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Albumin−CdTe Nanoparticle Bioconjugates: Preparation, Structure, and Interunit Energy Transfer with Antenna Effect
Abstract
Conjugates of bovine serum albumin and CdTe nanoparticles capped with l -cysteine have been synthesized via a one-pot glutaric dialdehyde cross-linking procedure. Diads (1:1) with some amount of 2:1 albumin−nanoparticle assemblies preferably form in this reaction, as evidenced by gel electrophoresis. Circular dichroism spectroscopy demonstrates that the tertiary structure of the protein remains largely intact after the conjugation. Attachment of protein moieties result in a significant increase of CdTe emission, which is attributed to the resonance energy transfer from the tryptophan moieties of albumin to CdTe nanoparticles acting as receptors for the protein antennae.
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Cites
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Cited by
Thiol-Capping of CdTe Nanocrystals: An Alternative to Organometallic Synthetic Routes
Gaponik, N., Talapin, D. V., Rogach, A. L., Hoppe, K., Shevchenko, E. V., Kornowski, A., Eychmüller, A., & Weller, H. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp025541k · Cited by 1,540
Self-citationDifferences in subcellular distribution and toxicity of green and red emitting CdTe quantum dots
Lovrić, J., Bazzi, H. S., Cuie, Y., Fortin, G. R. A., Winnik, F. M., & Maysinger, D. (2005) · Journal of Molecular Medicine · doi:10.1007/s00109-004-0629-x · Cited by 815
Biosensing with Luminescent Semiconductor Quantum Dots
Sapsford, K. E., Pons, T., Medintz, I. L., & Mattoussi, H. (2006) · Sensors · doi:10.3390/s6080925 · Cited by 420
Metadata
- Authors
- Mamedova, N. N., Kotov, N. A., Rogach, A. L., & Studer, J.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2001-05-16
- Volume
- 1
- Issue
- 6
- Pages
- 281-286
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2066479122
- Cited by
- 414
- References
- 1
- FWCI
- 11.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mamedova, N. N., Kotov, N. A., Rogach, A. L., & Studer, J. (2001). Albumin−CdTe Nanoparticle Bioconjugates: Preparation, Structure, and Interunit Energy Transfer with Antenna Effect. Nano Letters. https://doi.org/10.1021/nl015519n
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