CoChat
Sign Up
Cited by 31Polymer crystallization and propertiesBlock Copolymer Self-AssemblyAdvanced Polymer Synthesis and Characterization

Crystallization Kinetics of PEO and PE in Different Triblock Terpolymers: Effect of Microdomain Geometry and Confinement

Open access
Boschetti‐de‐Fierro, Adriana, Lorenzo, Arnaldo T., Müller, Alejandro J., Schmalz, Holger, Abetz, Volker·2008·Macromolecular Chemistry and Physics
DOI 10.1002/macp.200700434
Open this paper in CoChat — free accountOpen PDF

Abstract

Abstract The isothermal crystallization kinetics of PEO and PE blocks within various triblock terpolymers were studied by DSC. The effect of the geometry of the microdomains was analyzed by studying different compositions of PE‐b‐PS‐b‐PEO triblock terpolymers. The crystallization rate decreased for decreasing block content for both crystallizable blocks. The effect of the microdomain geometry, confinement or chain tethering on the crystallization of PEO was extensively studied by comparing pairs of triblock terpolymers with differences either in the nature (crystalline, glassy, amorphous) or in the location of the other blocks in the terpolymer. magnified image

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Integrity signals

Registry

Crossref · 10.1002/macp.200700434

Cites

71 of 71 references verified0 citation errors · 0 not checkable

Statistics

Claims the paper makes

The claims and statistics of this paper haven’t been checked yet.

Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.

A few free checks a day · papers already verified open instantly · results are public

Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • For ABC triblocks, the composition of the terpolymer, the melt segregation strength (influenced by three interaction parameters), and the block sequence (ABC, BCA or ACB) are important in addition to the previously mentioned transition temperatures.

    “Regarding ABC triblocks, the composition of the terpolymer, the melt segregation strength, which is influenced by three interaction parameters, and the block sequence [ 38 , 217 ], i.e., ABC, BCA or ACB, will be important in addition to the previously mentioned transition temperatures.”

    From Fractionated crystallization in semicrystalline polymers (2021) · cites this paper as [217]

    The Results and Discussion section identifies composition-related morphology and block sequence as parameters relevant to these triblock terpolymers; the Introduction also links segregation and morphology to interactions among blocks and transition temperatures. But our copy does not specify three interaction parameters or identify ABC, BCA and ACB as the block sequences. Page numbers are not available in the indexed passages. (LLM, conf=0.85)

    Experimental — accuracy not yet measured

Self-check

Percentages, sums and reported differences re-computed from the paper’s own numbers.

The self-check needs the paper’s full text.

