Dynamics of structure formation in crystallizable block copolymers
Abstract
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTDynamics of Structure Formation in Crystallizable Block CopolymersPratima Rangarajan, Richard A. Register, Douglas H. Adamson, Lewis J. Fetters, Wim Bras, Steven Naylor, and Anthony J. RyanCite this: Macromolecules 1995, 28, 5, 1422–1428Publication Date (Print):February 1, 1995Publication History Published online1 May 2002Published inissue 1 February 1995https://pubs.acs.org/doi/10.1021/ma00109a013https://doi.org/10.1021/ma00109a013research-articleACS PublicationsRequest reuse permissionsArticle Views713Altmetric-Citations154LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose Get e-Alerts
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In medium segregated systems (medium χN values, T_ODT > Tc > Tg), the final morphology depends on the applied thermal procedure: if the sample is cooled from the melt very fast (quenching), the morphology of the melt is maintained; otherwise, the final morphology is governed by the crystallization process.
“For these block copolymers the final morphology (i.e., the morphology of the solidified sample) depends on the applied thermal procedure: if the sample is cooled from the melt very fast, i.e., quenching, the morphology of the melt is maintained. Otherwise, the final morphology will be governed by the crystallization process [ 102 , 103 , 150-153 , 160-164 , 172 , 173 ].”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [151]
In weakly segregated systems (low χN values, T_ODT > Tc > Tg), there is little morphological restriction for crystallization, allowing a break out from the ordered melt structure, so crystallization determines the final structure, usually forming crystalline lamellae and erasing the previous melt structure.
“In this case, there is little morphological restriction for the crystallization process, which allows a break out from the ordered melt structure, therefore the crystallization determines the final structure, usually crystalline lamellae are formed, erasing the previous structure of the melt [ 102 , 103 , 109 , 121 , 125 , 150-153 , 160-171 ].”
From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [151]
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- Authors
- Rangarajan, P., Register, R. A., Adamson, D. H., Fetters, L. J., Bras, W., Naylor, S., & Ryan, A. J.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1995-02
- Volume
- 28
- Issue
- 5
- Pages
- 1422-1428
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2020630395
- Cited by
- 164
- References
- 0
- Citations by year
- 2026: 3 · 2025: 5 · 2024: 3 · 2023: 1 · 2022: 2 · 2021: 7 · 2020: 2 · 2019: 3 · 2018: 1 · 2017: 3 · 2016: 3 · 2015: 6 · 2014: 7 · 2013: 5 · 2012: 7
- FWCI
- 8.31
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecules (publishedVersion)
- Funders
- Division of Materials Research
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Keywords
- block copolymers, crystallization, structure formation, microphase separation, polymer dynamics, lamellar phase, block copolymer blends
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