The DOI matches its Crossref record; 10 of the 10 references it cites were found in a registry or an index.
Review: Oxidation of Lignin Using Ionic Liquids—An Innovative Strategy To Produce Renewable Chemicals
Abstract
Lignin, one of the three subcomponents of lignocellulosic biomass (along with cellulose and hemicellulose), represents more than 20% of the total mass of the Earth’s biosphere. However, essentially due to its complex structure, this renewable polymer derived from biomass is mainly burned as a source of energy in the pulp and paper industry. Today, the valorization of lignin into the production of chemical feedstocks represents a real challenge in terms of both sustainability and environmental protection. This review first briefly outlines the main points of this challenge and compares the different methods investigated by chemists over the past several decades, pointing out the major difficulties met. Next, the review highlights the recent use of ionic liquids (ILs) as solvents that have provided some new opportunities to efficiently convert lignin and lignin model compounds into value-added aromatic chemicals. Particular focus is given to these new strategies in terms of selectivity, separation and the unique compounds obtained for the oxidation of lignin using ILs. Finally, an assessment of the challenges that must be resolved in order for ILs to become an eco-friendly way of producing chemicals from biomass, including lignin, is proposed.
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Citations
Cites
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Self-citationDeconstruction of Lignocellulosic Biomass to Fuels and Chemicals
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Cited by
Catalytic Transformation of Lignin for the Production of Chemicals and Fuels
Li, C., Zhao, X., Wang, A., Huber, G. W., & Zhang, T. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00155 · Cited by 2,951
Strategies for the Conversion of Lignin to High-Value Polymeric Materials: Review and Perspective
Upton, B. M., & Kasko, A. M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00345 · Cited by 1,519
Lignin depolymerisation strategies: towards valuable chemicals and fuels
Xu, C., Arancon, R. A. D., Labidi, J., & Luque, R. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00235k · Cited by 1,031
A review on lignin-based polymeric, micro- and nano-structured materials
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Downstream processing of lignin derived feedstock into end products
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Self-citationWood-lignin: Supply, extraction processes and use as bio-based material
Tribot, A., Amer, G., Abdou Alio, M., de Baynast, H., Delattre, C., Pons, A., Mathias, J.-D., Callois, J.-M., Vial, C., Michaud, P., et al. (2019) · European Polymer Journal · doi:10.1016/j.eurpolymj.2019.01.007 · Cited by 394
The role of lignin and lignin-based materials in sustainable construction – A comprehensive review
Jędrzejczak, P., Collins, M. N., Jesionowski, T., & Klapiszewski, Ł. (2021) · International Journal of Biological Macromolecules · doi:10.1016/j.ijbiomac.2021.07.125 · Cited by 339
Efficient valorization of biomass to biofuels with bifunctional solid catalytic materials
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Lignin Depolymerization to BTXs
Serrano, L., Cecilia, J. A., García-Sancho, C., & García, A. (2019) · Topics in Current Chemistry · doi:10.1007/s41061-019-0251-6 · Cited by 36
Metadata
- Authors
- Chatel, G., & Rogers, R. D.
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-10
- Volume
- 2
- Issue
- 3
- Pages
- 322-339
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2320482023
- Cited by
- 351
- References
- 10
- FWCI
- 13.29
- Type
- journal article
- Language
- en
- Open access
- closed
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