The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Thermodynamics of N-Heterocyclic Carbene Dimerization: The Balance of Sterics and Electronics
Open accessAbstract
The past decade has seen N-heterocyclic carbenes (NHC) emerging as a credible alternative to ubiquitous tertiary phosphines as ligands in organic and organometallic chemistry. In many cases NHC ligands have proven more effective than phosphines as ancillary ligands in catalysis, while in some cases they also enable unexpected and welcomed chemical routes to new products. (1) These initial discoveries have paved the way to a continued search for new NHCs able to promote more effective and/or unprecedented catalysis. Nevertheless, the search for new and useful NHCs remains an arduous task, because, to date, useful NHCs have to be synthesized as monomeric species, while some monomeric NHCs have the disappointing tendency to easily dimerize as shown in eq 1 . (1)
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Steric and electronic effects in the bonding of N-heterocyclic ligands to transition metals
Cavallo, L., Correa, A., Costabile, C., & Jacobsen, H. (2005) · Journal of Organometallic Chemistry · doi:10.1016/j.jorganchem.2005.07.012 · Cited by 479
Self-citationRelation between singlet-triplet gaps and bond energies
Carter, E. A., & Goddard, W. A. (1986) · The Journal of Physical Chemistry · doi:10.1021/j100278a006 · Cited by 309
When and How Do Diaminocarbenes Dimerize?
Alder, R. W., Blake, M. E., Chaker, L., Harvey, J. N., Paolini, F., & Schütz, J. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200400654 · Cited by 305
Ab initio study on the stability of diaminocarbenes
Heinemann, C., & Thiel, W. (1994) · Chemical Physics Letters · doi:10.1016/0009-2614(93)e1360-s · Cited by 170
Getty, K., Delgado‐Jaime, M. U., & Kennepohl, P. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0747674 · Cited by 55
Cited by
Towards the online computer-aided design of catalytic pockets
Falivene, L., Cao, Z., Petta, A., Serra, L., Poater, A., Oliva, R., Scarano, V., & Cavallo, L. (2019) · Nature Chemistry · doi:10.1038/s41557-019-0319-5 · Cited by 1,290
Self-citationCoinage Metal−N-Heterocyclic Carbene Complexes
Lin, J. C. Y., Huang, R. T. W., Lee, C. S., Bhattacharyya, A., Hwang, W. S., & Lin, I. J. B. (2009) · Chemical Reviews · doi:10.1021/cr8005153 · Cited by 1,036
SambVca 2. A Web Tool for Analyzing Catalytic Pockets with Topographic Steric Maps
Falivene, L., Credendino, R., Poater, A., Petta, A., Serra, L., Oliva, R., Scarano, V., & Cavallo, L. (2016) · Organometallics · doi:10.1021/acs.organomet.6b00371 · Cited by 907
Self-citationUnderstanding the M (NHC) (NHC = N-heterocyclic carbene) bond
Jacobsen, H., Correa, A., Poater, A., Costabile, C., & Cavallo, L. (2009) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2008.06.006 · Cited by 744
Self-citationComputational Ligand Descriptors for Catalyst Design
Durand, D. J., & Fey, N. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00588 · Cited by 406
Metadata
- Authors
- Poater, A., Ragone, F., Giudice, S., Costabile, C., Dorta, R., Nolan, S. P., & Cavallo, L.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-05-14
- Volume
- 27
- Issue
- 12
- Pages
- 2679-2681
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2066009270
- Cited by
- 289
- References
- 5
- FWCI
- 4.95
- Type
- journal article
- Language
- en
- Open access
- green
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