Cites

Flagged first, then by citations

Research works printed but not linked: 68

  1. H.-L. Chen, S.-C. Hsiao, T.-L. Lin, K. Yamauchi, H. Hasegawa, T. Hashimoto, Macromolecules 2001, 34, 671;
  2. L. Li, Y. Serero, M. H. J. Koch, W. H. de Jeu, Macromolecules 2003, 36, 529.
  3. L. Zhu, H.-L. Chen, B. H. Calhoun, Q. Ge, R. P. Quirk, E. L. Thomas, B. S. Hsiao, F. Yeh, B. Lotz, Polymer 2001, 42, 5829.
  4. H. Schmalz, A. J. Mu ¨ller, V. Abetz, Macromol. Chem. Phys. 2003, 204, 111.
  5. L. Sun, Y. Lui, L. Zhu, B. S. Hsiao, C. A. Avila-Orta, Polymer 2004, 2004, 8181.
  6. A. J. Mu ¨ller, V. Balsamo, M. L. Arnal, Adv. Polym. Sci. 2005, 190, 1.
  7. H. Schmalz, A. Bo ¨ker, R. Lange, G. Krausch, V. Abetz, Macro- molecules 2001, 34, 8720.
  8. V. Balsamo, N. Urdaneta, L. Pe ´rez, P. Carrizales, V. Abetz, A. J. Mu ¨ller, Eur. Polym. J. 2004, 40, 1033.
  9. A. J. Mu ¨ller, V. Balsamo, M. L. Arnal, in: Lecture Notes in Physics: Progress in Understanding of Polymer Crystallization, G. Reiter, G. Strobl, Eds., Springer, Berlin 2007, p. 229.
  10. I. W. Hamley, J. P. A. Fairclough, F. S. Bates, A. J. Ryan, Polymer 1998, 39, 1429;
  11. A. J. Ryan, I. W. Hamley, W. Bras, F. S. Bates, Macromol- ecules 1995, 28, 3860;
  12. I. W. Hamley, Adv. Polym. Sci. 1999, 148, 113;
  13. G. Floudas, B. Vazaiou, F. Schipper, R. Ulrich, U. Wiesner, H. Iatrou, N. Hadjichristidis, Macromol- ecules 2001, 34, 2947.
  14. Y-. L. Loo, R. A. Register, A. J. Ryan, G. T. Dee, Macromolecules 2001, 34, 8968.
  15. Y.-L. Loo, R. A. Register, A. J. Ryan, Macromolecules 2002, 35, 2365.
  16. A. J. Mu ¨ller, V. Balsamo, M. L. Arnal, T. Jakob, H. Schmalz, V. Abetz, Macromolecules 2002, 35, 3048.
  17. P. Rangarajan, R. A. Register, D. H. Adamson, L. J. Fetters, W. Bras, S. Naylor, A. J. Ryan, Macromolecules 1995, 28, 1422.
  18. F. S. F. Bates, H. Glenn, Phys. Today 1999, 52, 32.
  19. R. E. Cohen, P.-L. Cheng, K. Douzinas, P. Kofinas, C. V. Berney, Macromolecules 1990, 23, 324;
  20. R. Se ´gue ´la, J. Prud'homme, Polymer 1989, 30, 1446.
  21. L. Sun, L. Zhu, Q. Ge, R. P. Quirk, C. Xue, S. Z. D. Cheng, B. S. Hsiao, C. A. Avila-Orta, I. Sics, M. E. Cantino, Polymer 2004, 45, 2931;
  22. L. Zhu, S. Z. D. Cheng, P. Huang, Q. Ge, R. P. Quirk, E. L. Thomas, B. Lotz, B. S. Hsiao, F. Yeh, L. Liu, Adv. Mater. 2002, 14, 31;
  23. L. Zhu, B. R. Mimnaugh, Q. Ge, R. P. Quirk, S. Z. D. Cheng, E. L. Thomas, B. Lotz, B. S. Hsiao, F. Yeh, L. Liu, Polymer 2001, 42, 9121.
  24. B. Heck, T. Hugel, M. Iijima, G. Strobl, Polymer 2000, 41, 8839;
  25. M. Muthukumar, P. Welch, Polymer 2000, 41, 8833;
  26. M. Muthukumar, Eur. Phys. J. E 2000, 3, 199.
  27. H. Schmalz, V. Abetz, R. Lange, M. Soliman, Macromolecules 2001, 34, 795.
  28. B. Esswein, M. Mo ¨ller, Angew. Chem. 1996, 108, 703;
  29. B. Esswein, N. M. Steidl, M. Mo ¨ller, Macromol. Rapid Commun. 1996, 17, 143;
  30. G. Floudas, B. Vazaiou, F. Schipper, R. Ulrich, U. Wiesner, H. Iatrou, N. Hadjichristidis, Macromolecules 2001, 34, 2947;
  31. S. Fo ¨rster, E. Kra ¨mer, Macromolecules 1999, 32, 2783.
  32. M. J. Galante, L. Mandelkern, R. G. Alamo, A. Lehtinen, R. Paukkeri, J. Therm. Anal. Calorim. 1996, 47, 913.
  33. B. Fillon, J. C. Wittmann, B. Lotz, A. Thierry, J. Polym. Sci., Part B: Polym. Phys. 1993, 31, 1383.
  34. A. Boschetti-de-Fierro, A. J. Mu ¨ller, V. Abetz, Macromolecules 2007, 40, 1290.
  35. A. T. Lorenzo, M. L. Arnal, J. Albuerne, A. J. Mu ¨ller, Polym. Test. 2007, 26, 222.
  36. M. Avrami, J. Chem. Phys. 1939, 7, 1103;
  37. M. Avrami, J. Chem. Phys. 1940, 8, 212.
  38. M. Avrami, J. Chem. Phys. 1941, 9, 177.
  39. E. Piorkowska, A. Galeski, J.-M. Haudin, Prog. Polym. Sci. 2006, 31, 549.
  40. A. J. Mu ¨ller, J. Albuerne, L. M. Esteves, L. Marquez, J.-M. Raquez, P. Dege ´e, P. Dubois, S. Collins, I. W. Hamley, Macromol. Symp. 2004, 215, 369;
  41. H.-L. Chen, S.-Y. Lin, Y.-Y. Huang, F.-C. Chiu, W. Liou, J. S. Lin, Macromolecules 2002, 35, 9434;
  42. I. W. Hamley, V. Castelletto, R. V. Castillo, A. J. Mu ¨ller, C. M. Martin, E. Pollet, P. Dubois, Macromolecules 2005, 38, 463;
  43. U. Jeong, H. H. Lee, H. Yang, J. K. Kim, S. Okamoto, S. Aida, S. Sakurai, Macromolecules 2003, 36, 1685;
  44. L. Sun, L. Zhu, Q. Ge, R. P. Quirk, C. Xue, S. Z. D. Cheng, B. S. Hsiao, C. A. Avila-Orta, I. Sics, M. E. Cantino, Polymer 2004, 45, 2931;
  45. G. Floudas, C. Tsitsilianis, Macro- molecules 1997, 30, 4381;
  46. I. Alig, S. Tadjbakhsch, G. Floudas, C. Tsitsilianis, Macromolecules 1998, 31, 6917;
  47. H. Takeshita, N. Ishii, C. Araki, M. Miya, K. Takenaka, T. Shiomi, J. Polym. Sci., Part B: Polym. Phys. 2004, 42, 4199;
  48. I. W. Hamley, P. Parras, V. Castelletto, R. V. Castillo, A. J. Mu ¨ller, E. Pollet, P. Dubois, C. M. Martin, Macromol. Chem. Phys. 2006, 207, 941.
  49. J. Albuerne, L. Ma ´rquez, A. J. Mu ¨ller, J. M. Raquez, P. Dege ´e, P. Dubois, V. Castelletto, I. W. Hamley, Macromolecules 2003, 36, 1633.
  50. H.-L. Chen, J.-C. Wu, T.-L. Lin, J. S. Lin, Macromolecules 2001, 34, 6936.
  51. R.-M. Ho, Y.-W. Chiang, C.-C. Lin, B.-H. Huang, Macromolecules 2005, 38, 4769.
  52. T. Shiomi, H. Takeshita, H. Kawaguchi, M. Nagai, K. Takenaka, M. Miya, Macromolecules 2002, 35, 8056.
  53. E. Piorkowska, A. Galeski, J. Phys. Chem. 1985, 89, 4700;
  54. J. Appl. Polym. Sci. 2002, 86, 1363; [33c
  55. J. Macromol. Sci., Part B: Phys. 2003, 42, 773.
  56. Y.-L. Loo, R. A. Register, A. J. Ryan, Phys. Rev. Lett. 2000, 84, 4120 LP.
  57. D. Turnbull, R. L. Cormia, J. Chem. Phys. 1961, 34, 820;
  58. R. L. Cormia, F. P. Price, D. Turnbull, J. Chem. Phys. 1962, 37, 1333.
  59. A. Boschetti-de-Fierro, L. Spindler, G. Reiter, D. Olmos, S. Magonov, V. Abetz, Macromolecules 2007, 40, 5487.
  60. R. Opitz, D. M. Lambreva, W. H. de Jeu, Macromolecules 2002, 35, 6930.
  61. X. Zhang, Z. Wang, X. Dong, D. Wang, C. C. Han, J. Chem. Phys. 2006, 125, 024907.
  62. H. Schmalz, A. Knoll, A. J. Mu ¨ller, V. Abetz, Macromolecules 2002, 35, 10004.
  63. A. J. Mu ¨ller, J. Albuerne, L. Ma ´rquez, J.-M. Raquez, P. Dege ´e, P. Dubois, J. Hobbs, I. W. Hamley, Faraday Discuss. 2005, 128, 231.
  64. M. Ueda, K. Sakurai, S. Okamoto, D. J. Lohse, W. J. MacKnight, S. Shinkai, S. Sakurai, S. Nomura, Polymer 2003, 44, 6995.
  65. T. H. Epps, T. S. Bailey, R. Waletzko, F. S. Bates, Macromolecules 2003, 36, 2873.
  66. A. T. Lorenzo, M. L. Arnal, A. J. Mu ¨ller, A. Boschetti-de-Fierro, V. Abetz, Macromolecules 2007, 40, 5023.
  67. P. A. Weimann, D. A. Hajduk, C. Chu, K. A. Chaffin, J. C. Brodil, F. S. Bates, J. Polym. Sci., Part B: Polym. Phys. 1999, 37, 2045.
  68. A. Boschetti-de-Fierro, D. Fierro, J. Albuerne, S. S. Funari, V. Abetz, J. Polym. Sci., Part B: Polym. Phys. 2007, 45, 3197.

