The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Anomalous Magnetic Properties of Nanoparticles Arising from Defect Structures: Topotaxial Oxidation of Fe1–xO|Fe3−δO4 Core|Shell Nanocubes to Single-Phase Particles
Open accessAbstract
Here we demonstrate that the anomalous magnetic properties of iron oxide nanoparticles are correlated with defects in their interior. We studied the evolution of microstructure and magnetic properties of biphasic core|shell Fe(1-x)O|Fe(3-δ)O4 nanoparticles synthesized by thermal decomposition during their topotaxial oxidation to single-phase nanoparticles. Geometric phase analysis of high-resolution electron microscopy images reveals a large interfacial strain at the core|shell interface and the development of antiphase boundaries. Dark-field transmission electron microscopy and powder X-ray diffraction concur that, as the oxidation proceeds, the interfacial strain is released as the Fe(1-x)O core is removed but that the antiphase boundaries remain. The antiphase boundaries result in anomalous magnetic behavior, that is, a reduced saturation magnetization and exchange bias effects in single-phase nanoparticles. Our results indicate that internal defects play an important role in dictating the magnetic properties of iron oxide nanoparticles.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Quantitative measurement of displacement and strain fields from HREM micrographs
Hÿtch, M. J., Snoeck, E., & Kilaas, R. (1998) · Ultramicroscopy · doi:10.1016/s0304-3991(98)00035-7 · Cited by 2,752
Lee, N., & Hyeon, T. (2012) · Chem. Soc. Rev. · doi:10.1039/c1cs15248c · Cited by 995
Cited by
Kandasamy, G., & Maity, D. (2015) · International Journal of Pharmaceutics · doi:10.1016/j.ijpharm.2015.10.058 · Cited by 422
Unni, M., Uhl, A. M., Savliwala, S., Savitzky, B. H., Dhavalikar, R., Garraud, N., Arnold, D. P., Kourkoutis, L. F., Andrew, J. S., & Rinaldi, C. (2017) · ACS Nano · doi:10.1021/acsnano.7b00609 · Cited by 411
Design strategies for shape-controlled magnetic iron oxide nanoparticles
Roca, A. G., Gutiérrez, L., Gavilán, H., Fortes Brollo, M. E., Veintemillas-Verdaguer, S., & Morales, M. D. P. (2019) · Advanced Drug Delivery Reviews · doi:10.1016/j.addr.2018.12.008 · Cited by 366
Improving the Heating Efficiency of Iron Oxide Nanoparticles by Tuning Their Shape and Size
Nemati, Z., Alonso, J., Rodrigo, I., Das, R., Garaio, E., García, J. Á., Orue, I., Phan, M.-H., & Srikanth, H. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b10528 · Cited by 256
Metadata
- Authors
- Wetterskog, E., Tai, C.-W., Grins, J., Bergström, L., & Salazar-Alvarez, G.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-05
- Volume
- 7
- Issue
- 8
- Pages
- 7132-7144
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2156244746
- Cited by
- 194
- References
- 3
- FWCI
- 6.36
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
