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Cited by 265

The DOI matches its Crossref record; 66 of the 66 references it cites were found in a registry or an index.

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

Open access
Carrow, Brad P., Nozaki, Kyoko·2014·Macromolecules
DOI 10.1021/ma500034g
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Abstract

The incorporation of polar functional groups into polyolefins can significantly alter the adhesion, barrier and surface properties, dyeability, printability, and compatibility of the resulting "functional polyolefin". Thus, the development of methods for the controlled synthesis of functional polyolefins from industrially relevant monomers holds the potential to expand the range of applications available to this already ubiquitous class of materials. In this Perspective, recent advances in transition-metal-catalyzed functional polyolefin synthesis will be reviewed. A common thread among the innovations discussed here is the perturbation of catalyst function by tailored design of the chelating ancillary ligand, aided in many cases by improved mechanistic understanding. Specific topics discussed here include rare examples of catalyst control over the regio- and stereochemistry of polar monomer insertion by phosphine–sulfonato palladium complexes (Drent-type), rate acceleration of insertion polymerization by binuclear cooperativity using salicylaldiminato nickel complexes (Grubbs-type), and formation of linear copolymers of ethylene and polar vinyl monomers using a cationic palladium catalyst ligated by a bisphosphine monoxide (BPMO) that contrasts the typical polymer microstructures formed by other cationic group 10 catalysts ligated by an α-diimine (Brookhart-type).

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Metadata

Authors
Carrow, B. P., & Nozaki, K.
Venue
Macromolecules
Publisher
American Chemical Society (ACS)
Published
2014-03-19
Volume
47
Issue
8
Pages
2541-2555
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
DOI
10.1021/ma500034g
OpenAlex
W2315746341
Cited by
265
References
66
FWCI
11.71
Type
journal article
Language
en
Open access
hybrid

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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