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Chirality-Responsive Helical Polymers
Abstract
Unique macromolecules that fold into a preferred-handed helical conformation induced by external chiral stimuli are mainly described in this review. In contrast to small molecular systems, the chiral information of nonracemic guest molecules transfers with a significant amplification in a dynamic helical polymer, such as stereoregular poly(phenylacetylene)s bearing functional pendant groups as an excess of a single-handed helix through noncovalent bonding interaction, which provides an efficient chirality-sensing system. The chirality sensing of other oligomers (foldamers) is also briefly described.
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Metadata
- Authors
- Yashima, E., & Maeda, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-11-10
- Volume
- 41
- Issue
- 1
- Pages
- 3-12
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2029246821
- Cited by
- 441
- References
- 51
- FWCI
- 22.34
- Type
- journal article
- Language
- en
- Open access
- closed
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