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Chemically Synthesized Heterostructures of Two-Dimensional Molybdenum/Tungsten-Based Dichalcogenides with Vertically Aligned Layers
Abstract
We demonstrate a one-step, facile chemical synthesis of heterostructures based on two-dimensional (2D) transition metal dichalcogenides (TMDCs) with vertically aligned 2D layers. Specifically, by using a chemical vapor transport method, we synthesize molybdenum (Mo)/tungsten (W)-based disulfide and diselenide heterostructures, such as MoS2/WS2 and MoSe2/WSe2. Detailed structural characterizations reveal that the 2D layers of two different TMDCs are vertically standing/aligned exposing the edge sites of the layers. The TMDC heterostructure materials exhibit a high uniformity of structural/chemical heterogeneity over a large area (>1 cm(2)) and show anisotropic carrier transport properties. These materials with unique heterostructures have great implications for both technological applications and fundamental sciences.
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Transition metal dichalcogenides (TMD) materials, such as MoS2, WS2, MoSe2, WSe2, and VSe2, are developed as potential alternatives to Pt-group electrocatalysts for HER due to their constrained electrons within two-dimensional layers.
“Transition metal dichalcogenides (TMD) materials, for instance, MoS2, WS2, MoSe2, WSe2, and VSe2, are developed as potential alternatives of Pt-group electrocatalysts for HER due to their constrained electrons within two-dimensional (2D) layers.2,15−21”
From In-Situ Growth of Few-Layered MoS2 Nanosheets on Highly Porous Carbon Aerogel as Advanced Electrocatalysts for Hydrogen Evolution Reaction (2015) · cites this paper as [18]
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Metadata
- Authors
- Jung, Y., Shen, J., Sun, Y., & Cha, J. J.
- Affiliations
- Yale University (US)
- Princeton University (US)
- Corresponding author
- Cha, Judy J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-08-25
- Volume
- 8
- Issue
- 9
- Pages
- 9550-9557
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2322420268
- Cited by
- 77
- References
- 38
- Citations by year
- 2026: 1 · 2025: 3 · 2024: 1 · 2023: 1 · 2022: 2 · 2021: 9 · 2020: 9 · 2019: 10 · 2018: 9 · 2017: 16 · 2016: 8 · 2015: 8
- FWCI
- 4.84
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Nano (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Division of Materials Research (DMR 1119826)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Physical Sciences › Materials Science › Materials Chemistry › Graphene research and applications
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Transition Metal Oxide Nanomaterials
- Keywords
- transition metal dichalcogenides, two-dimensional materials, heterostructures, chemical vapor transport synthesis, edge sites, anisotropic carrier transport
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