Toward the Ideal Catalyst: From Atomic Centers to a “Cocktail” of Catalysts

The Heck Reaction as a Sharpening Stone of Palladium Catalysis

Beletskaya, I. P., & Cheprakov, A. V. (2000) · Chemical Reviews · doi:10.1021/cr9903048 · Cited by 3,902

Nanoparticles as Recyclable Catalysts: The Frontier between Homogeneous and Heterogeneous Catalysis

Astruc, D., Lu, F., & Aranzaes, J. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200500766 · Cited by 3,131

Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts

Yin, & Liebscher, J. (2007) · Chemical Reviews · doi:10.1021/cr0505674 · Cited by 2,085

Biaryl Phosphane Ligands in Palladium‐Catalyzed Amination

Surry, D. S., & Buchwald, S. L. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200800497 · Cited by 2,016

On the Nature of the Active Species in Palladium Catalyzed Mizoroki–Heck and Suzuki–Miyaura Couplings – Homogeneous or Heterogeneous Catalysis, A Critical Review

Phan, N. T. S., Van Der Sluys, M., & Jones, C. W. (2006) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200505473 · Cited by 1,905

Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals

Magano, J., & Dunetz, J. R. (2011) · Chemical Reviews · doi:10.1021/cr100346g · Cited by 1,860

Catalytic CC, CN, and CO Ullmann‐Type Coupling Reactions

Monnier, F., & Taillefer, M. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200804497 · Cited by 1,730

Inertia and driving force of chemical reactions

Evans, M. G., & Polanyi, M. (1938) · Transactions of the Faraday Society · doi:10.1039/tf9383400011 · Cited by 1,679

Transition-Metal-Catalyzed C−S, C−Se, and C−Te Bond Formation via Cross-Coupling and Atom-Economic Addition Reactions

Beletskaya, I. P., & Ananikov, V. P. (2011) · Chemical Reviews · doi:10.1021/cr100347k · Cited by 1,675

Recent Applications of Palladium‐Catalyzed Coupling Reactions in the Pharmaceutical, Agrochemical, and Fine Chemical Industries

Torborg, C., & Beller, M. (2009) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200900587 · Cited by 1,469

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

Rosen, B. M., Quasdorf, K. W., Wilson, D. A., Zhang, N., Resmerita, A.-M., Garg, N. K., & Percec, V. (2011) · Chemical Reviews · doi:10.1021/cr100259t · Cited by 1,371

A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions

Widegren, J. A., & Finke, R. G. (2003) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/s1381-1169(02)00728-8 · Cited by 1,245

Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry

Copéret, C., Chabanas, M., Petroff Saint‐Arroman, R., & Basset, J. (2003) · Angewandte Chemie International Edition · doi:10.1002/anie.200390072 · Cited by 1,079

Efficient, Selective, and Recyclable Palladium Catalysts in Carbon−Carbon Coupling Reactions

Molnár, Á. (2011) · Chemical Reviews · doi:10.1021/cr100355b · Cited by 1,042

Palladium Nanoparticles as Efficient Green Homogeneous and Heterogeneous Carbon−Carbon Coupling Precatalysts: A Unifying View

Astruc, D. (2007) · Inorganic Chemistry · doi:10.1021/ic062183h · Cited by 779

A theory of the catalytic surface

Taylor, H. S. (1925) · Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character · doi:10.1098/rspa.1925.0061 · Cited by 669

Complementary Structure Sensitive and Insensitive Catalytic Relationships

Van Santen, R. A. (2009) · Accounts of Chemical Research · doi:10.1021/ar800022m · Cited by 655

Recyclable Heterogeneous Palladium Catalysts in Pure Water: Sustainable Developments in Suzuki, Heck, Sonogashira and Tsuji–Trost Reactions

Lamblin, M., Nassar‐Hardy, L., Hierso, J., Fouquet, É., & Felpin, F. (2010) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.200900765 · Cited by 649

Ligand-free Heck reactions using low Pd-loading

Reetz, M. T., & de Vries, J. G. (2004) · Chemical Communications · doi:10.1039/b406719n · Cited by 644

A unifying mechanism for all high-temperature Heck reactions. The role of palladium colloids and anionic species

de Vries, J. G. (2006) · Dalton Trans. · doi:10.1039/b506276b · Cited by 624

Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 2: The Suzuki reaction

Alonso, F., Beletskaya, I. P., & Yus, M. (2008) · Tetrahedron · doi:10.1016/j.tet.2007.12.036 · Cited by 532

