The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
One-Pot Hyperbranched Polymer Synthesis Mediated by Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization
Abstract
Reversible addition fragmentation chain transfer (RAFT) polymerization was used for the first time to produce poly(methyl methacrylate) hyperbranched polymers via the one-pot copolymerization of methyl methacrylate (MMA) and ethylene glycol dimethacrylate, mediated by 2-(2-cyanopropyl) dithiobenzoate. Hyperbranched structures were characterized by 1 H NMR spectroscopy, size exclusion chromatography (SEC), and thermal analyses. Monomer conversions and molecular weight distributions of hyperbranched poly(methyl methacrylate) (PMMA) prepared via RAFT polymerization are much higher and much lower, respectively, than those of the analogous polymers prepared via other living polymerization systems. Furthermore, the living character of the RAFT process was used to polymerize styrene from hyperbranched PMMA precursors (macro chain-transfer agent, macroCTA) and to produce starlike structures with hyperbranched PMMA as the core and polystyrene as the arms. DSC and SEC analyses support the observations made regarding the production of these novel architectures.
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Cites
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Scanning Interferometric Apertureless Microscopy: Optical Imaging at 10 Angstrom Resolution
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Facile, versatile and cost effective route to branched vinyl polymers
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An approach to hyperbranched polymers with a degree of branching of 100%
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Cited by
Design and Preparation of Porous Polymers
Wu, D., Xu, F., Sun, B., Fu, R., He, H., & Matyjaszewski, K. (2012) · Chemical Reviews · doi:10.1021/cr200440z · Cited by 1,748
Bioapplications of RAFT Polymerization
Boyer, C., Bulmus, V., Davis, T. P., Ladmiral, V., Liu, J., & Perrier, S. (2009) · Chemical Reviews · doi:10.1021/cr9001403 · Cited by 1,015
Self-citationGao, H., & Matyjaszewski, K. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2009.01.001 · Cited by 799
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Architecture-transformable polymers: Reshaping the future of stimuli-responsive polymers
Sun, H., Kabb, C. P., Sims, M. B., & Sumerlin, B. S. (2019) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.09.006 · Cited by 300
Metadata
- Authors
- Liu, B., Kazlauciunas, A., Guthrie, J. T., & Perrier, S.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-02-12
- Volume
- 38
- Issue
- 6
- Pages
- 2131-2136
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2024040838
- Cited by
- 276
- References
- 5
- FWCI
- 8.34
- Type
- journal article
- Language
- en
- Open access
- closed
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