The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Dendritic, Transferable, Strictly Monolayer MoS2 Flakes Synthesized on SrTiO3 Single Crystals for Efficient Electrocatalytic Applications
Abstract
Controllable synthesis of macroscopically uniform, high-quality monolayer MoS2 is crucial for harnessing its great potential in optoelectronics, electrocatalysis, and energy storage. To date, triangular MoS2 single crystals or their polycrystalline aggregates have been synthesized on insulating substrates of SiO2/Si, mica, sapphire, etc., via portable chemical vapor deposition methods. Herein, we report a controllable synthesis of dendritic, strictly monolayer MoS2 flakes possessing tunable degrees of fractal shape on a specific insulator, SrTiO3. Interestingly, the dendritic monolayer MoS2, characterized by abundant edges, can be transferred intact onto Au foil electrodes and serve as ideal electrocatalysts for hydrogen evolution reaction, reflected by a rather low Tafel slope of ∼73 mV/decade among CVD-grown two-dimensional MoS2 flakes. In addition, we reveal that centimeter-scale uniform, strictly monolayer MoS2 films consisting of relatively compact domains can also be obtained, offering insights into promising applications such as flexible energy conversion/harvesting and optoelectronics.
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Cites
The chemistry of two-dimensional layered transition metal dichalcogenide nanosheets
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Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
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MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
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Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250
Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
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Controlled Synthesis of Highly Crystalline MoS 2 Flakes by Chemical Vapor Deposition
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Layer-Dependent Electrocatalysis of MoS2 for Hydrogen Evolution
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Cited by
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Self-citationTwo-dimensional transition metal dichalcogenide nanosheet-based composites
Tan, C., & Zhang, H. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00182f · Cited by 1,605
Voiry, D., Yang, J., & Chhowalla, M. (2016) · Advanced Materials · doi:10.1002/adma.201505597 · Cited by 949
MoS2‐Based Nanocomposites for Electrochemical Energy Storage
Wang, T., Chen, S., Pang, H., Xue, H., & Yu, Y. (2017) · Advanced Science · doi:10.1002/advs.201600289 · Cited by 481
Samadi, M., Sarikhani, N., Zirak, M., Zhang, H., Zhang, H.-L., & Moshfegh, A. Z. (2018) · Nanoscale Horizons · doi:10.1039/c7nh00137a · Cited by 408
Metadata
- Authors
- Zhang, Y., Ji, Q., Han, G.-F., Ju, J., Shi, J., Ma, D., Sun, J., Zhang, Y., Li, M., Lang, X.-Y., Zhang, Y., & Liu, Z.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-21
- Volume
- 8
- Issue
- 8
- Pages
- 8617-8624
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2017653514
- Cited by
- 183
- References
- 10
- FWCI
- 8.49
- Type
- journal article
- Language
- en
- Open access
- closed
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