The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization
Abstract
A novel procedure was developed for activation of an oxidatively stable catalyst complex added to an atom transfer radical polymerization (ATRP). Tin(II) 2-ethylhexanoate (Sn(EH) 2 ) was used as a reducing agent of various Cu(II) complexes in ATRP of various monomers initiated by alkyl halides. This approach further improves a simultaneous normal and reverse initiation (SR&NI) by eliminating free radical initiators for the activation of the higher oxidation state catalyst complex. As a result, “activator generated by electron transfer” (AGET) ATRP allows the preparation of pure block copolymers. Several combinations of monomer/catalyst complex precursor were studied, including styrene/CuCl 2 /dNbpy, octadecyl methacrylate/CuCl 2 /dNbipy, methyl methacrylate/CuCl 2 /PMDETA, n -butyl acrylate/CuBr 2 /PMDETA, and methyl acrylate/CuCl 2 /Me 6 TREN. Polymerization proceeded in a controlled way for all systems, producing well-defined polymers with controlled degree of polymerization and narrow molecular weight distribution, demonstrating the robust nature of AGET ATRP. Additionally, Sn(EH) 2 was used simultaneously as a reducing agent for ATRP of octadecyl methacrylate and a catalyst for ring-opening polymerization (ROP) of ε-caprolactone, allowing direct synthesis of the corresponding block copolymer.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Atom Transfer Radical Polymerization
Matyjaszewski, K., & Xia, J. (2001) · Chemical Reviews · doi:10.1021/cr940534g · Cited by 7,654
Self-citationMetal-Catalyzed Living Radical Polymerization
Kamigaito, M., Ando, T., & Sawamoto, M. (2001) · Chemical Reviews · doi:10.1021/cr9901182 · Cited by 3,275
Handbook of Radical Polymerization
(2002) · Wiley eBooks · doi:10.1002/0471220450 · Cited by 1,595
Polymers with Complex Architecture by Living Anionic Polymerization
Hadjichristidis, N., Pitsikalis, M., Pispas, S., & Iatrou, H. (2001) · Chemical Reviews · doi:10.1021/cr9901337 · Cited by 1,330
Kinetics of living radical polymerization
Goto, A., & Fukuda, T. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.01.002 · Cited by 914
Matyjaszewski, K., Patten, T. E., & Xia, J. (1997) · Journal of the American Chemical Society · doi:10.1021/ja963361g · Cited by 891
Self-citationSynthesis of Polymer Brushes Using Atom Transfer Radical Polymerization
Pyun, J., Kowalewski, T., & Matyjaszewski, K. (2003) · Macromolecular Rapid Communications · doi:10.1002/marc.200300078 · Cited by 686
Self-citationApplication of ionic liquids as solvents for polymerization processes
Kubisa, P. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2003.10.002 · Cited by 609
Adaptive and responsive surfaces through controlled reorganization of interfacial polymer layers
Luzinov, I., Minko, S., & Tsukruk, V. V. (2004) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2004.03.001 · Cited by 556
The Synthesis of Densely Grafted Copolymers by Atom Transfer Radical Polymerization
Beers, K. L., Gaynor, S. G., Matyjaszewski, K., Sheiko, S. S., & Möller, M. (1998) · Macromolecules · doi:10.1021/ma981402i · Cited by 550
Self-citation
Cited by
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Self-citationBarbey, R., Lavanant, L., Paripovic, D., Schüwer, N., Sugnaux, C., Tugulu, S., & Klok, H.-A. (2009) · Chemical Reviews · doi:10.1021/cr900045a · Cited by 1,753
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Marrying click chemistry with polymerization: expanding the scope of polymeric materials
Golas, P. L., & Matyjaszewski, K. (2010) · Chem. Soc. Rev. · doi:10.1039/b901978m · Cited by 863
Self-citationAtrp in the design of functional materials for biomedical applications
Siegwart, D. J., Oh, J. K., & Matyjaszewski, K. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.001 · Cited by 613
Self-citation
Metadata
- Authors
- Jakubowski, W., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-04-21
- Volume
- 38
- Issue
- 10
- Pages
- 4139-4146
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2030714364
- Cited by
- 555
- References
- 23
- FWCI
- 14.69
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization. https://app.cochat.ai/papers/10.1021/ma047389l
- The paper
- Jakubowski, W., & Matyjaszewski, K. (2005). Activator Generated by Electron Transfer for Atom Transfer Radical Polymerization. Macromolecules. https://doi.org/10.1021/ma047389l
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
