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Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries
Abstract
Reduced graphene oxide/Fe(2)O(3) composite was prepared using a facile two-step synthesis by homogeneous precipitation and subsequent reduction of the G-O with hydrazine under microwave irradiation to yield reduced graphene oxide (RG-O) platelets decorated with Fe(2)O(3) nanoparticles. As an anode material for Li-ion batteries, the RG-O/Fe(2)O(3) composite exhibited discharge and charge capacities of 1693 and 1227 mAh/g, respectively, normalized to the mass of Fe(2)O(3) in the composite (and ∼1355 and 982 mAh/g, respectively, based on the total mass of the composite), with good cycling performance and rate capability. Characterization shows that the Fe(2)O(3) nanoparticles are uniformly distributed on the surface of the RG-O platelets in the composite. The total specific capacity of RG-O/Fe(2)O(3) is higher than the sum of pure RG-O and nanoparticle Fe(2)O(3), indicating a positive synergistic effect of RG-O and Fe(2)O(3) on the improvement of electrochemical performance. The synthesis approach presents a promising route for a large-scale production of RG-O platelet/metal oxide nanoparticle composites as electrode materials for Li-ion batteries.
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Cites
Graphene: Status and Prospects
Geim, A. K. (2009) · Science · doi:10.1126/science.1158877 · Cited by 13,942
Graphene-based composite materials
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Cited by
Smith, A. T., LaChance, A. M., Zeng, S., Liu, B., & Sun, L. (2019) · Nano Materials Science · doi:10.1016/j.nanoms.2019.02.004 · Cited by 1,643
Synthesis, characterization, applications, and challenges of iron oxide nanoparticles
Ali, A., Zafar, H., Zia, M., ul Haq, I., Phull, A. R., Ali, J. S., & Hussain, A. (2016) · Nanotechnology, Science and Applications · doi:10.2147/nsa.s99986 · Cited by 1,591
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Nanostructured carbon for energy storage and conversion
Candelaria, S. L., Shao, Y., Zhou, W., Li, X., Xiao, J., Zhang, J.-G., Wang, Y., Liu, J., Li, J., & Cao, G. (2012) · Nano Energy · doi:10.1016/j.nanoen.2011.11.006 · Cited by 975
Graphene and Graphene‐Based Materials for Energy Storage Applications
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Metadata
- Authors
- Zhu, X., Zhu, Y., Murali, S., Stoller, M. D., & Ruoff, R. S.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-31
- Volume
- 5
- Issue
- 4
- Pages
- 3333-3338
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W146429852
- Cited by
- 1,270
- References
- 2
- FWCI
- 94.92
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhu, X., Zhu, Y., Murali, S., Stoller, M. D., & Ruoff, R. S. (2011). Nanostructured Reduced Graphene Oxide/Fe2O3 Composite As a High-Performance Anode Material for Lithium Ion Batteries. ACS Nano. https://doi.org/10.1021/nn200493r
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