The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Controlled Radical Polymerization of Acrylates Regulated by Visible Light
Open accessAbstract
The controlled radical polymerization of a variety of acrylate monomers is reported using an Ir-catalyzed visible light mediated process leading to well-defined homo-, random, and block copolymers. The polymerizations could be efficiently activated and deactivated using light while maintaining a linear increase in molecular weight with conversion and first order kinetics. The robust nature of the fac -[Ir(ppy) 3 ] catalyst allows carboxylic acids to be directly introduced at the chain ends through functional initiators or along the backbone of random copolymers (controlled process up to 50 mol % acrylic acid incorporation). In contrast to traditional ATRP procedures, low polydispersity block copolymers, poly(acrylate)- b -(acrylate), poly(methacrylate)- b -(acrylate), and poly(acrylate)- b -(methacrylate), could be prepared with no monomer sequence requirements. These results illustrate the increasing generality and utility of light mediated Ir-catalyzed polymerization as a platform for polymer synthesis.
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Cites
Radical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Cited by
Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications
Chen, M., Zhong, M., & Johnson, J. A. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00671 · Cited by 1,202
Zoppe, J. O., Ataman, N. C., Mocny, P., Wang, J., Moraes, J., & Klok, H.-A. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00314 · Cited by 1,046
Metal-Free Atom Transfer Radical Polymerization
Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja510389m · Cited by 939
Self-citationPhotoinduced Electron Transfer Reactions for Macromolecular Syntheses
Dadashi-Silab, S., Doran, S., & Yagci, Y. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00586 · Cited by 846
Shanmugam, S., Xu, J., & Boyer, C. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05274 · Cited by 521
Metadata
- Authors
- Treat, N. J., Fors, B. P., Kramer, J. W., Christianson, M., Chiu, C.-Y., Read de Alaniz, J., & Hawker, C. J.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-06-02
- Volume
- 3
- Issue
- 6
- Pages
- 580-584
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2327283322
- Cited by
- 251
- References
- 1
- FWCI
- 19.37
- Type
- journal article
- Language
- en
- Open access
- green
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