The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Thio-Click Modification of Poly[2-(3-butenyl)-2-oxazoline]
Abstract
The radical addition of mercaptans (RSH) onto poly[2-(3-butenyl)-2-oxazoline], which is available through a living/controlled cationic isomerization polymerization, can proceed smoothly in the absence of side reactions, exhibiting the characteristics of a click reaction. The “thio-click” reaction can be performed under feasible ([RSH]/[C C] ∼ 1.2−1.5, no transition metal additives) and mild conditions (generation of radicals with UV light at room temperature) and goes to completion within a day. Hydrophobic fluoropolymers can be prepared in the same way as water-soluble (co-)polymers or glycopolymers, starting from readily available materials.
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Citations
Cites
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The dawning era of polymer therapeutics
Duncan, R. (2003) · Nature Reviews Drug Discovery · doi:10.1038/nrd1088 · Cited by 3,269
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Nucleophilic Catalysis of Oxime Ligation
Dirksen, A., Hackeng, T. M., & Dawson, P. E. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200602877 · Cited by 488
Anthracene−Maleimide-Based Diels−Alder “Click Chemistry” as a Novel Route to Graft Copolymers
Gacal, B., Durmaz, H., Tasdelen, M. A., Hizal, G., Tunca, U., Yagci, Y., & Demirel, A. L. (2006) · Macromolecules · doi:10.1021/ma060690c · Cited by 298
Click Chemistry with Poly(2-oxazoline)s
Luxenhofer, R., & Jordan, R. (2006) · Macromolecules · doi:10.1021/ma052515m · Cited by 188
Toward a toolbox of functional block copolymers via free-radical addition of mercaptans
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Self-citationReaction of Alkene–Zirconocene Complexes and Cyclic Enol Ethers through New Reaction Pathways
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Cited by
Thiol-click chemistry: a multifaceted toolbox for small molecule and polymer synthesis
Hoyle, C. E., Lowe, A. B., & Bowman, C. N. (2010) · Chemical Society Reviews · doi:10.1039/b901979k · Cited by 1,639
Thiol-ene “click” reactions and recent applications in polymer and materials synthesis
Lowe, A. B. (2010) · Polym. Chem. · doi:10.1039/b9py00216b · Cited by 1,563
The power of thiol‐ene chemistry
Kade, M. J., Burke, D. J., & Hawker, C. J. (2010) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.23824 · Cited by 853
Designing degradable hydrogels for orthogonal control of cell microenvironments
Kharkar, P. M., Kiick, K. L., & Kloxin, A. M. (2013) · Chem. Soc. Rev. · doi:10.1039/c3cs60040h · Cited by 717
Poly (2-oxazoline) s as polymer therapeutics
Luxenhofer, R., Han, Y., Schulz, A., Tong, J., He, Z., Kabanov, A. V., & Jordan, R. (2012) · Macromolecular Rapid Communications · doi:10.1002/marc.201200354 · Cited by 470
Metadata
- Authors
- Gress, A., Völkel, A., & Schlaad, H.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-10-01
- Volume
- 40
- Issue
- 22
- Pages
- 7928-7933
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2077725430
- Cited by
- 417
- References
- 10
- FWCI
- 17.16
- Type
- journal article
- Language
- en
- Open access
- closed
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