Uptake of HNO3 on water‐ice and coadsorption of HNO3 and HCl in the temperature range 210–235 K
Open accessAbstract
The uptake of HNO 3 on water‐ice films was investigated in a coated wall flow reactor under tropospheric temperature conditions. Experiments were performed in the “ice” region of the HNO 3–H 2 O phase diagram. With HNO 3 partial pressures in the range of (0.3–2.0) × 10−6 Torr, continuous uptake was observed below 215 K; whereas above 215 K, the uptake was time dependent. Using the geometric surface area of the ice film, the surface coverage at 218 K was 3.0 × 10 14 molecules/cm 2, decreasing to 1.5 × 10 14 molecules/cm 2 at 233 K; the timescales for saturation were 700 and 800 s at 218 and 233 K, respectively. The surface coverage was found to change by a factor of 2 over a 10‐fold change in HNO 3 partial pressure. By assuming that the surface coverage can be represented by a Langmuir isotherm for dissociative adsorption, the enthalpy of adsorption of HNO 3 onto ice was found to be −(54.0 ± 2.6) kJ/mol. At a constant HNO 3 partial pressure, the maximum uptake coefficients, γ, were measured as a function of temperature, decreasing from 0.03 at 215 K down to 0.006 at 235 K. The uptake coefficients at 218 K were not significantly affected by changes in HNO 3 partial pressure. The uptake of HCl at 218 K on ice surfaces previously dosed with HNO 3 was found to be reversible, and the coadsorption of HNO 3 with HCl indicates that HCl is displaced from surface sites by HNO 3 molecules. Uptake of HNO 3 on HCl‐dosed surfaces showed that HNO 3 molecules displace ∼10 13 molecules/cm 3 of HCl. The efficiency of cirrus clouds in scavenging HNO 3 is discussed, as well as the implications for chlorine activation reactions under tropospheric temperature conditions.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
In the absence of measurements on alumina, the reduction factor f for HCl adsorption due to HNO3 was estimated from a comparison of measurements of HCl uptake on ice with and without HNO3, giving f ≈ 33.
“In the absence of measurements on alumina, we have estimated f from a comparison of measurements of the HCl uptake on ice with HNO 3 (Hynes et al., 2002) and without HNO 3 (Zimmermann et al., 2016) and find f ≈ 33 (Text S5 in Supporting Information S1).”
From Chemical Impact of Stratospheric Alumina Particle Injection for Solar Radiation Modification and Related Uncertainties (2023) · cites this paper as Hynes et al., 2002
Cites
Physical chemistry of surfaces
Taylor, P. (1991) · Colloids and Surfaces · doi:10.1016/0166-6622(91)80262-m · Cited by 2,827 · see citing works
Laboratory studies of the nitric acid trihydrate: Implications for the south polar stratosphere
Hanson, D. R., & Mauersberger, K. (1988) · Geophysical Research Letters · doi:10.1029/gl015i008p00855 · Cited by 759 · see citing works
Condensation and evaporation of water on ice surfaces
Haynes, D. R., Tro, N. J., & George, S. M. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100200a055 · Cited by 263 · see citing works
Molecular Dynamics Simulation of Hydrochloric Acid Ionization at the Surface of Stratospheric Ice
Gertner, B. J., & Hynes, J. T. (1996) · Science · doi:10.1126/science.271.5255.1563 · Cited by 262 · see citing works