Cited by

Sorted by citations

Related

Authors
Boschetti‐de‐Fierro, A., Lorenzo, A. T., Müller, A. J., Schmalz, H., & Abetz, V.
Affiliations
  • Universidad Simón Bolívar (VE)
  • University of Bayreuth (DE)
Corresponding author
Abetz, Volker
ORCID
Venue
Macromolecular Chemistry and Physics
Publisher
Wiley
Published
2008-03-03
Volume
209
Issue
5
Pages
476-487
ISSN
  • 1022-1352 (ISSN-L)
  • 1521-3935
DOI
10.1002/macp.200700434
OpenAlex
W2055302271
Cited by
31
References
71
Citations by year
2024: 1 · 2023: 1 · 2021: 3 · 2020: 2 · 2017: 2 · 2016: 1 · 2015: 3 · 2014: 5 · 2013: 2 · 2012: 2
FWCI
1.55
Type
journal article
Language
en
Open access
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor)
Locations
  • Macromolecular Chemistry and Physics (publishedVersion)
  • Helmholtz-Zentrum Geesthacht Zentrum für Materialforschung und kustenforschung (The Helmholtz Center Geesthacht) (submittedVersion)
Funders
Deutsche Forschungsgemeinschaft
Topics
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
  • Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
Keywords
crystallization kinetics, poly(ethylene oxide), polyethylene, triblock terpolymers, confinement, block copolymers, isothermal crystallization

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

Are you an author, or do you see a problem with this page? Request a review