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Raman Spectra of Graphite Oxide and Functionalized Graphene Sheets

Kudin, Konstantin N., Ozbas, Bulent, Schniepp, Hannes C., Prud'homme, Robert K., Aksay, Ilhan A., Car, Roberto·2008·Nano Letters

Abstract

We investigate Raman spectra of graphite oxide and functionalized graphene sheets with epoxy and hydroxyl groups and Stone-Wales and 5-8-5 defects by first-principles calculations to interpret our experimental results. Only the alternating pattern of single-double carbon bonds within the sp2 carbon ribbons provides a satisfactory explanation for the experimentally observed blue shift of the G band of the Raman spectra relative to graphite. To obtain these single-double bonds, it is necessary to have sp3 carbons on the edges of a zigzag carbon ribbon.

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Cites

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Metadata

Authors
Kudin, K. N., Ozbas, B., Schniepp, H. C., Prud'homme, R. K., Aksay, I. A., & Car, R.
Venue
Nano Letters
Published
2007-12-22
Volume
8
Issue
1
Pages
36-41
ISSN
  • 1530-6984 (ISSN-L)
  • 1530-6992
OpenAlex
W2042454875
Cited by
4,475
References
2
FWCI
30.35
Type
journal article
Language
en
Open access
closed

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