Hanson, D. R., Burkholder, J. B., Howard, C. J., & Ravishankara, A. R. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100191a046 · Cited by 260 · see citing works
Tubular flow reactors with first-order kinetics
Brown, R. L. (1978) · Journal of Research of the National Bureau of Standards · doi:10.6028/jres.083.001 · Cited by 257 · see citing works
Hanson, D. R., & Ravishankara, A. R. (1992) · The Journal of Physical Chemistry · doi:10.1021/j100185a052 · Cited by 255 · see citing works
Vapor Pressures of Solid Hydrates of Nitric Acid: Implications for Polar Stratospheric Clouds
Worsnop, D. R., Zahniser, M. S., Fox, L. E., & Wofsy, S. C. (1993) · Science · doi:10.1126/science.259.5091.71 · Cited by 247 · see citing works
The reaction probabilities of ClONO2 and N2O5 on polar stratospheric cloud materials
Hanson, D. R., & Ravishankara, A. R. (1991) · Journal of Geophysical Research Atmospheres · doi:10.1029/90jd02613 · Cited by 181 · see citing works
Doren, J. M. V., Watson, L. R., Davidovits, P., Worsnop, D. R., Zahniser, M. S., & Kolb, C. E. (1990) · The Journal of Physical Chemistry · doi:10.1021/j100371a009 · Cited by 178 · see citing works
Interaction of HNO3 with water‐ice surfaces at temperatures of the free troposphere
Abbatt, J. P. D. (1997) · Geophysical Research Letters · doi:10.1029/97gl01403 · Cited by 157 · see citing works
Adsorption to Ice of n-Alcohols (Ethanol to 1-Hexanol), Acetic Acid, and Hexanal
Sokolov, O. V., & Abbatt, J. P. D. (2002) · The Journal of Physical Chemistry A · doi:10.1021/jp013291m · Cited by 114 · see citing works
Uptake of hydrogen chloride in water ice and nitric acid ice films
Chu, L. T., Leu, M., & Keyser, L. F. (1993) · The Journal of Physical Chemistry · doi:10.1021/j100131a057 · Cited by 106 · see citing works
Uptake of HNO3 on ice under upper tropospheric conditions
Zondlo, M. A., Barone, S. B., & Tolbert, M. A. (1997) · Geophysical Research Letters · doi:10.1029/97gl01287 · Cited by 103 · see citing works
Arnold, F. H., Scheid, J., Stilp, T., Schlager, H., & Reinhardt, M. (1992) · Geophysical Research Letters · doi:10.1029/92gl02926 · Cited by 99 · see citing works
Zondlo, M. A., Onasch, T. B., Warshawsky, M. S., Tolbert, M. A., Mallick, G., Arentz, P., & Robinson, M. S. (1997) · The Journal of Physical Chemistry B · doi:10.1021/jp9709870 · Cited by 93 · see citing works
The impact of cloud particle gravitational settling on soluble trace gas distributions
Lawrence, M. G., & Crutzen, P. J. (1998) · Tellus B · doi:10.1034/j.1600-0889.1998.t01-2-00005.x · Cited by 88 · see citing works
Doren, J. M. V., Watson, L. R., Davidovits, P., Worsnop, D. R., Zahniser, M. S., & Kolb, C. E. (1990) · ChemInform · doi:10.1002/chin.199032023 · Cited by 76 · see citing works
Foster, K. L., Tolbert, M. A., & George, S. M. (1997) · The Journal of Physical Chemistry A · doi:10.1021/jp970772q · Cited by 68 · see citing works
Adsorption and Desorption of HCl on Ice
Isakson, M. J., & Sitz, G. O. (1999) · The Journal of Physical Chemistry A · doi:10.1021/jp984106g · Cited by 66 · see citing works
The uptake of HNO3 onto ice, NAT, and frozen sulfuric acid
Hanson, D. R. (1992) · Geophysical Research Letters · doi:10.1029/92gl02182 · Cited by 63 · see citing works
