The DOI matches its Crossref record; 35 of the 35 references it cites were found in a registry or an index.
Functionalization of Surfaces by Water-Accelerated Atom-Transfer Radical Polymerization of Hydroxyethyl Methacrylate and Subsequent Derivatization
Abstract
We report the synthesis of unusually thick poly(2-hydroxyethyl methacrylate) (PHEMA) films on gold surfaces by surface-initiated atom transfer radical polymerization (ATRP). Polymerization from the surface occurs rapidly at room temperature in aqueous media, resulting in the formation of 700 nm thick polymer films in just 12 h. Control experiments using neat monomer and catalyst (no water) yield films with thicknesses of only 6 nm, demonstrating the accelerating effect of water on surface-initiated ATRP. Kinetic studies reveal a nearly linear increase in thickness with reaction time, indicating that chain growth from the surface is a controlled process with some “living” character. A second block can be grown from dormant initiators at the end of PHEMA chains, providing further evidence of “living” chain ends. Derivatization of the hydroxyl groups of grafted PHEMA with a variety of molecules allows dense functionalization of these films. Reflectance FTIR spectroscopy shows a virtually quantitative yield in derivatization reactions, and the increase in film thickness after surface derivatization correlates with the molecular mass of the newly formed repeat unit.
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Cites
Formation and Structure of Self-Assembled Monolayers
Ulman, A. (1996) · Chemical Reviews · doi:10.1021/cr9502357 · Cited by 7,906
Polymer brushes: surface-immobilized macromolecules
Zhao, B., & Brittain, W. J. (2000) · Progress in Polymer Science · doi:10.1016/s0079-6700(00)00012-5 · Cited by 1,628
Tethered chains in polymer microstructures
Halperin, A., Tirrell, M., & Lodge, T. P. (2006) · Advances in Polymer Science · doi:10.1007/bfb0051635 · Cited by 1,139
Controlled Synthesis of Polymer Brushes by “Living” Free Radical Polymerization Techniques
Husseman, M., Malmström, E. E., McNamara, M., Mate, M., Mecerreyes, D., Benoit, D. G., Hedrick, J. L., Mansky, P., Huang, E., Russell, T. P., et al. (1999) · Macromolecules · doi:10.1021/ma981290v · Cited by 927
Matyjaszewski, K., Miller, P. J., Shukla, N., Immaraporn, B., Gelman, A., Luokala, B. B., Siclovan, T. M., Kickelbick, G., Vallant, T., Hoffmann, H., et al. (1999) · Macromolecules · doi:10.1021/ma991146p · Cited by 919
Löfås, S., & Johnsson, B. (1990) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39900001526 · Cited by 766
Prucker, O., & Rühe, J. (1998) · Macromolecules · doi:10.1021/ma970660x · Cited by 641
Ejaz, M., Yamamoto, S., Ohno, K., Tsujii, Y., & Fukuda, T. (1998) · Macromolecules · doi:10.1021/ma980240n · Cited by 565
New Methods of Preparative Organic Chmistry IV. Syntheses Using Heterocyclic Amides (Azolides)
Staab, H. A. (1962) · Angewandte Chemie International Edition in English · doi:10.1002/anie.196203511 · Cited by 487
Surface-Initiated Anionic Polymerization of Styrene by Means of Self-Assembled Monolayers
Jordan, R., Ulman, A., Kang, J. F., Rafailovich, M. H., & Sokolov, J. (1999) · Journal of the American Chemical Society · doi:10.1021/ja981348l · Cited by 388
Shah, R. R., Merreceyes, D., Husemann, M., Rees, I., Abbott, N. L., Hawker, C. J., & Hedrick, J. L. (2000) · Macromolecules · doi:10.1021/ma991264c · Cited by 358
Utilizing Halide Exchange To Improve Control of Atom Transfer Radical Polymerization
Matyjaszewski, K., Shipp, D. A., Wang, J.-L., Grimaud, T., & Patten, T. E. (1998) · Macromolecules · doi:10.1021/ma980476r · Cited by 352
Surface Initiated Living Cationic Polymerization of 2-Oxazolines
Jordan, R., & Ulman, A. (1998) · Journal of the American Chemical Society · doi:10.1021/ja973392r · Cited by 343
Atom Transfer Radical Polymerization of 2-Hydroxyethyl Methacrylate
Beers, K. L., Boo, S., Gaynor, S. G., & Matyjaszewski, K. (1999) · Macromolecules · doi:10.1021/ma990176p · Cited by 288
Controlled Surface-Initiated Polymerizations in Aqueous Media
