The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Metal-Free Atom Transfer Radical Polymerization
Open accessAbstract
Overcoming the challenge of metal contamination in traditional ATRP systems, a metal-free ATRP process, mediated by light and catalyzed by an organic-based photoredox catalyst, is reported. Polymerization of vinyl monomers are efficiently activated and deactivated with light leading to excellent control over the molecular weight, polydispersity, and chain ends of the resulting polymers. Significantly, block copolymer formation was facile and could be combined with other controlled radical processes leading to structural and synthetic versatility. We believe that these new organic-based photoredox catalysts will enable new applications for controlled radical polymerizations and also be of further value in both small molecule and polymer chemistry.
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Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations
Hawker, C. J., Bosman, A. W., & Harth, E. (2001) · Chemical Reviews · doi:10.1021/cr990119u · Cited by 3,850
Self-citationRadical addition–fragmentation chemistry in polymer synthesis
Moad, G., Rizzardo, E., & Thang, S. H. (2008) · Polymer · doi:10.1016/j.polymer.2007.11.020 · Cited by 1,397
Nitroxide-mediated polymerization
Nicolas, J., Guillaneuf, Y., Lefay, C., Bertin, D., Gigmes, D., & Charleux, B. (2013) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2012.06.002 · Cited by 1,380
Ouchi, M., Terashima, T., & Sawamoto, M. (2009) · Chemical Reviews · doi:10.1021/cr900234b · Cited by 1,257
Macromolecular Engineering by Atom Transfer Radical Polymerization
Matyjaszewski, K., & Tsarevsky, N. V. (2014) · Journal of the American Chemical Society · doi:10.1021/ja408069v · Cited by 1,159
Xu, J., Jung, K., Atme, A., Shanmugam, S., & Boyer, C. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501745g · Cited by 990
Diminishing catalyst concentration in atom transfer radical polymerization with reducing agents
Matyjaszewski, K., Jakubowski, W., Min, K., Tang, W., Huang, J., Braunecker, W. A., & Tsarevsky, N. V. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602675103 · Cited by 887
Recent Applications of Organic Dyes as Photoredox Catalysts in Organic Synthesis
Nicewicz, D. A., & Nguyen, T. M. (2014) · ACS Catalysis · doi:10.1021/cs400956a · Cited by 856
Control of a Living Radical Polymerization of Methacrylates by Light
Fors, B. P., & Hawker, C. J. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201203639 · Cited by 820
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Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Radical Approach to Thioester-Containing Polymers
Smith, R. A., Fu, G., McAteer, O., Xu, M., & Gutekunst, W. R. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b12154 · Cited by 248
Block copolymer synthesis in one shot: Concurrent metal-free atrp and rop processes under sunlight
Aydogan, C., Kutahya, C., Allushi, A., Yilmaz, G., & Yagci, Y. (2017) · Polymer Chemistry · doi:10.1039/c7py00069c · Cited by 78
Metadata
- Authors
- Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-31
- Volume
- 136
- Issue
- 45
- Pages
- 16096-16101
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1998350146
- Cited by
- 939
- References
- 34
- FWCI
- 33.24
- Type
- journal article
- Language
- en
- Open access
- green
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- Treat, N. J., Sprafke, H., Kramer, J. W., Clark, P. G., Barton, B. E., Read de Alaniz, J., Fors, B. P., & Hawker, C. J. (2014). Metal-Free Atom Transfer Radical Polymerization. Journal of the American Chemical Society. https://doi.org/10.1021/ja510389m
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
