The DOI matches its Crossref record.
Polymer Melt Intercalation in Organically-Modified Layered Silicates: Model Predictions and Experiment
Abstract
The effect of silicate functionalization, anneal temperature, polymer molecular weight, and constituent interactions on polymer melt intercalation of a variety of styrene-derivative polymers in alkylammonium-functionalized silicates is examined. Hybrid formation requires an optimal interlayer structure for the organically-modified layered silicate (OLS), with respect to the number per host area and size of the alkylammonium chains, as well as the presence of polar interactions between the OLS and polymer. From these observations and the qualitative predictions of the mean-field lattice-based model of polymer melt intercalation (preceding paper in this issue), general guidelines may be established for selecting potentially compatible polymer−OLS systems. The interlayer structure of the OLS should be optimized to maximize the configurational freedom of the functionalizing chains upon layer separation while maximizing potential interaction sites with the surface. The most successful polymers for intercalation exhibited polar character or contained Lewis-acid/base groups.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Polymer nanotechnology: Nanocomposites
Paul, D. R., & Robeson, L. M. (2008) · Polymer · doi:10.1016/j.polymer.2008.04.017 · Cited by 3,317
SINHARAY, S., & BOUSMINA, M. (2005) · Progress in Materials Science · doi:10.1016/j.pmatsci.2005.05.002 · Cited by 1,611
Structural and mechanical properties of polymer nanocomposites
Tjong, S. C. (2006) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2006.06.001 · Cited by 1,531
Biobased plastics and bionanocomposites: Current status and future opportunities
Reddy, M. M., Vivekanandhan, S., Misra, M., Bhatia, S. K., & Mohanty, A. K. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2013.05.006 · Cited by 1,080
Nylon 6 nanocomposites by melt compounding
Cho, J. W., & Paul, D. R. (2001) · Polymer · doi:10.1016/s0032-3861(00)00380-3 · Cited by 1,045
Food packaging based on polymer nanomaterials
Silvestre, C., Duraccio, D., & Cimmino, S. (2011) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.02.003 · Cited by 937
Polymer Nanocomposites—A Comparison between Carbon Nanotubes, Graphene, and Clay as Nanofillers
Bhattacharya, M. (2016) · Materials · doi:10.3390/ma9040262 · Cited by 747
Müller, K., Bugnicourt, E., Latorre, M., Jorda, M., Echegoyen Sanz, Y., Lagaron, J., Miesbauer, O., Bianchin, A., Hankin, S., Bölz, U., et al. (2017) · Nanomaterials · doi:10.3390/nano7040074 · Cited by 746
Multiscale modeling and simulation of polymer nanocomposites
Zeng, Q. H., Yu, A. B., & Lu, G. Q. (2008) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2007.09.002 · Cited by 657
Effect of organoclay structure on nylon 6 nanocomposite morphology and properties
Fornes, T. D., Yoon, P. J., Hunter, D. L., Keskkula, H., & Paul, D. R. (2002) · Polymer · doi:10.1016/s0032-3861(02)00400-7 · Cited by 621
New polylactide/layered silicate nanocomposites. 1. Preparation, characterization, and properties
Sinha Ray, S., Maiti, P., Okamoto, M., Yamada, K., & Ueda, K. (2002) · Macromolecules · doi:10.1021/ma011613e · Cited by 607
Sinha Ray, S., Yamada, K., Okamoto, M., & Ueda, K. (2003) · Polymer · doi:10.1016/s0032-3861(02)00818-2 · Cited by 566
Recent Advances in Biopolymers and Biopolymer-Based Nanocomposites for Food Packaging Materials
Tang, X. Z., Kumar, P., Alavi, S., & Sandeep, K. P. (2012) · Critical Reviews in Food Science and Nutrition · doi:10.1080/10408398.2010.500508 · Cited by 477
Park, H.-M., Lee, W.-K., Park, C.-Y., Cho, W.-J., & Ha, C.-S. (2003) · Journal of Materials Science · doi:10.1023/a:1022308705231 · Cited by 447
