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Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates
Abstract
Thermally evaporated silver nanoparticles on conducting substrates spontaneously evolve in size when immersed in pure water. The process was studied using scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), and optical absorption spectroscopy. The particles are proposed to reform through an electrochemical Ostwald ripening mechanism driven by the size dependence of the work function and standard electrode potential. We also discuss prior literature experiments where this process appears to occur. Our results show the sensitivity of the electrochemical properties of metallic nanoparticles at relatively large sizes (approximately 50 nm).
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Cited by
Ren, P., Pei, P., Li, Y., Wu, Z., Chen, D., & Huang, S. (2020) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2020.100859 · Cited by 737
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Electrochemical Stability of Nanometer-Scale Pt Particles in Acidic Environments
Tang, L., Han, B., Persson, K., Friesen, C., He, T., Sieradzki, K., & Ceder, G. (2010) · Journal of the American Chemical Society · doi:10.1021/ja9071496 · Cited by 357
On the origin of the capacity fading for aluminium negative electrodes in Li-ion batteries
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Metadata
- Authors
- Redmond, P. L., Hallock, A. J., & Brus, L. E.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2004-12-04
- Volume
- 5
- Issue
- 1
- Pages
- 131-135
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2089435498
- Cited by
- 306
- References
- 0
- FWCI
- 4.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates. https://app.cochat.ai/papers/10.1021/nl048204r
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- Redmond, P. L., Hallock, A. J., & Brus, L. E. (2005). Electrochemical Ostwald Ripening of Colloidal Ag Particles on Conductive Substrates. Nano Letters. https://doi.org/10.1021/nl048204r
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