The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst
Abstract
Well-controlled polymerization of methyl methacrylate at 35 °C was achieved by photochemically mediated atom transfer radical polymerization using a copper catalyst concentration as low as 50–100 ppm. Irradiation at λ > 350 nm provided both a reduction of initially added copper(II) catalyst complexed with either PMDETA or TPMA ligand to a copper(I) activator and a sufficient rate of polymerization. Poly(methyl methacrylate) with a narrow dispersity and predictable molar mass was obtained when an initiator, such as 2-bromopropionitrile, was used. Successful chain-extension polymerization confirmed the living character of the photopolymerization system.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Controlled/living radical polymerization: Features, developments, and perspectives
Braunecker, W. A., & Matyjaszewski, K. (2007) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.11.002 · Cited by 3,202
Cited by
Macromolecular Engineering by Atom Transfer Radical Polymerization
Matyjaszewski, K., & Tsarevsky, N. V. (2014) · Journal of the American Chemical Society · doi:10.1021/ja408069v · Cited by 1,159
SARA ATRP or SET-LRP. End of controversy?
Konkolewicz, D., Wang, Y., Krys, P., Zhong, M., Isse, A. A., Gennaro, A., & Matyjaszewski, K. (2014) · Polymer Chemistry · doi:10.1039/c4py00149d · Cited by 314
Yeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Metadata
- Authors
- Mosnáček, J., & Ilčíková, M.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-07-19
- Volume
- 45
- Issue
- 15
- Pages
- 5859-5865
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2332298298
- Cited by
- 241
- References
- 1
- FWCI
- 12.98
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst. https://app.cochat.ai/papers/10.1021/ma300773t
- The paper
- Mosnáček, J., & Ilčíková, M. (2012). Photochemically Mediated Atom Transfer Radical Polymerization of Methyl Methacrylate Using ppm Amounts of Catalyst. Macromolecules. https://doi.org/10.1021/ma300773t
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
