Aluminum for Plasmonics
Open accessAbstract
Unlike silver and gold, aluminum has material properties that enable strong plasmon resonances spanning much of the visible region of the spectrum and into the ultraviolet. This extended response, combined with its natural abundance, low cost, and amenability to manufacturing processes, makes aluminum a highly promising material for commercial applications. Fabricating Al-based nanostructures whose optical properties correspond with theoretical predictions, however, can be a challenge. In this work, the Al plasmon resonance is observed to be remarkably sensitive to the presence of oxide within the metal. For Al nanodisks, we observe that the energy of the plasmon resonance is determined by, and serves as an optical reporter of, the percentage of oxide present within the Al. This understanding paves the way toward the use of aluminum as a low-cost plasmonic material with properties and potential applications similar to those of the coinage metals.
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Cites
Handbook of Optical Constants of Solids
(1985) · Elsevier eBooks · doi:10.1016/c2009-0-20920-2 · Cited by 21,162 · see citing works
Plasmonics for improved photovoltaic devices
Atwater, H. A., & Polman, A. (2010) · Nature Materials · doi:10.1038/nmat2629 · Cited by 8,366 · see citing works
Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy
Linic, S., Christopher, P., & Ingram, D. B. (2011) · Nature Materials · doi:10.1038/nmat3151 · Cited by 4,854 · see citing works
Alternative Plasmonic Materials: Beyond Gold and Silver
Naik, G. V., Shalaev, V. M., & Boltasseva, A. E. (2013) · Advanced Materials · doi:10.1002/adma.201205076 · Cited by 2,375 · see citing works
Nano-optics from sensing to waveguiding
Lal, S., Link, S., & Halas, N. J. (2007) · Nature Photonics · doi:10.1038/nphoton.2007.223 · Cited by 2,124 · see citing works
Self-citationPhotodetection with Active Optical Antennas
Knight, M. W., Sobhani, H., Nordlander, P. J., & Halas, N. J. (2011) · Science · doi:10.1126/science.1203056 · Cited by 1,999 · see citing works
Self-citationHot Electrons Do the Impossible: Plasmon-Induced Dissociation of H 2 on Au
Mukherjee, S., Libisch, F., Large, N., Neumann, O., Brown, L. V., Cheng, J. H., Lassiter, J. B., Carter, E. A., Nordlander, P. J., & Halas, N. J. (2012) · Nano Letters · doi:10.1021/nl303940z · Cited by 1,579 · see citing works
Self-citationAn autonomous photosynthetic device in which all charge carriers derive from surface plasmons
Mubeen, S., Lee, J., Singh, N., et al. (2013) · Nature Nanotechnology · doi:10.1038/nnano.2013.18 · Cited by 1,187 · see citing works
Plasmon Resonant Enhancement of Photocatalytic Water Splitting Under Visible Illumination
Liu, Z., Hou, W., Pavaskar, P., Aykol, M., & Cronin, S. B. (2011) · Nano Letters · doi:10.1021/nl104005n · Cited by 1,011 · see citing works
Plasmonic solar water splitting
Warren, S. C., & Thimsen, E. (2011) · Energy & Environmental Science · doi:10.1039/c1ee02875h · Cited by 838 · see citing works
An ESCA method for determining the oxide thickness on aluminum alloys
Strohmeier, B. R. (1990) · Surface and Interface Analysis · doi:10.1002/sia.740150109 · Cited by 600 · see citing works
Localized Surface Plasmon Resonances in Aluminum Nanodisks
Langhammer, C., Schwind, M., Kasemo, B., & Zorić, I. (2008) · Nano Letters · doi:10.1021/nl080453i · Cited by 586 · see citing works
Govorov, A. O., Zhang, H., & Gun’ko, Y. K. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp405430m · Cited by 579 · see citing works
Aluminum Plasmonic Nanoantennas
Knight, M. W., Liu, L., Wang, Y., Brown, L. V., Mukherjee, S., King, N. S., Everitt, H. O., Nordlander, P. J., & Halas, N. J. (2012) · Nano Letters · doi:10.1021/nl303517v · Cited by 569 · see citing works
Self-citationPlasmon Enhanced Solar-to-Fuel Energy Conversion
Thomann, I., Pinaud, B. A., Chen, Z., et al. (2011) · Nano Letters · doi:10.1021/nl201908s · Cited by 496 · see citing works
Zorić, I., Zäch, M., Kasemo, B., & Langhammer, C. (2011) · ACS Nano · doi:10.1021/nn102166t · Cited by 485 · see citing works
