containing N‐ethoxypyrrolidone side groups

Bi, Y., Yin, Y., Huang, R., & Li, Y. (2009) · Polymer International · doi:10.1002/pi.2720 · Cited by 12 · see citing works

Polyphosphazenes containing lactic acid ester and methoxyethoxyethoxy side groups — Thermosensitive properties and, in vitro degradation, and biocompatibility

Bi, Y., Gong, X., He, F., et al. (2011) · Canadian Journal of Chemistry · doi:10.1139/v11-102 · Cited by 11 · see citing works

Thermoresponsive Properties of Poly[oligo(ethylene glycol) sorbate]s Prepared by Organocatalyzed Group Transfer Polymerization

Liu, Y., Lei, Y., & Chen, Y. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00678 · Cited by 10 · see citing works

Thermosetting polymers from cationic copolymerization of tung oil: Synthesis and characterization

Li, F., & Larock, R. C. (2000) · Journal of Applied Polymer Science · doi:10.1002/1097-4628(20001031)78:5 · Cited by 135 · see citing works

Photochemical Behavior of Poly(Organophosphazenes). 15. Light-Induced Cross-Linking of [(4-Benzoylphenoxy) x (Methoxyethoxyethoxy)2 − x ] Phosphazene Copolymers

Minto, F., Gleria, M., Bertani, R., Noto, V. D., & VIDALI, M. (1998) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1023/a:1022411205861 · Cited by 9 · see citing works

Synthesis, characterization, hydrolytic degradation, mathematical modeling and antibacterial activity of poly[bis((methoxyethoxy)ethoxy)phosphazene] (MEEP)

Abid, M. A., Hussain, S., Intisar, A., Rizwan, M., Ain, Q. U., Mutahir, Z., Yar, M., Aamir, A., Qureshi, A. K., & Jamil, M. (2021) · Polymer Bulletin · doi:10.1007/s00289-021-03625-w · Cited by 7 · see citing works

Polymeric networks by the cationic crosslinking reaction of poly(allenyl ether)s having oligo(oxyethylene) moieties in the side chain

Aggour, Y. A., Tomita, I., & Endo, T. (1994) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.1994.080321023 · Cited by 8 · see citing works

Salt-Induced Thermoresponsivity of a Cationic Phosphazene Polymer in Aqueous Solutions

Burova, T. V., Grinberg, V. Y., Grinberg, N. V., Dubovik, A. S., Moskalets, A. P., Papkov, V. S., & Khokhlov, A. R. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01621 · Cited by 7 · see citing works

Phase separation in aqueous solutions of polyethylaminophosphazene hydrochloride during heating

Grinberg, V. Y., Grinberg, N. V., Burova, T. V., et al. (2010) · Polymer Science Series A · doi:10.1134/s0965545x10110167 · Cited by 6 · see citing works

Synthesis and Characterization of Thermosensitive Poly(organophosphazenes) with Methoxy-Poly(ethylene glycol) and Alkylamines as Side Groups

Lee, B. H. (2002) · Bulletin of the Korean Chemical Society · doi:10.5012/bkcs.2002.23.4.549 · Cited by 6 · see citing works

Recent Developments with an Impact on the Future of Polyphosphazene Science and Technology

Allcock, H. R. (1999) · Phosphorus, sulfur, and silicon and the related elements · doi:10.1080/10426509908546182 · Cited by 5 · see citing works

Hydration of crystalline polydimethylphosphazene

Meille, S. V., Farina, A., & Gallazzi, M. C. (1994) · Macromolecular Rapid Communications · doi:10.1002/marc.1994.030150701 · Cited by 5 · see citing works

Design and Synthesis of New Biomaterials via Macromolecular Substitutiona

Allcock, H. R. (1997) · Annals of the New York Academy of Sciences · doi:10.1111/j.1749-6632.1997.tb52181.x · Cited by 4 · see citing works

Nucleophilic cosubstitution of poly(dichlorophosphazene) with alkyl ether and amino acid ester

