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Imaging Stacking Order in Few-Layer Graphene
Open accessAbstract
Few-layer graphene (FLG) has been predicted to exist in various crystallographic stacking sequences, which can strongly influence the material's electronic properties. We demonstrate an accurate and efficient method to characterize stacking order in FLG using the distinctive features of the Raman 2D-mode. Raman imaging allows us to visualize directly the spatial distribution of Bernal (ABA) and rhombohedral (ABC) stacking in tri- and tetralayer graphene. We find that 15% of exfoliated graphene tri- and tetralayers is composed of micrometer-sized domains of rhombohedral stacking, rather than of usual Bernal stacking. These domains are stable and remain unchanged for temperatures exceeding 800 °C.
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Citations
Cited by
Raman spectroscopy as a versatile tool for studying the properties of graphene
Ferrari, A. C., & Basko, D. M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.46 · Cited by 7,405
Topological valley transport at bilayer graphene domain walls
Ju, L., Shi, Z., Nair, N., Lv, Y., Jin, C., Velasco, J., Ojeda-Aristizabal, C., Bechtel, H. A., Martin, M. C., Zettl, A., et al. (2015) · Nature · doi:10.1038/nature14364 · Cited by 680
Two-dimensional phonon transport in graphene
Nika, D. L., & Balandin, A. A. (2012) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/24/23/233203 · Cited by 346
Nonblinking, Intense Two-Dimensional Light Emitter: Monolayer WS2 Triangles
Peimyoo, N., Shang, J., Cong, C., Shen, X., Wu, X., Yeow, E. K. L., & Yu, T. (2013) · ACS Nano · doi:10.1021/nn4046002 · Cited by 308
Metadata
- Authors
- Lui, C. H., Li, Z., Chen, Z., Klimov, P. V., Brus, L. E., & Heinz, T. F.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-12-01
- Volume
- 11
- Issue
- 1
- Pages
- 164-169
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1994608548
- Cited by
- 389
- References
- 0
- FWCI
- 15.60
- Type
- journal article
- Language
- en
- Open access
- green
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- Lui, C. H., Li, Z., Chen, Z., Klimov, P. V., Brus, L. E., & Heinz, T. F. (2011). Imaging Stacking Order in Few-Layer Graphene. Nano Letters. https://doi.org/10.1021/nl1032827
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