Non-conventional methodologies for transition-metal catalysed carbon–carbon coupling: a critical overview. Part 1: The Heck reaction

Alonso, F., Beletskaya, I. P., & Yus, M. (2005) · Tetrahedron · doi:10.1016/j.tet.2005.08.054 · Cited by 498

The mechanism of the catalytic action of platinum in the reactions 2Co + O2= 2Co2 and 2H2+ O2= 2H2O

Langmuir, I. (1922) · Transactions of the Faraday Society · doi:10.1039/tf9221700621 · Cited by 482

Inner-Sphere Heterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis: The Challenge

Bard, A. J. (2010) · Journal of the American Chemical Society · doi:10.1021/ja101578m · Cited by 397

Combining Enabling Techniques in Organic Synthesis: Continuous Flow Processes with Heterogenized Catalysts

Kirschning, A., Solodenko, W., & Mennecke, K. (2006) · Chemistry – A European Journal · doi:10.1002/chem.200600236 · Cited by 373

La Catalyse en chimie organique

Sabatier, P. (2013) · Nouveau Monde eBooks · doi:10.14375/np.9782369430186 · Cited by 361

Molecular Heterogeneous Catalysis: A Conceptual and Computational Approach

van Santen, R. A., & Neurock, M. (2006) · Wiley eBooks · doi:10.1002/9783527610846 · Cited by 323

Organo-f-element catalysts for efficient and highly selective hydroalkoxylation and hydrothiolation

Weiss, C. J., & Marks, T. J. (2010) · Dalton Transactions · doi:10.1039/c003089a · Cited by 245

Modern State of the Multiplet Theor of Heterogeneous Catalysis

Balandin, A. A. (1969) · Advances in Catalysis · doi:10.1016/s0360-0564(08)60029-2 · Cited by 234

Twist Sense Bias Induced by Chiral Side Chains in Helically Folded Oligomers

Prince, R. B., Brunsveld, L., Meijer, E. W., & Moore, J. S. (2000) · Angewandte Chemie International Edition · doi:10.1002/(sici)1521-3773(20000103)39:1 · Cited by 230

Hypo–hyper-d-electronic interactive nature of interionic synergism in catalysis and electrocatalysis for hydrogen reactions

Jaksic, M. M. (2001) · International Journal of Hydrogen Energy · doi:10.1016/s0360-3199(00)00120-8 · Cited by 207

An Overview of Palladium Nanocatalysts: Surface and Molecular Reactivity

Durand, J., Teuma, E., & Gómez, M. (2008) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200800569 · Cited by 202

Probing catalytic reactions at surfaces

Zaera, F. (2001) · Progress in Surface Science · doi:10.1016/s0079-6816(01)00040-5 · Cited by 198

Heterogenized Homogeneous Catalysts for Fine Chemicals Production: Materials and Processes

(2010) · Catalysis by Metal Complexes · doi:10.1007/978-90-481-3696-4 · Cited by 161

Is It Homogeneous or Heterogeneous Catalysis? Compelling Evidence for Both Types of Catalysts Derived from [Rh(η5-C5Me5)Cl2]2 as a Function of Temperature and Hydrogen Pressure

Hagen, C. M., Widegren, J. A., Maitlis, P. M., & Finke, R. G. (2005) · Journal of the American Chemical Society · doi:10.1021/ja044154g · Cited by 131

Surface structure sensitivity of manganese oxides for low-temperature selective catalytic reduction of NO with NH3

Wang, C., Sun, L., Cao, Q., Bingqing, H., Huang, Z., & Tang, X. (2010) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2010.10.034 · Cited by 130

Can the Observed Changes in the Size or Shape of a Colloidal Nanocatalyst Reveal the Nanocatalysis Mechanism Type: Homogeneous or Heterogeneous?

Narayanan, R., Tabor, C. E., & El‐Sayed, M. A. (2008) · Topics in Catalysis · doi:10.1007/s11244-008-9057-4 · Cited by 128

Experiment and Theory of Fuel Cell Catalysis: Methanol and Formic Acid Decomposition on Nanoparticle Pt/Ru

Rigsby, M. A., Zhou, W.-P., Lewera, A., Duong, H. T., Bagus, P. S., Jaegermann, W., Hunger, R., & Więckowski, A. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp805374p · Cited by 107

Zur Theorie der heterogenen katalytischen Reaktionen. Multipletthypothese. Modell der Dehydrierungskatalyse

