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Self-Healing Materials Based on Disulfide Links
Abstract
Autonomous healing of damage is a common phenomenon in living organisms but is hardly ever encountered in synthetic materials. Disulfide chemistry is used to introduce a self-healing ability in a covalently cross-linked rubber. Autonomous healing of a cut takes place at moderate temperatures and leads to full recovery of mechanical properties. This result is achieved by introducing disulfide groups in the network that are able to exchange, leading to renewal of cross-links across the damaged surfaces. The healing process can be repeated many times. The combination of their unique self-healing properties and applicability for a large variety of polymers makes this approach ideal for coatings.
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Cited by
Advances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
Self-healing gels based on constitutional dynamic chemistry and their potential applications
Wei, Z., Yang, J. H., Zhou, J., Xu, F., Zrínyi, M., Dussault, P. H., Osada, Y., & Chen, Y. M. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00219a · Cited by 896
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
Winne, J. M., Leibler, L., & Du Prez, F. E. (2019) · Polymer Chemistry · doi:10.1039/c9py01260e · Cited by 736
Light-triggered self-healing and shape-memory polymers
Habault, D., Zhang, H., & Zhao, Y. (2013) · Chemical Society Reviews · doi:10.1039/c3cs35489j · Cited by 662
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Metadata
- Authors
- Canadell, J., Goossens, H., & Klumperman, B.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-17
- Volume
- 44
- Issue
- 8
- Pages
- 2536-2541
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2114826329
- Cited by
- 1,007
- References
- 0
- FWCI
- 24.27
- Type
- journal article
- Language
- en
- Open access
- closed
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- Canadell, J., Goossens, H., & Klumperman, B. (2011). Self-Healing Materials Based on Disulfide Links. Macromolecules. https://doi.org/10.1021/ma2001492
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