Chemical perturbation of the lowermost stratosphere through exchange with the troposphere
Lelieveld, J., Bregman, B., Arnold, F. H., Bürger, V., Crutzen, P. J., Fischer, H., Waibel, A. E., Siegmund, P., & van Velthoven, P. F. J. (1997) · Geophysical Research Letters · doi:10.1029/97gl00255 · Cited by 60 · see citing works
Tabazadeh, A., Toon, O. B., & Jensen, E. J. (1999) · Geophysical Research Letters · doi:10.1029/1999gl900501 · Cited by 46 · see citing works
Vertical profiles of hydrogen chloride in the troposphere
Vierkorn-Rudolph, B., B�chmann, K., Schwarz, B., & Meixner, F. X. (1984) · Journal of Atmospheric Chemistry · doi:10.1007/bf00127262 · Cited by 46 · see citing works
The vapor pressures of supercooled HNO3/H2O solutions
Hanson, D. R. (1990) · Geophysical Research Letters · doi:10.1029/gl017i004p00421 · Cited by 46 · see citing works
The HCl+ClONO2 reaction rate on various water ice surfaces
Lee, S., Leard, D. C., Zhang, R., Molina, L. T., & Molina, M. J. (1999) · Chemical Physics Letters · doi:10.1016/s0009-2614(99)01182-3 · Cited by 45 · see citing works
The interaction of HCl with water‐ice at tropospheric temperatures
Hynes, R. G., Mössinger, J. C., & Cox, R. A. (2001) · Geophysical Research Letters · doi:10.1029/2000gl012706 · Cited by 36 · see citing works
Self-citationSurface Sensitive Studies of the Reactive Uptake of Chlorine Nitrate on Ice
Berland, B. S., Tolbert, M. A., & George, S. M. (1997) · The Journal of Physical Chemistry A · doi:10.1021/jp971121x · Cited by 33 · see citing works
Schiller, C., Afchine, A., Eicke, N., Feigl, C., Fischer, H., Giez, A., Konopka, P., Schlager, H., Tuitjer, F., Wienhold, F. G., et al. (1999) · Geophysical Research Letters · doi:10.1029/1999gl900337 · Cited by 32 · see citing works
Uptake of nitric acid by sub‐micron‐sized ice particles
Arora, O. P., Cziczo, D. J., Morgan, A. M., Abbatt, J. P. D., & Niedziela, R. F. (1999) · Geophysical Research Letters · doi:10.1029/1999gl010881 · Cited by 29 · see citing works
Aguzzi, A., & Rossi, M. J. (2001) · Physical Chemistry Chemical Physics · doi:10.1039/b100546o · Cited by 23 · see citing works
The uptake of HI and HBr on ice
Percival, C. J., Mössinger, J. C., & Cox, R. A. (1999) · Physical Chemistry Chemical Physics · doi:10.1039/a904651h · Cited by 22 · see citing works
Self-citationInteraction of HOBr and HCl on ice surfaces in the temperature range 205–227 K
Mössinger, J. C., Hynes, R. G., & Cox, R. A. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd002151 · Cited by 8 · see citing works
Self-citation
Flagged first, then by citations
Cited by
Sorted by citations
Crowley, J. N., Ammann, M., Cox, R. A., Hynes, R. G., Jenkin, M. E., Mellouki, A., Rossi, M. J., Troe, J., & Wallington, T. J. (2010) · Atmospheric Chemistry and Physics · doi:10.5194/acp-10-9059-2010 · Cited by 379 · see citing works
Self-citationPöschl, U., Rudich, Y., & Ammann, M. (2007) · Atmospheric chemistry and physics · doi:10.5194/acp-7-5989-2007 · Cited by 321 · see citing works
Bartels‐Rausch, T., Jacobi, H., Kahan, T. F., Thomas, J. L., Thomson, E. S., Abbatt, J. P. D., Ammann, M., Blackford, J. R., Bluhm, H., Boxe, C. S., et al. (2014) · Atmospheric chemistry and physics · doi:10.5194/acp-14-1587-2014 · Cited by 319 · see citing works
