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In Situ Transmission Electron Microscopy Observations of Electrochemical Oxidation of Li2O2
Abstract
In this Letter, we report the first in situ transmission electron microscopy observation of electrochemical oxidation of Li2O2, providing insights into the rate limiting processes that govern charge in Li-O2 cells. In these studies, oxidation of electrochemically formed Li2O2 particles, supported on multiwall carbon nanotutubes (MWCNTs), was found to occur preferentially at the MWCNT/Li2O2 interface, suggesting that electron transport in Li2O2 ultimately limits the oxidation kinetics at high rates or overpotentials.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Lithium Batteries: Status, Prospects and Future
Scrosati, B., & Garche, J. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2009.11.048 · Cited by 5,153
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Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Chen, D., Chen, C., Baiyee, Z. M., Shao, Z., & Ciucci, F. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00073 · Cited by 936
Carbon-based electrocatalysts for advanced energy conversion and storage
Zhang, J., Xia, Z., & Dai, L. (2015) · Science Advances · doi:10.1126/sciadv.1500564 · Cited by 735
A review of cathode materials and structures for rechargeable lithium–air batteries
Ma, Z., Yuan, X., Li, L., Ma, Z.-F., Wilkinson, D. P., Zhang, L., & Zhang, J. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00838g · Cited by 485
Song, K., Cho, E., & Kang, Y.-M. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b01196 · Cited by 112
Metadata
- Authors
- Zhong, L., Mitchell, R. R., Liu, Y., Gallant, B. M., Thompson, C. V., Huang, J. Y., Mao, S. X., & Shao-Horn, Y.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-04-25
- Volume
- 13
- Issue
- 5
- Pages
- 2209-2214
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W2315158659
- Cited by
- 226
- References
- 2
- FWCI
- 19.97
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhong, L., Mitchell, R. R., Liu, Y., Gallant, B. M., Thompson, C. V., Huang, J. Y., Mao, S. X., & Shao-Horn, Y. (2013). In Situ Transmission Electron Microscopy Observations of Electrochemical Oxidation of Li2O2. Nano Letters. https://doi.org/10.1021/nl400731w
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