The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Silver Cluster Formation, Dynamics, and Chemistry in Metal−Organic Frameworks
Abstract
Synthetic methods used to produce metal nanoparticles typically lead to a distribution of particle sizes. In addition, creation of the smallest clusters, with sizes of a few to tens of atoms, remains very challenging. Nanoporous metal-organic frameworks (MOFs) are a promising solution to these problems, since their long-range crystalline order creates completely uniform pore sizes with the potential for both steric and chemical stabilization. We report a systematic investigation of silver nanocluster formation within MOFs using three representative MOF templates. The as-synthesized clusters are spectroscopically consistent with dimensions < or =1 nm, with a significant fraction existing as Ag(3) clusters, as shown by electron paramagnetic resonance. Importantly, we show conclusively that very rapid TEM-induced MOF degradation leads to agglomeration and stable, easily imaged particles, explaining prior reports of particles larger than MOF pores. These results solve an important riddle concerning MOF-based templates and suggest that heterostructures composed of highly uniform arrays of nanoparticles within MOFs are feasible.
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Cites
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Metadata
- Authors
- Houk, R. J. T., Jacobs, B. W., Gabaly, F. E., Chang, N. N., Talin, A. A., Graham, D. D., House, S. D., Robertson, I. M., & Allendorf, M. D.
- Venue
- Nano Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-09-16
- Volume
- 9
- Issue
- 10
- Pages
- 3413-3418
- ISSN
- 1530-6984 (ISSN-L)
- 1530-6992
- OpenAlex
- W1967576885
- Cited by
- 249
- References
- 1
- FWCI
- 8.39
- Type
- journal article
- Language
- en
- Open access
- closed
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