The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Electrophilicity and Nucleophilicity Index for Radicals
Abstract
Radicals can be regarded as electrophilic/nucleophilic, depending on their tendency to attack sites of relatively higher/lower electron density. In this paper, an electrophilicity scale, global as well as local, and a nucleophilicity scale for 35 radicals is reported. The global electrophilicity scale correlates well with the nucleophilicity scale, suggesting that these concepts are inversely related.
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Citations
Cites
Nucleophilic reactivity constants toward methyl iodide and trans-dichlorodi(pyridine)platinum(II)
Pearson, R. G., Sobel, H. R., & Songstad, J. (1968) · Journal of the American Chemical Society · doi:10.1021/ja01004a021 · Cited by 455
Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Radical philicity and its role in selective organic transformations
Parsaee, F., Senarathna, M. C., Kannangara, P. B., Alexander, S. N., Arche, P. D. E., & Welin, E. R. (2021) · Nature Reviews Chemistry · doi:10.1038/s41570-021-00284-3 · Cited by 462
Redox Signaling by Reactive Electrophiles and Oxidants
Parvez, S., Long, M. J. C., Poganik, J. R., & Aye, Y. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00698 · Cited by 359
Davies, J., Svejstrup, T. D., Fernandez Reina, D., Sheikh, N. S., & Leonori, D. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b04920 · Cited by 334
Peng, J., Zhou, H., Liu, W., Ao, Z., Ji, H., Liu, Y., Su, S., Yao, G., & Lai, B. (2020) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.125387 · Cited by 253
Metadata
- Authors
- De Vleeschouwer, F., Van Speybroeck, V., Waroquier, M., Geerlings, P., & De Proft, F.
- Venue
- Organic Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-06-09
- Volume
- 9
- Issue
- 14
- Pages
- 2721-2724
- ISSN
- 1523-7052 (ISSN-L)
- 1523-7060
- OpenAlex
- W2049917615
- Cited by
- 530
- References
- 1
- FWCI
- 5.01
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
