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“Pulling” Nanoparticles into Water: Phase Transfer of Oleic Acid Stabilized Monodisperse Nanoparticles into Aqueous Solutions of α-Cyclodextrin
Abstract
This paper describes a general method to drastically improve the dispersity of oleic acid stabilized nanoparticles in aqueous solutions. We use oleic acid stabilized monodisperse nanoparticles of iron oxides and silver as model systems, and have modified the surface properties of these nanoparticles through the formation of an inclusion complex between surface-bound surfactant molecules and α-cyclodextrin (α-CD). After the modification, the nanoparticles of both iron oxide and Ag can transfer from hydrophobic solvents, such as hexane, to α-CD aqueous phase. The efficiency of the phase transfer to the aqueous solutions depends on the initial α-CD concentration. The α-CD/oleic acid complex stabilized nanoparticles can be stable for long periods of time in aqueous phase under ambient atmospheric conditions. Transmission electron microscopy (TEM), ultraviolet−visible (UV−vis) spectroscopy, Fourier transform-infrared (FT-IR) spectroscopy, and colorimetric methods have been used in the characterization of these nanoparticles.
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Cites
Fluidity of Bound Hydration Layers
Raviv, U., & Klein, J. (2002) · Science · doi:10.1126/science.1074481 · Cited by 721
Perez, J. M., O'Loughin, T., Simeone, F. J., Weissleder, R., & Josephson, L. (2002) · Journal of the American Chemical Society · doi:10.1021/ja017773n · Cited by 355
Cited by
Laurent, S., Forge, D., Port, M., Roch, A., Robic, C., Vander Elst, L., & Muller, R. N. (2008) · Chemical Reviews · doi:10.1021/cr068445e · Cited by 6,852
Environmental behavior and ecotoxicity of engineered nanoparticles to algae, plants, and fungi
Navarro, E., Baun, A., Behra, R., Hartmann, N. B., Filser, J., Miao, A.-J., Quigg, A., Santschi, P. H., & Sigg, L. (2008) · Ecotoxicology · doi:10.1007/s10646-008-0214-0 · Cited by 1,772
Dong, A., Ye, X., Chen, J., Kang, Y., Gordon, T., Kikkawa, J. M., & Murray, C. B. (2011) · Journal of the American Chemical Society · doi:10.1021/ja108948z · Cited by 907
Wu, W., Jiang, C. Z., & Roy, V. A. L. (2016) · Nanoscale · doi:10.1039/c6nr07542h · Cited by 417
Devaraj, M., Saravanan, R., Deivasigamani, R., Gupta, V. K., Gracia, F., & Jayadevan, S. (2016) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2016.06.028 · Cited by 382
Metadata
- Authors
- Wang, Y., Wong, J. F., Teng, X., Lin, X. Z., & Yang, H.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2003-10-18
- Volume
- 3
- Issue
- 11
- Pages
- 1555-1559
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1963543410
- Cited by
- 294
- References
- 2
- FWCI
- 7.51
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