Interactions of Atmospheric Trace Gases with Ice Surfaces: Adsorption and Reaction
Abbatt, J. P. D. (2003) · Chemical Reviews · doi:10.1021/cr0206418 · Cited by 251 · see citing works
Atmospheric Degradation of Ozone Depleting Substances, Their Substitutes, and Related Species
Burkholder, J. B., Cox, R. A., & Ravishankara, A. R. (2015) · Chemical Reviews · doi:10.1021/cr5006759 · Cited by 230 · see citing works
Self-citationThe Uptake of Acidic Gases on Ice
Huthwelker, T., Ammann, M., & Peter, T. (2006) · Chemical Reviews · doi:10.1021/cr020506v · Cited by 189 · see citing works
Nitric acid uptake on subtropical cirrus cloud particles
Popp, P. J., Gao, R. S., Marcy, T. P., Fahey, D. W., Hudson, P. K., Thompson, T. L., Kärcher, B., Ridley, B. A., Weinheimer, A. J., Knapp, D. J., et al. (2004) · Journal of Geophysical Research Atmospheres · doi:10.1029/2003jd004255 · Cited by 79 · see citing works
Uptake of reactive nitrogen on cirrus cloud particles during INCA
Ziereis, H., Minikin, A., Schlager, H., Gayet, J., Auriol, F., Stock, P., Baehr, J., Petzold, A., Schumann, U., Weinheimer, A., et al. (2004) · Geophysical Research Letters · doi:10.1029/2003gl018794 · Cited by 46 · see citing works
Ullerstam, M., Thornberry, T., & Abbatt, J. P. D. (2005) · Faraday Discussions · doi:10.1039/b417418f · Cited by 40 · see citing works
Coexistence of Physisorbed and Solvated HCl at Warm Ice Surfaces
Kong, X., Waldner, A., Orlando, F., Artiglia, L., Huthwelker, T., Ammann, M., & Bartels‐Rausch, T. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b01573 · Cited by 37 · see citing works
A kinetic model for uptake of HNO3 and HCl on ice in a coated wall flow system
Cox, R. A., Fernandez, M. A., Symington, A., Ullerstam, M., & Abbatt, J. P. D. (2005) · Physical Chemistry Chemical Physics · doi:10.1039/b506683b · Cited by 33 · see citing works
Self-citationHallar, A. G., Avallone, L. M., Herman, R. L., Anderson, B. E., & Heymsfield, A. J. (2004) · Journal of Geophysical Research Atmospheres · doi:10.1029/2003jd004348 · Cited by 32 · see citing works
Burial of gas-phase HNO3 by growing ice surfaces under tropospheric conditions
Ullerstam, M., & Abbatt, J. P. D. (2005) · Physical Chemistry Chemical Physics · doi:10.1039/b507797d · Cited by 29 · see citing works
Xueref-Rémy, I., & Dominé, F. (2003) · Atmospheric chemistry and physics · doi:10.5194/acp-3-1779-2003 · Cited by 29 · see citing works
Bock, J., Savarino, J., & Picard, G. (2016) · Atmospheric chemistry and physics · doi:10.5194/acp-16-12531-2016 · Cited by 27 · see citing works
Ionization of Nitric Acid on Crystalline Ice: The Role of Defects and Collective Proton Movement
Riikonen, S., Parkkinen, P., Halonen, L., & Gerber, R. B. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400531q · Cited by 27 · see citing works
Vattioni, S., Luo, B., Feinberg, A., Stenke, A., Vockenhuber, C., Weber, R., Dykema, J. A., Krieger, U. K., Ammann, M., Keutsch, F., et al. (2023) · Geophysical Research Letters · doi:10.1029/2023gl105889 · Cited by 26 · see citing works
“In the absence of measurements on alumina, we have estimated f from a comparison of measurements of the HCl uptake on ice with HNO 3 (Hynes et al., 2002) and without HNO 3 (Zimmermann et al., 2016) and find f ≈ 33 (Text S5 in Supporting Information S1).”
