The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Relative Reaction Rates of Olefin Substrates with Ruthenium(II) Carbene Metathesis Initiators1
Abstract
The metathesis of terminal olefins having different steric bulk and different geometries as well as electronically different para -substituted styrenes was studied with the ruthenium-based metathesis initiators trans -(PCy 3 ) 2 Cl 2 Ru CHR. Bulkier olefins were found to react slower, and trans internal olefins were found to be slower than cis. The kinetic product of all reactions was found to be the alkylidene rather than the methylidene. Observed effects were used to explain the mechanism of ring-opening cross metathesis. No linear electronic effects were observed.
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Citations
Cites
Steric effects of phosphorus ligands in organometallic chemistry and homogeneous catalysis
Tolman, C. A. (1977) · Chemical Reviews · doi:10.1021/cr60307a002 · Cited by 4,824
The development of functional group tolerant ROMP catalysts
Grubbs, R. H. (1994) · Journal of Macromolecular Science, Part A · doi:10.1080/10601329408545884 · Cited by 95
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Cited by
Grubbs, R. H. (2004) · Tetrahedron · doi:10.1016/j.tet.2004.05.124 · Cited by 1,205
Self-citationDíez-González, S., & Nolan, S. P. (2007) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2006.10.004 · Cited by 939
Enantioselective Ruthenium-Catalyzed Ring-Closing Metathesis
Seiders, T. J., Ward, D. W., & Grubbs, R. H. (2001) · Organic Letters · doi:10.1021/ol0165692 · Cited by 422
Self-citationRuthenium Carbene-Based Olefin Metathesis Initiators: Catalyst Decomposition and Longevity
Ulman, M., & Grubbs, R. H. (1999) · The Journal of Organic Chemistry · doi:10.1021/jo9908703 · Cited by 364
Self-citationFunctional end groups for polymers prepared using ring-opening metathesis polymerization
Hilf, S., & Kilbinger, A. F. M. (2009) · Nature Chemistry · doi:10.1038/nchem.347 · Cited by 228
Metadata
- Authors
- Ulman, M., & Grubbs, R. H.
- Venue
- Organometallics
- Publisher
- American Chemical Society (ACS)
- Published
- 1998-05-13
- Volume
- 17
- Issue
- 12
- Pages
- 2484-2489
- ISSN
- 0276-7333 (ISSN-L)
- 1520-6041
- OpenAlex
- W2060571053
- Cited by
- 222
- References
- 2
- FWCI
- 9.10
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ulman, M., & Grubbs, R. H. (1998). Relative Reaction Rates of Olefin Substrates with Ruthenium(II) Carbene Metathesis Initiators1. Organometallics. https://doi.org/10.1021/om9710172
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
