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Expanding the Catalytic Activity of Nucleophilic N-Heterocyclic Carbenes for Transesterification Reactions
Abstract
[reaction: see text] Currently, there is a renewed interest in reactions that are catalyzed by organic compounds. Typical organic catalysts for acylation or transesterification reactions are based on either nucleophilic tertiary amines or phosphines. This communication discusses the use of nucleophilic N-heterocyclic carbenes as efficient transesterification catalysts. These relatively unexplored and highly versatile organic catalysts were found to be mild, selective, and more active than traditional organic nucleophiles.
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Cited by
Controlled Ring-Opening Polymerization of Lactide and Glycolide
Dechy-Cabaret, O., Martin-Vaca, B., & Bourissou, D. (2004) · Chemical Reviews · doi:10.1021/cr040002s · Cited by 2,257
Organocatalytic Ring-Opening Polymerization
Kamber, N. E., Jeong, W., Waymouth, R. M., Pratt, R. C., Lohmeijer, B. G. G., & Hedrick, J. L. (2007) · Chemical Reviews · doi:10.1021/cr068415b · Cited by 1,489
Self-citationOrganocatalysis: Opportunities and Challenges for Polymer Synthesis
Kiesewetter, M. K., Shin, E. J., Hedrick, J. L., & Waymouth, R. M. (2010) · Macromolecules · doi:10.1021/ma9025948 · Cited by 907
Self-citationWang, X., Liu, J., Xu, S., Xu, J., Pan, X., Liu, J., Cui, S., Li, Z., & Guo, K. (2016) · Polymer Chemistry · doi:10.1039/c6py01107a · Cited by 50
Progress in Catalytic Ring-Opening Polymerization of Biobased Lactones
Al-Shok, L., Haddleton, D. M., & Adams, F. (2022) · Advances in Polymer Science · doi:10.1007/12_2021_111 · Cited by 10
Zhang, L., Li, N., Wang, Y., Guo, J., & Li, J. (2014) · Macromolecular Research · doi:10.1007/s13233-014-2092-z · Cited by 10
Metadata
- Authors
- Nyce, G. W., Lamboy, J. A., Connor, E. F., Waymouth, R. M., & Hedrick, J. L.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-09-25
- Volume
- 4
- Issue
- 21
- Pages
- 3587-3590
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2003046410
- Cited by
- 333
- References
- 0
- FWCI
- 7.33
- Type
- journal article
- Language
- en
- Open access
- closed
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