MethodMarécal, V., Pirre, M., Rivière, E., Pouvesle, N., Crowley, J. N., Freitas, S. R., & Longo, K. M. (2010) · Atmospheric chemistry and physics · doi:10.5194/acp-10-4977-2010 · Cited by 26 · see citing works
The impact of ice uptake of nitric acid on atmospheric chemistry
von Kuhlmann, R., & Lawrence, M. G. (2006) · Atmospheric chemistry and physics · doi:10.5194/acp-6-225-2006 · Cited by 26 · see citing works
Aubin, D., & Abbatt, J. P. D. (2005) · Environmental Science & Technology · doi:10.1021/es050800f · Cited by 25 · see citing works
Ozone in Interstitial Air of the Mid-Latitude, Seasonal Snowpack at Niwot Ridge, Colorado
Bocquet, F., Helmig, D., & Oltmans, S. J. (2007) · Arctic Antarctic and Alpine Research · doi:10.1657/1523-0430(06-027)[boquet]2.0.co;2 · Cited by 23 · see citing works
Chlorine activation near the midlatitude tropopause
Thornton, B. F., Toohey, D. W., Tuck, A. F., Elkins, J. W., Kelly, K. K., Hovde, S. J., Richard, E. C., Rosenlof, K. H., Thompson, T. L., Mahoney, M. J., et al. (2007) · Journal of Geophysical Research Atmospheres · doi:10.1029/2006jd007640 · Cited by 23 · see citing works
Kinetics of ClONO2 Reactive Uptake on Ice Surfaces at Temperatures of the Upper Troposphere
Fernandez, M. A., Hynes, R. G., & Cox, R. A. (2005) · The Journal of Physical Chemistry A · doi:10.1021/jp053477b · Cited by 21 · see citing works
Self-citationGuo, L., Su, H., Kühn, U., Meusel, H., Ammann, M., Shao, M., Pöschl, U., & Cheng, Y. (2018) · Atmospheric chemistry and physics · doi:10.5194/acp-18-2669-2018 · Cited by 21 · see citing works
The adsorption of peroxynitric acid on ice between 230 K and 253 K
Ulrich, T., Ammann, M., Leutwyler, S., & Bartels‐Rausch, T. (2012) · Atmospheric chemistry and physics · doi:10.5194/acp-12-1833-2012 · Cited by 19 · see citing works
Nitric acid partitioning in cirrus clouds: the role of aerosol particles and relative humidity
Krämer, M., Schiller, C., Ziereis, H., Ovarlez, J., & Bunz, H. (2006) · Tellus B · doi:10.1111/j.1600-0889.2006.00177.x · Cited by 19 · see citing works
Reversible Gas Adsorption in Coated Wall Flow Tube Reactors. Model Simulations for Langmuir Kinetics
Behr, P. M., Terziyski, A. T., & Zellner, R. (2004) · Zeitschrift für Physikalische Chemie · doi:10.1524/zpch.218.11.1307.50806 · Cited by 19 · see citing works
Adsorption isotherms for hydrogen chloride (HCl) on ice surfaces between 190 and 220 K
Zimmermann, S., Kippenberger, M., Schuster, G., & Crowley, J. N. (2016) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp01962e · Cited by 17 · see citing works
Influence of the ice growth rate on the incorporation of gaseous HClPreprint
Dominé, F., & Rauzy, C. (2004) · doi:10.5194/acpd-4-4719-2004 · Cited by 17 · see citing works
Co-adsorption of acetic acid and nitrous acid on ice
Kerbrat, M., Huthwelker, T., Bartels‐Rausch, T., Gäggeler, H. W., & Ammann, M. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/b924782c · Cited by 16 · see citing works
Influence of the ice growth rate on the incorporation of gaseous HCl
Dominé, F., & Rauzy, C. (2004) · Atmospheric chemistry and physics · doi:10.5194/acp-4-2513-2004 · Cited by 16 · see citing works
Evidence of nitric acid uptake in warm cirrus anvil clouds during the NASA TC4 campaign
