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Cited by 440

The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.

Ni12P5 Nanoparticles as an Efficient Catalyst for Hydrogen Generation via Electrolysis and Photoelectrolysis

Huang, Zhipeng, Chen, Zhibo, Chen, Zhongzhong, Lv, Cuncai, Meng, Hua, Zhang, Chi·2014·ACS Nano

Abstract

The exploitation of a low-cost catalyst is desirable for hydrogen generation from electrolysis or photoelectrolysis. In this study we have demonstrated that nickel phosphide (Ni12P5) nanoparticles have efficient and stable catalytic activity for the hydrogen evolution reaction. The catalytic performance of Ni12P5 nanoparticles is favorably comparable to those of recently reported efficient nonprecious catalysts. The optimal overpotential required for 20 mA/cm(2) current density is 143 ± 3 mV in acidic solution (H2SO4, 0.5 M). The catalytic activity of Ni12P5 is likely to be correlated with the charged natures of Ni and P. Ni12P5 nanoparticles were introduced to silicon nanowires, and the power conversion efficiency of the resulting composite is larger than that of silicon nanowires decorated with platinum particles. This result demonstrates the promising application potential of metal phosphide in photoelectrochemical hydrogen generation.

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Metadata

Authors
Huang, Z., Chen, Z., Chen, Z., Lv, C., Meng, H., & Zhang, C.
Venue
ACS Nano
Published
2014-07-30
Volume
8
Issue
8
Pages
8121-8129
ISSN
  • 1936-0851 (ISSN-L)
  • 1936-086X
OpenAlex
W2411987129
Cited by
440
References
8
FWCI
17.25
Type
journal article
Language
en
Open access
closed

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