Localized Surface Plasmon Resonance Spectroscopy of Triangular Aluminum Nanoparticles
Chan, G., Zhao, J., Schatz, G. C., & Duyne, R. P. V. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp804088z · Cited by 401 · see citing works
Plasmonics in the ultraviolet with the poor metals Al, Ga, In, Sn, Tl, Pb, and Bi
McMahon, J. M., Schatz, G. C., & Gray, S. K. (2013) · Phys. Chem. Chem. Phys. · doi:10.1039/c3cp43856b · Cited by 371 · see citing works
Chen, H. M., Chen, C. K., Chen, C., et al. (2012) · ACS Nano · doi:10.1021/nn3024877 · Cited by 332 · see citing works
Handbook of optical constants (A)
Palik, E. D. (1984) · Cited by 332 · see citing works
Sanz, J. M., Ortiz, D., de la Osa, R. A., Saiz, J. M., González, F., Brown, A. S., Losurdo, M., Everitt, H. O., & Moreno, F. G. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp405773p · Cited by 315 · see citing works
Self-citationReflecting upon the losses in plasmonics and metamaterials
Khurgin, J. B., & Boltasseva, A. E. (2012) · MRS Bulletin · doi:10.1557/mrs.2012.173 · Cited by 279 · see citing works
Deep-UV Surface-Enhanced Resonance Raman Scattering of Adenine on Aluminum Nanoparticle Arrays
Jha, S. K., Ahmed, Z., Agio, M., Ekinci, Y., & Löffler, J. F. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210446w · Cited by 254 · see citing works
Plasmon resonances of aluminum nanoparticles and nanorods
Ekinci, Y., Solak, H. H., & Löffler, J. F. (2008) · Journal of Applied Physics · doi:10.1063/1.2999370 · Cited by 245 · see citing works
Choy, T. C. (2015) · Oxford University Press eBooks · doi:10.1093/acprof:oso/9780198705093.001.0001 · Cited by 242 · see citing works
Optical Nanoantennas for Multiband Surface-Enhanced Infrared and Raman Spectroscopy
D’Andrea, C., Bochterle, J., Toma, A., Huck, C., Neubrech, F., Messina, E., Fazio, B., Maragò, O. M., Fabrizio, E. M. D., de la Chapelle, M. L., et al. (2013) · ACS Nano · doi:10.1021/nn4004764 · Cited by 240 · see citing works
Chowdhury, M. H., Ray, K., Gray, S. K., Pond, J., & Lakowicz, J. R. (2009) · Analytical Chemistry · doi:10.1021/ac802118s · Cited by 224 · see citing works
Deep Ultraviolet Plasmon Resonance in Aluminum Nanoparticle Arrays
Maidecchi, G., Gonella, G., Zaccaria, R. P., Moroni, R., Anghinolfi, L., Giglia, A., Nannarone, S., Mattera, L., Dai, H., Canepa, M., et al. (2013) · ACS Nano · doi:10.1021/nn400918n · Cited by 198 · see citing works
Quantification of oxide film thickness at the surface of aluminium using XPS
Alexander, M. R., Thompson, G. E., Zhou, X., et al. (2002) · Surface and Interface Analysis · doi:10.1002/sia.1344 · Cited by 186 · see citing works
Castro-López, M., Brinks, D., Sapienza, R., et al. (2011) · Nano Letters · doi:10.1021/nl202255g · Cited by 172 · see citing works
Quantitative Modeling of the Third Harmonic Emission Spectrum of Plasmonic Nanoantennas
Hentschel, M., Utikal, T., Giessen, H. W., & Lippitz, M. (2012) · Nano Letters · doi:10.1021/nl301686x · Cited by 165 · see citing works
Zheng, Y., Thai, T., Reineck, P., Qiu, L., Guo, Y., & Bach, U. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201202073 · Cited by 162 · see citing works
Taguchi, A., Saito, Y., Watanabe, K., Yijian, S., & Kawata, S. (2012) · Applied Physics Letters · doi:10.1063/1.4747489 · Cited by 151 · see citing works
Yang, Y., Callahan, J. M., Kim, T.-H., Brown, A. S., & Everitt, H. O. (2013) · Nano Letters · doi:10.1021/nl401145j · Cited by 146 · see citing works
Self-citationEnhanced Second Harmonic Generation by Photonic–Plasmonic Fano-Type Coupling in Nanoplasmonic Arrays
Walsh, G. F., & Negro, L. D. (2013) · Nano Letters · doi:10.1021/nl401037n · Cited by 133 · see citing works
Martin, J., Proust, J., Gérard, D., et al. (2013) · Optical Materials Express · doi:10.1364/ome.3.000954 · Cited by 91 · see citing works
Knight, M. W., Fan, J. A., Capasso, F., et al. (2010) · Optics Express · doi:10.1364/oe.18.002579 · Cited by 76 · see citing works
Self-citationFluorescence enhancement with deep-ultraviolet surface plasmon excitation
Ono, A., Kikawada, M., Akimoto, R., Inami, W., & Kawata, Y. (2013) · Optics Express · doi:10.1364/oe.21.017447 · Cited by 65 · see citing works
