The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Promoting Formation of Noncrystalline Li2O2 in the Li–O2 Battery with RuO2 Nanoparticles
Abstract
Low electrical efficiency for the lithium-oxygen (Li-O2) electrochemical reaction is one of the most significant challenges in current nonaqueous Li-O2 batteries. Here we present ruthenium oxide nanoparticles (RuO2 NPs) dispersed on multiwalled carbon nanotubes (CNTs) as a cathode, which dramatically increase the electrical efficiency up to 73%. We demonstrate that the RuO2 NPs contribute to the formation of poorly crystalline lithium peroxide (Li2O2) that is coated over the CNT with large contact area during oxygen reduction reaction (ORR). This unique Li2O2 structure can be smoothly decomposed at low potential upon oxygen evolution reaction (OER) by avoiding the energy loss associated with the decomposition of the more typical Li2O2 structure with a large size, small CNT contact area, and insulating crystals.
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Cites
Li-O2 and Li-S batteries with high energy storage
Bruce, P. G., Freunberger, S. A., Hardwick, L. J., & Tarascon, J.-M. (2012) · Nature Materials · doi:10.1038/nmat3191 · Cited by 9,479
Cited by
Metal-Free Catalysts for Oxygen Reduction Reaction
Dai, L., Xue, Y., Qu, L., Choi, H.-J., & Baek, J.-B. (2015) · Chemical Reviews · doi:10.1021/cr5003563 · Cited by 2,380
Boosting bifunctional oxygen electrocatalysis with 3D graphene aerogel-supported Ni/MnO particles
Fu, G., Yan, X., Chen, Y., Xu, L., Sun, D., Lee, J., & Tang, Y. (2018) · Advanced Materials · doi:10.1002/adma.201704609 · Cited by 660
A review of cathode materials and structures for rechargeable lithium–air batteries
Ma, Z., Yuan, X., Li, L., Ma, Z.-F., Wilkinson, D. P., Zhang, L., & Zhang, J. (2015) · Energy & Environmental Science · doi:10.1039/c5ee00838g · Cited by 485
Artificial Protection Film on Lithium Metal Anode toward Long‐Cycle‐Life Lithium–Oxygen Batteries
Liu, Q., Xu, J., Yuan, S., Chang, Z., Xu, D., Yin, Y., Li, L., Zhong, H., Jiang, Y., Yan, J., et al. (2015) · Advanced Materials · doi:10.1002/adma.201501490 · Cited by 482
Channel‐Rich RuCu Nanosheets for pH‐Universal Overall Water Splitting Electrocatalysis
Yao, Q., Huang, B., Zhang, N., Sun, M., Shao, Q., & Huang, X. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201908092 · Cited by 378
Metadata
- Authors
- Yilmaz, E., Yogi, C., Yamanaka, K., Ohta, T., & Byon, H. R.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-16
- Volume
- 13
- Issue
- 10
- Pages
- 4679-4684
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W207216418
- Cited by
- 457
- References
- 1
- FWCI
- 34.35
- Type
- journal article
- Language
- en
- Open access
- closed
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