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The Influence of Strong Electron and Hole Doping on the Raman Intensity of Chemical Vapor-Deposition Graphene
Abstract
Electrochemical charging has been applied to study the influence of doping on the intensity of the various Raman features observed in chemical vapor-deposition-grown graphene. Three different laser excitation energies have been used to probe the influence of the excitation energy on the behavior of both the G and G' modes regarding their dependence on doping. The intensities of both the G and G' modes exhibit a significant but different dependence on doping. While the intensity of the G' band monotonically decreases with increasing magnitude of the electrode potential (positive or negative), for the G band a more complex behavior has been found. The striking feature is an increase of the Raman intensity of the G mode at a high value of the positive electrode potential. Furthermore, the observed increase of the Raman intensity of the G mode is found to be a function of laser excitation energy.
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Citations
Cites
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Raman spectroscopy as a versatile tool for studying the properties of graphene
Ferrari, A. C., & Basko, D. M. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.46 · Cited by 7,405
Graphene‐Based Materials: Synthesis, Characterization, Properties, and Applications
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Electrochemistry of Graphene and Related Materials
Ambrosi, A., Chua, C. K., Bonanni, A., & Pumera, M. (2014) · Chemical Reviews · doi:10.1021/cr500023c · Cited by 1,208
Grapheneviasonication assisted liquid-phase exfoliation
Ciesielski, A., & Samorì, P. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60217f · Cited by 1,207
Raman characterization of defects and dopants in graphene
Beams, R., Gustavo Cançado, L., & Novotny, L. (2015) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/27/8/083002 · Cited by 709
Chemical functionalization and characterization of graphene-based materials
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Doping Dependence of the Raman Spectrum of Defected Graphene
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Raman spectroscopy of graphene and related materials
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Electronic and plasmonic phenomena at graphene grain boundaries
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Metadata
- Authors
- Kalbac, M., Reina-Cecco, A., Farhat, H., Kong, J., Kavan, L., & Dresselhaus, M. S.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-08
- Volume
- 4
- Issue
- 10
- Pages
- 6055-6063
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2136979982
- Cited by
- 273
- References
- 1
- FWCI
- 8.03
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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