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Design and Tailoring of the Nanotubular Arrayed Architecture of Hydrous RuO2 for Next Generation Supercapacitors
Abstract
By use of the membrane-templated synthesis route, hydrous RuO2 (RuO2.xH2O) nanotubular arrayed electrodes were successfully synthesized by means of the anodic deposition technique. The desired three-dimensional mesoporous architecture of RuO2.xH2O nanotubular arrayed electrodes with annealing in air at 200 degrees C for 2 h simultaneously maintained the facility of electrolyte penetration, the ease of proton exchange/diffusion, and the metallic conductivity of crystalline RuO2, exhibiting unexpectedly ultrahigh power characteristics with its frequency "knee" reaching ca. 4.0-7.8 kHz, 20-40 times better than that of RuO2 single crystalline, arrayed nanorods. The specific power and specific energy of annealed RuO2.xH2O nanotubes measured at 0.8 V and 4 kHz is equal to 4320 kW kg-1 and 7.5 W h kg-1, respectively, demonstrating the characteristics of next generation supercapacitors.
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Metadata
- Authors
- Hu, C.-C., Chang, K.-H., Lin, M.-C., & Wu, Y.-T.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2006-11-18
- Volume
- 6
- Issue
- 12
- Pages
- 2690-2695
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1981051545
- Cited by
- 1,734
- References
- 29
- FWCI
- 15.90
- Type
- journal article
- Language
- en
- Open access
- closed
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