Thermally evaporated aluminium thin films
Semaltianos, N. G. (2001) · Applied Surface Science · doi:10.1016/s0169-4332(01)00565-7 · Cited by 54 · see citing works
Aluminum nanoparticles for plasmon-improved coupling of light into silicon
Villesen, T. F., Uhrenfeldt, C., Johansen, B., et al. (2012) · Nanotechnology · doi:10.1088/0957-4484/23/8/085202 · Cited by 54 · see citing works
Chuntonov, L., & Haran, G. (2013) · Nano Letters · doi:10.1021/nl400046z · Cited by 46 · see citing works
Angstrom-Scale Distance Dependence of Antenna-Enhanced Vibrational Signals
Bochterle, J., Neubrech, F., Nagao, T., et al. (2012) · ACS Nano · doi:10.1021/nn304341c · Cited by 45 · see citing works
Grubisic, A., Schweikhard, V., Baker, T. A., & Nesbitt, D. J. (2012) · ACS Nano · doi:10.1021/nn305194n · Cited by 45 · see citing works
Self-assembled Al nanoparticles on Si and fused silica, and their application for Si solar cells
Villesen, T. F., Uhrenfeldt, C., Johansen, B., et al. (2013) · Nanotechnology · doi:10.1088/0957-4484/24/27/275606 · Cited by 42 · see citing works
Organization of Metal Nanoparticles for Surface-Enhanced Spectroscopy: A Difference in Size Matters
Thomas, R., & Swathi, R. S. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp3086914 · Cited by 36 · see citing works
Ultraviolet surface-enhanced Raman scattering at the plasmonic band edge of a metallic grating
Mattiucci, N., D’Aguanno, G., Everitt, H. O., Foreman, J. V., Callahan, J. M., Buncick, M. C., & Bloemer, M. J. (2012) · Optics Express · doi:10.1364/oe.20.001868 · Cited by 35 · see citing works
Self-citationSurface plasmon amplification characteristics of an active three-layer nanoshell-based spaser
Zhang, H., Zhou, J., Zou, W., et al. (2012) · Journal of Applied Physics · doi:10.1063/1.4757416 · Cited by 31 · see citing works
Könenkamp, R., Word, R. C., Fitzgerald, J. P. S., et al. (2012) · Applied Physics Letters · doi:10.1063/1.4757125 · Cited by 21 · see citing works
Toroghi, S., & Kik, P. G. (2012) · Physical Review B · doi:10.1103/physrevb.85.045432 · Cited by 19 · see citing works
Chen, Y., Song, G. Y., Xiao, J., et al. (2013) · Optics Express · doi:10.1364/oe.21.000314 · Cited by 7 · see citing works
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Research works printed but not linked: 1
- [41]41. Langhammer, C.; Schwind, M.; Kasemo, B.; Zoric, I. Loca- lized Surface Plasmon Resonances in Aluminum Nano- disks. Nano Lett. 2008, 8, 1461-1471.
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“The most experimentally tested UV-SERS platforms are Al, Ga, In, Pb, Sn, Bi, Rh, Ru, Pt and Pd, owing to their availability and to the absence of interband transitions in the UV [192].”
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- Authors
- Knight, M. W., King, N. S., Liu, L., Everitt, H. O., Nordlander, P., & Halas, N. J.
- Affiliations
- Rice University (US)
- Duke University (US)
- Corresponding author
- Halas, Naomi J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-04
- Volume
- 8
- Issue
- 1
- Pages
- 834-840
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2089552145
- Semantic Scholar
- 4bd276d87a05f2f497e95ce6e90d3606c8fcf76e
- Cited by
- 1,261
- References
- 50
- Citations by year
- 2026: 59 · 2025: 71 · 2024: 78 · 2023: 88 · 2022: 95 · 2021: 113 · 2020: 121 · 2019: 137 · 2018: 139 · 2017: 140 · 2016: 95 · 2015: 76 · 2014: 49
- FWCI
- 40.49
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Locations
- ACS Nano (publishedVersion)
- PubMed (publishedVersion)
- DukeSpace (Duke University) (submittedVersion)
- Funders
- Air Force Office of Scientific Research (FA9550-10-1-0469)
- Welch Foundation (C-1220, C-1222)
- Topics
- Physical Sciences › Engineering › Biomedical Engineering › Plasmonic and Surface Plasmon Research
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Gold and Silver Nanoparticles Synthesis and Applications
- Physical Sciences › Physics and Astronomy › Atomic and Molecular Physics, and Optics › Orbital Angular Momentum in Optics
- Keywords
- plasmon resonance, alumina, nanodiscs, nanostructuring
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