The DOI matches its Crossref record; 25 of the 25 references it cites were found in a registry or an index.
Fluorographene: A Wide Bandgap Semiconductor with Ultraviolet Luminescence
Abstract
The manipulation of the bandgap of graphene by various means has stirred great interest for potential applications. Here we show that treatment of graphene with xenon difluoride produces a partially fluorinated graphene (fluorographene) with covalent C-F bonding and local sp(3)-carbon hybridization. The material was characterized by Fourier transform infrared spectroscopy, Raman spectroscopy, electron energy loss spectroscopy, photoluminescence spectroscopy, and near edge X-ray absorption spectroscopy. These results confirm the structural features of the fluorographane with a bandgap of 3.8 eV, close to that calculated for fluorinated single layer graphene, (CF)(n). The material luminesces broadly in the UV and visible light regions, and has optical properties resembling diamond, with both excitonic and direct optical absorption and emission features. These results suggest the use of fluorographane as a new, readily prepared material for electronic, optoelectronic applications, and energy harvesting applications.
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Cites
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Cited by
A Facile Microwave Avenue to Electrochemiluminescent Two‐Color Graphene Quantum Dots
Li, L., Ji, J., Fei, R., Wang, C., Lu, Q., Zhang, J., Jiang, L., & Zhu, J. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201200166 · Cited by 890
Two‐Dimensional Fluorinated Graphene: Synthesis, Structures, Properties and Applications
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Chemistry, properties, and applications of fluorographene
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Linear Scaling of the Exciton Binding Energy versus the Band Gap of Two-Dimensional Materials
Choi, J.-H., Cui, P., Lan, H., & Zhang, Z. (2015) · Physical Review Letters · doi:10.1103/physrevlett.115.066403 · Cited by 258
Metadata
- Authors
- Jeon, K.-J., Lee, Z., Pollak, E., Moreschini, L., Bostwick, A., Park, C.-M., Mendelsberg, R., Radmilovic, V., Kostecki, R., Richardson, T. J., & Rotenberg, E.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-01-04
- Volume
- 5
- Issue
- 2
- Pages
- 1042-1046
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2025226488
- Cited by
- 451
- References
- 25
- FWCI
- 22.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jeon, K.-J., Lee, Z., Pollak, E., Moreschini, L., Bostwick, A., Park, C.-M., Mendelsberg, R., Radmilovic, V., Kostecki, R., Richardson, T. J., & Rotenberg, E. (2011). Fluorographene: A Wide Bandgap Semiconductor with Ultraviolet Luminescence. ACS Nano. https://doi.org/10.1021/nn1025274
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