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Cited by 408

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Soluble Stoichiometric Complexes from Poly(N-ethyl-4-vinylpyridinium) Cations and Poly(ethylene oxide)-block-polymethacrylate Anions

Kabanov, Alexander V., Bronich, Tatiana K., Kabanov, Victor A., Yu, Kui, Eisenberg, Adi·1996·Macromolecules

Abstract

Block ionomer complexes formed between the block copolymers containing poly(sodium methacrylate) (PMANa) and poly(ethylene oxide) (PEO) segments and poly( N -ethyl-4-vinylpyridinium bromide) (PEVP) were investigated. The data obtained suggest that (i) these systems form water-soluble stoichiometric complexes; (ii) these complexes are stable in a much broader pH range compared to the polyelectrolyte complexes prepared from homopolymers; (iii) they self-assemble to form the core of a micelle comprised of neutralized polyions, surrounded by the PEO corona; (iv) they are salt sensitive since they fall apart as the salt concentration increases beyond a critical value; and (v) they can participate in the cooperative polyion substitution reactions. Therefore, these complexes represent a new class of hybrid materials which combine properties of polyelectrolyte complexes and block copolymer micelles.

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Metadata

Authors
Kabanov, A. V., Bronich, T. K., Kabanov, V. A., Yu, K., & Eisenberg, A.
Venue
Macromolecules
Published
1996-01-01
Volume
29
Issue
21
Pages
6797-6802
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W2063173103
Cited by
408
References
1
FWCI
4.49
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Soluble Stoichiometric Complexes from Poly(N-ethyl-4-vinylpyridinium) Cations and Poly(ethylene oxide)-block-polymethacrylate Anions. https://app.cochat.ai/papers/10.1021/ma960120k
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Kabanov, A. V., Bronich, T. K., Kabanov, V. A., Yu, K., & Eisenberg, A. (1996). Soluble Stoichiometric Complexes from Poly(N-ethyl-4-vinylpyridinium) Cations and Poly(ethylene oxide)-block-polymethacrylate Anions. Macromolecules. https://doi.org/10.1021/ma960120k

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