Zhang, T., Cai, Q., Wu, Z. P., Li, C. Q., & Jin, R. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20722 · Cited by 4 · see citing works

Physical properties of some organophosphazene copolymers. I. Structural aspects, transition temperatures, and stress-strain isotherms of the cross-linked networks

Sohoni, G. B., & Mark, J. E. (1993) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/bf00683958 · Cited by 3 · see citing works

Polyphosphazenes and the Process of Macromolecular Substitution

Allcock, H. R., & Chen, C. (2025) · ACS Polymers Au · doi:10.1021/acspolymersau.5c00082 · Cited by 2 · see citing works

Synthesis of Block Copolymers Based on N-alkyl Substituted Acrylamide via Combination of Reversible Addition-Fragmentation Transfer Polymerization and Click Chemistry

Liu, X., Feng, X., Chen, J., et al. (2012) · Journal of Macromolecular Science Part A · doi:10.1080/10601325.2013.735972 · Cited by 2 · see citing works

Binding Energetics of Charged Amphiphilic Ligands to Thermoresponsive Biodegradable Poly(methoxyethylaminophosphazene) Hydrogels

Grinberg, V. Y., Burova, T. V., Grinberg, N. V., et al. (2019) · Langmuir · doi:10.1021/acs.langmuir.9b03204 · Cited by 2 · see citing works

Quantitative analysis on swelling behavior of ionic gels in the mixed solvents

Park, O. O., Lee, W. S., Oh, Y. R., et al. (1994) · Korean Journal of Chemical Engineering · doi:10.1007/bf02697361 · Cited by 2 · see citing works

Synthesis of Synthetic Polymers

Allcock, H. R. (2002) · Elsevier eBooks · doi:10.1016/b978-012436636-7/50166-x · Cited by 2 · see citing works

Biodegradable Thermogelling Poly(Organophosphazenes) and Their Potential Biomedical Applications

Liu, X. (2014) · Series in bioengineering · doi:10.1007/978-981-287-152-7_3 · Cited by 1 · see citing works

Appendix: Harry R. Allcock Bibliography

Allcock, H. R. (2007) · Journal of Inorganic and Organometallic Polymers and Materials · doi:10.1007/s10904-006-9069-0

Stimuli-Responsive Polymers: Recent Advances in Thermosensitive Polymers with Well-Controlled Structures

Aoshima, S., Kanazawa, A., & Kanaoka, S. (2014) · Oleoscience · doi:10.5650/oleoscience.14.73

Polyphosphazenes: macromolecular structures, properties, and their methods of synthesis

Iturmendi, A., Henke, H., Pappas, G. S., & Teasdale, I. (2021) · Elsevier eBooks · doi:10.1016/b978-0-12-818429-5.00009-0

Thermally Responsive Materials

(2016) · Royal Society of Chemistry eBooks · doi:10.1039/bk9781849736565-00055

Gellan gum microgel-reinforced cell-laden gelatin hydrogels

Shin, H., Olsen, B. D., & Khademhosseini, A. (2013) · Journal of Materials Chemistry B · doi:10.1039/c3tb20984a · Cited by 59 · see citing works

Bioinspired double network hydrogels: from covalent double network hydrogels via hybrid double network hydrogels to physical double network hydrogels

Xu, X., Jerca, V. V., & Hoogenboom, R. (2020) · Materials Horizons · doi:10.1039/d0mh01514h · Cited by 536 · see citing works

Advanced Hydrogel Structures

Majcher, M. J., & Hoare, T. R. (2019) · Polymers and polymeric composites · doi:10.1007/978-3-319-95990-0_16 · Cited by 3 · see citing works

Advanced Hydrogel Structures

Majcher, M. J., & Hoare, T. R. (2018) · Polymers and polymeric composites · doi:10.1007/978-3-319-92066-5_16-1 · Cited by 3 · see citing works

Hydrogels and Biodegradable Polymers for Bioapplications

Ottenbrite, R. M., Huang2, S. J., & Park, K. (1996) · ACS symposium series · doi:10.1021/bk-1996-0627 · Cited by 198 · see citing works