Jones, D. M., & Huck, W. T. S. (2001) · Advanced Materials · doi:10.1002/1521-4095(200108)13:16<1256::aid-adma1256>3.0.co;2-b · Cited by 272
Ring-Opening Metathesis Polymerization from Surfaces
Weck, M., Jackiw, J. J., Rossi, R. R., Weiss, P. S., & Grubbs, R. H. (1999) · Journal of the American Chemical Society · doi:10.1021/ja983297y · Cited by 268
Controlled Polymerization of 2-Hydroxyethyl Methacrylate by ATRP at Ambient Temperature
Robinson, K. L., Khan, M. A., de Paz Báñez, M. V., Wang, X. S., & Armes, S. P. (2001) · Macromolecules · doi:10.1021/ma0019611 · Cited by 266
Surface-Initiated Atom Transfer Radical Polymerization on Gold at Ambient Temperature
Kim, J.-B., Bruening, M. L., & Baker, G. L. (2000) · Journal of the American Chemical Society · doi:10.1021/ja001652q · Cited by 265
Self-citationPhysics of Polymer Surfaces and Interfaces
(1992) · Elsevier eBooks · doi:10.1016/c2009-0-26081-8 · Cited by 250
Zhao, B., & Brittain, W. J. (1999) · Journal of the American Chemical Society · doi:10.1021/ja984428y · Cited by 222
“Living” Free Radical Photopolymerization Initiated from Surface-Grafted Iniferter Monolayers
de Boer, B., Simon, H. K., Werts, M. P. L., van der Vegte, E. W., & Hadziioannou, G. (2000) · Macromolecules · doi:10.1021/ma9910944 · Cited by 213
Controlled/“Living” Radical Polymerization of 2-(Dimethylamino)ethyl Methacrylate
Zhang, X., Xia, J., & Matyjaszewski, K. (1998) · Macromolecules · doi:10.1021/ma980477j · Cited by 211
Surface-Initiated Radical Polymerization on Porous Silica
Huang, X., & Wirth, M. J. (1997) · Analytical Chemistry · doi:10.1021/ac9704523 · Cited by 195
Wang, X.-S., Lascelles, S. F., Jackson, R. A., & Armes, S. P. (1999) · Chemical Communications · doi:10.1039/a904691g · Cited by 194
Huang, X., & Wirth, M. J. (1999) · Macromolecules · doi:10.1021/ma981304x · Cited by 187
Zhao, B., & Brittain, W. J. (2000) · Macromolecules · doi:10.1021/ma000433m · Cited by 155
Surface Functionalization and Imaging Using Monolayers and Surface-Grafted Polymer Layers
Ingall, M. D. K., Honeyman, C. H., Mercure, J. V., Bianconi, P. A., & Kunz, R. R. (1999) · Journal of the American Chemical Society · doi:10.1021/ja9833927 · Cited by 146
Surface-Initiated Ring-Opening Metathesis Polymerization on Si/SiO2
Kim, N. Y., Jeon, N. L., Choi, I. S., Takami, S., Harada, Y., Finnie, K. R., Girolami, G. S., Nuzzo, R. G., Whitesides, G. M., & Laibinis, P. E. (2000) · Macromolecules · doi:10.1021/ma000046c · Cited by 146
Surface-Confined Living Radical Polymerization for Coatings in Capillary Electrophoresis
Huang, X., Doneski, L. J., & Wirth, M. J. (1998) · Analytical Chemistry · doi:10.1021/ac980231c · Cited by 137
Bruening, M. L., Zhou, Y., Aguilar, G., Agee, R., Bergbreiter, D. E., & Crooks, R. M. (1997) · Langmuir · doi:10.1021/la961098r · Cited by 133
Self-citationSedjo, R. A., Mirous, B. K., & Brittain, W. J. (2000) · Macromolecules · doi:10.1021/ma991549p · Cited by 123
Preparation of Hyperbranched Polymer Films Grafted on Self-Assembled Monolayers
Zhou, Y., Bruening, M. L., Bergbreiter, D. E., Crooks, R. M., & Wells, M. (1996) · Journal of the American Chemical Society · doi:10.1021/ja960142m · Cited by 116
Self-citationZhao, B., & Brittain, W. J. (1999) · Macromolecules · doi:10.1021/ma9910181 · Cited by 114
Huang, W., Baker, G. L., & Bruening, M. L. (2001) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20010417)40:8<1510::aid-anie1510>3.0.co;2-u · Cited by 94
Self-citationMori, H., Wakisaka, O., Hirao, A., & Nakahama, S. (1994) · Macromolecular Chemistry and Physics · doi:10.1002/macp.1994.021950918 · Cited by 73
Cited by
Barbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Metadata
- Authors
- Huang, W., Kim, J.-B., Bruening, M. L., & Baker, G. L.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-01-10
- Volume
- 35
- Issue
- 4
- Pages
- 1175-1179
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W1972569526
- Cited by
- 276
- References
- 35
- FWCI
- 12.22
- Type
- journal article
- Language
- en
- Open access
- closed
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