The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Chemically Active Reduced Graphene Oxide with Tunable C/O Ratios
Abstract
Organic dispersions of graphene oxide can be thermally reduced in polar organic solvents under reflux conditions to afford electrically conductive, chemically active reduced graphene oxide (CARGO) with tunable C/O ratios, dependent on the boiling point of the solvent. The reductions are achieved after only 1 h of reflux, and the corresponding C/O ratios do not change upon further thermal treatment. Hydroxyl and carboxyl groups can be removed when the reflux is carried out above 155 °C, while epoxides are removable only when the temperature is higher than 200 °C. The increasing hydrophobic nature of CARGO, as its C/O ratio increases, improves the dispersibility of the nanosheets in a polystyrene matrix, in contrast to the aggregates formed with CARGO having lower C/O ratios. The excellent processability of the obtained CARGO dispersions is demonstrated via free-standing CARGO papers that exhibit tunable electrical conductivity/chemical activity and can be used as lithium-ion battery anodes with enhanced Coulombic efficiency.
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Cites
Superior Thermal Conductivity of Single-Layer Graphene
Balandin, A. A., Ghosh, S., Bao, W., Calizo, I., Teweldebrhan, D., Miao, F., & Lau, C. N. (2008) · Nano Letters · doi:10.1021/nl0731872 · Cited by 13,823
Graphene-based composite materials
Stankovich, S., Dikin, D. A., Dommett, G. H. B., Kohlhaas, K. M., Zimney, E. J., Stach, E. A., Piner, R. D., Nguyen, S. T., & Ruoff, R. S. (2006) · Nature · doi:10.1038/nature04969 · Cited by 12,922
Self-citation
Cited by
Folded Structured Graphene Paper for High Performance Electrode Materials
Liu, F., Song, S., Xue, D., & Zhang, H. (2012) · Advanced Materials · doi:10.1002/adma.201104691 · Cited by 657
Nanocarbon Networks for Advanced Rechargeable Lithium Batteries
Xin, S., Guo, Y.-G., & Wan, L.-J. (2012) · Accounts of Chemical Research · doi:10.1021/ar300094m · Cited by 549
High-performance polystyrene/graphene-based nanocomposites with excellent anti-corrosion properties
Yu, Y.-H., Lin, Y.-Y., Lin, C.-H., Chan, C.-C., & Huang, Y.-C. (2014) · Polym. Chem. · doi:10.1039/c3py00825h · Cited by 451
Zheng, Q., Cai, Z., Ma, Z., & Gong, S. (2015) · ACS Applied Materials & Interfaces · doi:10.1021/am507999s · Cited by 417
Enhanced Osteogenesis by Reduced Graphene Oxide/Hydroxyapatite Nanocomposites
Lee, J. H., Shin, Y. C., Lee, S.-M., Jin, O. S., Kang, S. H., Hong, S. W., Jeong, C.-M., Huh, J. B., & Han, D.-W. (2015) · Scientific Reports · doi:10.1038/srep18833 · Cited by 258
Metadata
- Authors
- Compton, O. C., Jain, B., Dikin, D. A., Abouimrane, A., Amine, K., & Nguyen, S. T.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-06-03
- Volume
- 5
- Issue
- 6
- Pages
- 4380-4391
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2313132466
- Cited by
- 384
- References
- 2
- FWCI
- 17.04
- Type
- journal article
- Language
- en
- Open access
- closed
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