Balandin, A. A. (1929) · Zeitschrift für Physikalische Chemie · doi:10.1515/zpch-1929-0222 · Cited by 97

Syntheses, structures and properties of primarily nanosized homo/heterometallic palladium CO/PR 3 -ligated clusters

Mednikov, E. G., & Dahl, L. F. (2010) · Philosophical Transactions of the Royal Society A Mathematical Physical and Engineering Sciences · doi:10.1098/rsta.2009.0272 · Cited by 89

Acid‐Free Nickel Catalyst for Stereo‐ and Regioselective Hydrophosphorylation of Alkynes: Synthetic Procedure and Combined Experimental and Theoretical Mechanistic Study

Ananikov, V. P., Khemchyan, L. L., Beletskaya, I. P., & Starikova, Z. A. (2010) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201000606 · Cited by 83

The effect of palladium particle size on the kinetics of hydrogenation of acetylene–ethylene mixtures over Pd/SiO2 catalysts

Borodziński, A. (2001) · Catalysis Letters · doi:10.1023/a:1009061916463 · Cited by 81

Implication of palladium geometric and electronic structures to hydrogen activation on bulk surfaces and clusters

Efremenko, I. (2001) · Journal of Molecular Catalysis A Chemical · doi:10.1016/s1381-1169(01)00144-3 · Cited by 79

Two Distinct Mechanisms of Alkyne Insertion into the Metal–Sulfur Bond: Combined Experimental and Theoretical Study and Application in Catalysis

Ananikov, V. P., Gayduk, K. A., Orlov, N. V., Beletskaya, I. P., Khrustalev, V. N., & Antipin, M. Y. (2010) · Chemistry - A European Journal · doi:10.1002/chem.200902928 · Cited by 78

Isomorphous Substitutions of Rare Earth Elements for Calcium in Synthetic Hydroxyapatites

Ardanova, L. I., Get’man, E. I., Loboda, S. N., Prisedsky, V. V., Tkachenko, T. V., Marchenko, V. I., Antonovich, V. P., Chivireva, N. A., Chebyshev, K. A., & Lyashenko, A. S. (2010) · Inorganic Chemistry · doi:10.1021/ic1015127 · Cited by 76

Celebrating 20 Years of SYNLETT - Special Essay: General Procedure for the Palladium-Catalyzed Selective Hydrophosphorylation of Alkynes

Ananikov, V. P., Beletskaya, I. P., & Khemchyan, L. L. (2009) · Synlett · doi:10.1055/s-0029-1217739 · Cited by 69

Selective Nanocatalysis of Organic Transformation by Metals: Concepts, Model Systems, and Instruments

Somorjai, G. A., & Li, Y. (2010) · Topics in Catalysis · doi:10.1007/s11244-010-9511-y · Cited by 66

Preparation of metal “nanosalts” and their application in catalysis: heterogeneous and homogeneous pathways

Ananikov, V. P., & Beletskaya, I. P. (2011) · Dalton Transactions · doi:10.1039/c0dt01277g · Cited by 44

Is it homogeneous Pt(II) or heterogeneous Pt(0) catalysis? Evidence that Pt(1,5-COD)Cl2 and Pt(1,5-COD)(CH3)2 plus H2 form heterogeneous, nanocluster plus bulk-metal Pt(0) hydrogenation catalysts

Finney, E. E., & Finke, R. G. (2006) · Inorganica Chimica Acta · doi:10.1016/j.ica.2005.11.023 · Cited by 39

Bond control in surface reactions

Nørskov, J. K., & Abild‐Pedersen, F. (2009) · Nature · doi:10.1038/4611223a · Cited by 32

An understanding and implications of the coverage of surface free sites in heterogeneous catalysis

Wang, H., Guo, Y., Lu, G., & Hu, P. (2009) · The Journal of Chemical Physics · doi:10.1063/1.3140202 · Cited by 25

Metal Catalysts for Heterogeneous Catalysis: From Single Atoms to Nanoclusters and Nanoparticles

Liu, L., & Corma, A. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00776 · Cited by 4,777

Target-oriented analysis of gaseous, liquid and solid chemical systems by mass spectrometry, nuclear magnetic resonance spectroscopy and electron microscopy

Kachala, V. V., Khemchyan, L. L., Kashin, A. S., Orlov, N. V., Grachev, A. A., Zalesskiy, S. S., & Ananikov, V. P. (2013) · Russian Chemical Reviews · doi:10.1070/rc2013v082n07abeh004413 · Cited by 262