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Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates

Redmond, Peter L., Hallock, A. J., Brus, Louis E.·2005·Nano Letters

Abstract

Thermally evaporated silver nanoparticles on conducting substrates spontaneously evolve in size when immersed in pure water. The process was studied using scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and optical absorption spectroscopy. The particles are proposed to reform through an electrochemical Ostwald ripening mechanism driven by the size dependence of the work function and standard electrode potential. We also discuss prior literature experiments where this process appears to occur. Our results show the sensitivity of the electrochemical properties of metallic nanoparticles at relatively large sizes (approximately 50 nm).

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Metadata

Authors
Redmond, P. L., Hallock, A. J., & Brus, L. E.
Venue
Nano Letters
Published
2004-12-04
Volume
5
Issue
1
Pages
131-135
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2089435498
Cited by
306
References
0
FWCI
4.35
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates. https://app.cochat.ai/papers/10.1021/nl048204r
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Redmond, P. L., Hallock, A. J., & Brus, L. E. (2005). Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates. Nano Letters. https://doi.org/10.1021/nl048204r

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