The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Responsive Gels Based on a Dynamic Covalent Trithiocarbonate Cross-Linker
Abstract
Dimethacrylate trithiocarbonate was synthesized and used as a dynamic covalent cross-linker to prepare PMMA and PSt gels via radical polymerization. The swelling properties of the PMMA gels were studied and showed that in the presence of radicals the gels reorganize to accommodate forces generated by the swelling processes. This reshuffling of the cross-link network yields an increase in the swelling ratio (up to 300% increase) of the PMMA gels. Two different radical generators, a thermal initiator and a Cu I /L complex, were successfully used to trigger the reorganization of the gels. To illustrate the broad utility of the procedure, three discrete pieces of gels were fused into one single piece to demonstrate that dynamic covalent cross-linkers can be used to prepare materials that can be reprocessed and/or undergo self-repair.
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Cites
Wang, J.-S., & Matyjaszewski, K. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00125a035 · Cited by 4,622
Self-citationKato, M., Kamigaito, M., Sawamoto, M., & Higashimura, T. (1995) · Macromolecules · doi:10.1021/ma00109a056 · Cited by 3,046
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
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Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
Matyjaszewski, K. (2012) · Macromolecules · doi:10.1021/ma3001719 · Cited by 2,606
Self-citationSelf-healing polymeric materials
Yang, Y., & Urban, M. W. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60109a · Cited by 1,444
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Self-citationWang, S., & Urban, M. W. (2020) · Nature Reviews Materials · doi:10.1038/s41578-020-0202-4 · Cited by 1,374
Metadata
- Authors
- Nicolaÿ, R., Kamada, J., Van Wassen, A., & Matyjaszewski, K.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-04-15
- Volume
- 43
- Issue
- 9
- Pages
- 4355-4361
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2033634360
- Cited by
- 240
- References
- 3
- FWCI
- 6.17
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