Scheuer, E., Dibb, J. E., Twohy, C. H., Rogers, D. C., Heymsfield, A. J., & Bansemer, A. R. (2010) · Journal of Geophysical Research Atmospheres · doi:10.1029/2009jd012716 · Cited by 14 · see citing works
Development of a gas phase source for perfluoroalkyl acids to examine atmospheric sampling methods
MacInnis, J. J., VandenBoer, T. C., & Young, C. J. (2016) · The Analyst · doi:10.1039/c6an00313c · Cited by 14 · see citing works
Sokolov, O. V., & Abbatt, J. P. D. (2002) · Geophysical Research Letters · doi:10.1029/2002gl014843 · Cited by 13 · see citing works
Evidence of rapid hydrogen chloride uptake on water ice in the atmosphere of Mars
Luginin, M., Trokhimovskiy, A. Y., Taysum, B. M., Fedorova, A. A., Korablev, O., Olsen, K. S., Montmessin, F., & Lefèvre, F. (2024) · Icarus · doi:10.1016/j.icarus.2024.115960 · Cited by 12 · see citing works
Variability of active chlorine in the lowermost Arctic stratosphere
Thornton, B. F., Toohey, D. W., Avallone, L. M., Hallar, A. G., Harder, H., Martínez, M., Simpas, J. B., Brune, W. H., Koike, M., Kondo, Y., et al. (2005) · Journal of Geophysical Research Atmospheres · doi:10.1029/2004jd005580 · Cited by 12 · see citing works
Clapp, C. E., & Anderson, J. G. (2019) · Journal of Geophysical Research Atmospheres · doi:10.1029/2018jd029703 · Cited by 9 · see citing works
Interaction of HOBr and HCl on ice surfaces in the temperature range 205–227 K
Mössinger, J. C., Hynes, R. G., & Cox, R. A. (2002) · Journal of Geophysical Research Atmospheres · doi:10.1029/2002jd002151 · Cited by 8 · see citing works
Self-citationChiesa, S., & Rossi, M. J. (2013) · Atmospheric chemistry and physics · doi:10.5194/acp-13-11905-2013 · Cited by 7 · see citing works
Vapor-deposited water and nitric acid ices: Physical and chemical properties
Leu, M., & Keyser, L. F. (2009) · International Reviews in Physical Chemistry · doi:10.1080/01442350802617129 · Cited by 7 · see citing works
Nitric acid partitioning in cirrus clouds: a synopsis based on field, laboratory and model studiesPreprint
Krämer, M., Beuermann, J., Schiller, C., Grimm, F., Arnold, F. H., Peter, T., Meilinger, S., Meier, A. C., Hendricks, J., Petzold, A., et al. (2003) · doi:10.5194/acpd-3-413-2003 · Cited by 7 · see citing works
Uptake of Formic Acid on Thin Ice Films and on Ice Doped with Nitric Acid between 195 and 211 K
Romanías, M. N., Zogka, A., Stefanopoulos, V. G., Papadimitriou, V. C., & Papagiannakopoulos, P. (2010) · ChemPhysChem · doi:10.1002/cphc.201000434 · Cited by 6 · see citing works
Gamblin, B., Toon, O. B., Tolbert, M. A., Kondo, Y., Takegawa, N., Irie, H., Koike, M., Hudson, P. K., Ballenthin, J. O., Hunton, D. E., et al. (2007) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd006049 · Cited by 5 · see citing works
Iannarelli, R., & Rossi, M. J. (2016) · Atmospheric chemistry and physics · doi:10.5194/acp-16-11937-2016 · Cited by 4 · see citing works
Exposure of nitric acid trihydrate crystals to HCl: A spectroscopic study
Ortega, I. K., Escribano, R. M., Herrero, V. J., Maté, B., & Moreno, M. Á. (2006) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd006931 · Cited by 4 · see citing works
Gamblin, B., Toon, O. B., Tolbert, M. A., Kondo, Y., Takegawa, N., Irie, H., Koike, M., Ballenthin, J. O., Hunton, D. E., Miller, T. M., et al. (2006) · Journal of Geophysical Research Atmospheres · doi:10.1029/2005jd006048 · Cited by 4 · see citing works
