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Cited by 288

The DOI matches its Crossref record; 14 of the 14 references it cites were found in a registry or an index.

Atom Transfer Radical Polymerization of 2-Hydroxyethyl Methacrylate

Beers, Kathryn L., Boo, Sohyun, Gaynor, Scott G., Matyjaszewski, Krzysztof·1999·Macromolecules

Abstract

Atom transfer radical polymerization (ATRP) has been used to directly prepare linear pHEMA of controlled molecular weight and low polydispersity. Reaction conditions were adjusted to successfully polymerize the functional, polar methacrylate monomer. These adjustments included the use of a mixed solvent system consisting of methyl ethyl ketone and 1-propanol, lowering the temperature to 50 °C or less and using an alkyl bromide initiator with a copper chloride catalyst. The Cu/2,2‘-bipyridyl (bpy) complex, normally a heterogeneous mixture in nonpolar, organic solvents, was completely soluble in the above solvent system. A block copolymer was prepared with a poly(methyl methacrylate) macroinitiator. The monomer can also be protected and polymerized under conditions very similar to those used for the ATRP of methyl methacrylate.

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Crossref · 10.1021/ma990176p

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Metadata

Authors
Beers, K. L., Boo, S., Gaynor, S. G., & Matyjaszewski, K.
Venue
Macromolecules
Published
1999-08-10
Volume
32
Issue
18
Pages
5772-5776
ISSN
  • 0024-9297 (ISSN-L)
  • 1520-5835
OpenAlex
W2056467304
Cited by
288
References
14
FWCI
8.90
Type
journal article
Language
en
Open access
closed

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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