The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts
Abstract
A new method for the assessment of the π-acceptor strength of N-heterocyclic carbenes is presented. The 77 Se chemical shifts of the easily available selenium carbene adducts 1 ·Se– 7 ·Se correlate with the π-acceptor character of the respective carbenes. The observed δ( 77 Se) values cover a range of almost 800 ppm, with increasing π-acidity leading to a downfield shift of the signal.
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Cites
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N-Heterocyclic Carbenes in Late Transition Metal Catalysis
Díez-González, S., Marion, N., & Nolan, S. P. (2009) · Chemical Reviews · doi:10.1021/cr900074m · Cited by 3,066
Organocatalysis by N-Heterocyclic Carbenes
Enders, D., Niemeier, O., & Henseler, A. (2007) · Chemical Reviews · doi:10.1021/cr068372z · Cited by 3,059
Heterocyclic Carbenes: Synthesis and Coordination Chemistry
Hahn, F. E., & Jahnke, M. C. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200703883 · Cited by 2,775
Quantifying and understanding the electronic properties of N-heterocyclic carbenes
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Understanding the M (NHC) (NHC = N-heterocyclic carbene) bond
Jacobsen, H., Correa, A., Poater, A., Costabile, C., & Cavallo, L. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.06.006 · Cited by 744
Cited by
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
Melaimi, M., Jazzar, R., Soleilhavoup, M., & Bertrand, G. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201702148 · Cited by 788
Computational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Quantifying and understanding the steric properties of N-heterocyclic carbenes
Gómez-Suárez, A., Nelson, D. J., & Nolan, S. P. (2017) · Chemical Communications · doi:10.1039/c7cc00255f · Cited by 391
Vummaleti, S. V. C., Nelson, D. J., Poater, A., Gómez-Suárez, A., Cordes, D. B., Slawin, A. M. Z., Nolan, S. P., & Cavallo, L. (2015) · Chemical Science · doi:10.1039/c4sc03264k · Cited by 286
Determining the Ligand Properties of N‐Heterocyclic Carbenes from 77Se NMR Parameters
Verlinden, K., Buhl, H., Frank, W., & Ganter, C. (2015) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201500174 · Cited by 270
Self-citation
Metadata
- Authors
- Liske, A., Verlinden, K., Buhl, H., Schaper, K., & Ganter, C.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-24
- Volume
- 32
- Issue
- 19
- Pages
- 5269-5272
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2325339364
- Cited by
- 375
- References
- 32
- FWCI
- 10.39
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liske, A., Verlinden, K., Buhl, H., Schaper, K., & Ganter, C. (2013). Determining the π-Acceptor Properties of N-Heterocyclic Carbenes by Measuring the 77Se NMR Chemical Shifts of Their Selenium Adducts. Organometallics. https://doi.org/10.1021/om400858y
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