Simpson, I. J., Wingenter, O. W., Westberg, D. J., Fuelberg, H. E., Kiley, C. M., Crawford, J. H., Meinardi, S., Blake, D. R., & Rowland, F. S. (2003) · Geophysical Research Letters · doi:10.1029/2003gl017598 · Cited by 4 · see citing works
Zhang-Liu, Y., Muller, R. H., Grooß, J., Robrecht, S., Vogel, B., Zafar, A. M., & Lehmann, R. (2024) · Atmospheric chemistry and physics · doi:10.5194/acp-24-12557-2024 · Cited by 3 · see citing works
Reactive uptake coefficients for multiphase reactions determined by a dynamic chamber system
Guo, L., Su, H., Li, M., Kühn, U., Zheng, G., Han, L., Bao, F., Pöschl, U., & Cheng, Y. (2022) · Atmospheric measurement techniques · doi:10.5194/amt-15-6433-2022 · Cited by 2 · see citing works
Santachiara, G., Belosi, F., Nicosia, A., & PRODI, F. (2016) · Atmospheric and Climate Sciences · doi:10.4236/acs.2016.61007 · Cited by 1 · see citing works
Spectroscopic investigation of nitric acid monohydrate
Baloh, P., Grothe, H., Whitmore, K., Parker, S. F., Martín-Llorente, B., & Escribano, R. M. (2011) · Molecular Physics · doi:10.1080/00268976.2011.593571 · Cited by 1 · see citing works
Giraud, X., Baroni, M., & Traversi, R. (2023) · doi:10.5194/egusphere-2022-1455 · Cited by 1 · see citing works
Schreiber, S., Kerbrat, M., Huthwelker, T., Birrer, M., & Ammann, M. (2013) · Review of Scientific Instruments · doi:10.1063/1.4793405
Corelation between Earth Weather and Space Weather
Yılmaz, A. (2014) · AIAA SPACE Conference & Exposition · doi:10.2514/6.2014-4286
(2022) · Atmospheric measurement techniques · doi:10.5194/amt-2022-211-rc1
(2022) · Atmospheric measurement techniques · doi:10.5194/amt-2022-211-rc2
Guo, L. (2022) · Atmospheric measurement techniques · doi:10.5194/amt-2022-211-ac2
Guo, L. (2022) · Atmospheric measurement techniques · doi:10.5194/amt-2022-211-ac1
Uptake of Stratospheric Species on Minerals Proposed for Stratospheric Aerosol Injection
Lostier, A., Segev, Y., Kislev, T., Roitman, G. S., & Romanías, M. N. (2026) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.6c00142
- Authors
- Hynes, R. G., Fernandez, M. A., & Cox, R. A.
- Affiliations
- University of Cambridge (GB)
- ORCID
- Cox, R. Anthony
- Venue
- Journal of Geophysical Research: Atmospheres
- Publisher
- American Geophysical Union (AGU)
- Published
- 2002-12-27
- Volume
- 107
- Issue
- D24
- ISSN
- 0148-0227 (ISSN-L)
- OpenAlex
- W2089116442
- Cited by
- 61
- References
- 33
- Citations by year
- 2026: 1 · 2024: 2 · 2023: 4 · 2022: 5 · 2019: 1 · 2018: 1 · 2017: 1 · 2016: 5 · 2015: 1 · 2014: 2 · 2013: 3 · 2012: 1
- FWCI
- 4.46
- Type
- journal article
- Language
- en
- Open access
- bronze
- doi.org
- Locations
- Journal of Geophysical Research Atmospheres (publishedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Environmental Science › Global and Planetary Change › Atmospheric aerosols and clouds
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › nanoparticles nucleation surface interactions
- Keywords
- nitric acid uptake, water ice, coadsorption, hydrogen chloride, Langmuir isotherm, heat of adsorption, uptake coefficient, surface coverage, dissociative adsorption, ice clouds, chlorine activation, tropospheric temperature
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