Preparation and characterization of graphite nanosheets from ultrasonic powdering technique
Chen, G., Weng, W., Wu, D., Wu, C., Lu, J., Wang, P., & Chen, X. (2004) · Carbon · doi:10.1016/j.carbon.2003.12.074 · Cited by 434
Lepoittevin, B., Devalckenaere, M., Pantoustier, N., Alexandre, M., Kubies, D., Calberg, C., Jérôme, R., & Dubois, P. (2002) · Polymer · doi:10.1016/s0032-3861(02)00229-x · Cited by 411
Hybrid materials based on clays for environmental and biomedical applications
Ruiz-Hitzky, E., Aranda, P., Darder, M., & Rytwo, G. (2010) · Journal of Materials Chemistry · doi:10.1039/c0jm00432d · Cited by 325
Applications of nanocomposite hydrogels for biomedical engineering and environmental protection
Sharma, G., Thakur, B., Naushad, M., Kumar, A., Stadler, F. J., Alfadul, S. M., & Mola, G. T. (2018) · Environmental Chemistry Letters · doi:10.1007/s10311-017-0671-x · Cited by 325
Microstructure, tensile properties, and biodegradability of aliphatic polyester/clay nanocomposites
Lee, S.-R., Park, H.-M., Lim, H., Kang, T., Li, X., Cho, W.-J., & Ha, C.-S. (2002) · Polymer · doi:10.1016/s0032-3861(02)00012-5 · Cited by 324
Preparation of polystyrene/graphite nanosheet composite
Chen, G., Wu, C., Weng, W., Wu, D., & Yan, W. (2003) · Polymer · doi:10.1016/s0032-3861(03)00050-8 · Cited by 324
Progress in nano-biocomposites based on polysaccharides and nanoclays
Chivrac, F., Pollet, E., & Avérous, L. (2009) · Materials Science and Engineering: R: Reports · doi:10.1016/j.mser.2009.09.002 · Cited by 321
New polylactide/layered silicate nanocomposites. 5. Designing of materials with desired properties
Sinha Ray, S., Yamada, K., Okamoto, M., Fujimoto, Y., Ogami, A., & Ueda, K. (2003) · Polymer · doi:10.1016/j.polymer.2003.08.021 · Cited by 317
Chitosan/clay nanocomposite film preparation and characterization
Xu, Y., Ren, X., & Hanna, M. A. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.22664 · Cited by 301
Nanoscopic-Confinement Effects on Local Dynamics
Anastasiadis, S. H., Karatasos, K., Vlachos, G., Manias, E., & Giannelis, E. P. (2000) · Physical Review Letters · doi:10.1103/physrevlett.84.915 · Cited by 291
Self-citationGanesan, V., & Jayaraman, A. (2014) · Soft Matter · doi:10.1039/c3sm51864g · Cited by 273
Model for the Viscosity of Particle Dispersions
BICERANO, J., DOUGLAS, J. F., & BRUNE, D. A. (1999) · Journal of Macromolecular Science, Part C: Polymer Reviews · doi:10.1081/mc-100101428 · Cited by 271
Polymer and ceramic nanocomposites for aerospace applications
Rathod, V. T., Kumar, J. S., & Jain, A. (2017) · Applied Nanoscience · doi:10.1007/s13204-017-0592-9 · Cited by 264
Synthetic Biodegradable Aliphatic Polyester/Montmorillonite Nanocomposites
Lim, S. T., Hyun, Y. H., Choi, H. J., & Jhon, M. S. (2002) · Chemistry of Materials · doi:10.1021/cm010377j · Cited by 254
Carli, L. N., Crespo, J. S., & Mauler, R. S. (2011) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2011.07.007 · Cited by 186
Enhancement of mechanical properties of PLA/PCL (80/20) blend by reinforcing with MMT nanoclay
Umamaheswara Rao, R., Venkatanarayana, B., & Suman, K. N. S. (2019) · Materials Today Proceedings · doi:10.1016/j.matpr.2019.06.280 · Cited by 45
Macro, micro and nanostructured morphologies of multiphase polymer systems
Huang, H. (2011) · Handbook of Multiphase Polymer Systems · doi:10.1002/9781119972020.ch6 · Cited by 16
Metadata
- Authors
- Vaia, R. A., & Giannelis, E. P.
- Venue
- Macromolecules
- Publisher
- American Chemical Society (ACS)
- Published
- 1997-12-01
- Volume
- 30
- Issue
- 25
- Pages
- 8000-8009
- ISSN
- 0024-9297 (ISSN-L)
- 1520-5835
- OpenAlex
- W2049792135
- Cited by
- 1,007
- References
- 0
- FWCI
- 14.09
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
